Systematically varying zwitterionic-siloxane surfactant structure to affect interfacial properties, foam stability, and fire suppression

Abstract

Zwitterionic siloxane-sulfobetaine (siloxaneSB) surfactants are developed to replace per- and poly-fluoroalkyl substances (PFAS) used currently in aqueous firefighting foams because PFAS pose significant threats to environment and human health. SiloxaneSB surfactant's head and tail structures are varied gradually, one step at a time, to vary hydrophilicity of the head and hydrophobicity, and oleophobicity of the tail. Identical methods and conditions are used across all the surfactants to correlate surfactant structure to interfacial and foam properties, and fire suppression. The results suggest that the amphiphilic balance of the siloxane surfactant have dramatic effects on CMC, interfacial tension, foam expansion ratio, foam degradation, heptane vapor permeation through a foam layer, and fire suppression but little effect on bubble size, coarsening, and liquid drainage. They show synergism between siloxaneSB and alkylpolyglycoside in gasoline fire suppression while trisiloxane-polyoxyethylene exhibited synergism in heptane fire suppression. A 28 ft² gasoline pool-fire suppression results were consistent with the bench-scale findings for tetrasiloxaneSB and trisiloxane-polyoxyethylene formulations. Small changes to surfactant molecular structure can dramatically improve its amphiphilic balance, synergisms, fuel-foam interactions resulting in improved effectiveness of fluorine-free foams but depend very much on the fuel, unlike the fluorocarbon surfactants.