K. Nagpal, E. Rauwel, Frédérique Ducroquet, Isabelle Gélard, P. Rauwel
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引用次数: 0
Abstract
This work reports on the fabrication of ZnO polymer-based hybrid ultraviolet (UV) photodiodes with a configuration of ITO/ZnO-nanorod/F8BT/PEDOT:PSS/Ag. The diode was fabricated by spin-coating p-type F8BT and PEDOT:PSS polymers on hydrothermally grown n-type ZnO nanorods. The growth of ZnO nanorods was carried out by varying seed layer alcohols, viz., methanol, ethanol, isopropanol, and aqueous ethanol (70% alcohol). These solvents influenced the nanorod diameter, surface coverage, and surface defects. Herein, we demonstrate that the uniformity and defects in ZnO nanorods govern the electrical properties, photoresponse, and figures of merit of the photodiodes. In particular, the photodiodes are evaluated on their rectification ratio, ideality factor (η), responsivity (R), external quantum efficiency (EQE), and response time (Tdecay). The photodiode fabricated with ZnO nanorods grown on the methanol seeding layer has demonstrated the best performance, owing to the uniform surface coverage of the nanorods. It also presented the highest rectification ratio of ∼640, a Tdecay of 108 s, a η of 2, an EQE of ∼2760%, and an R of ∼8.14 A/W at −2 V.
期刊介绍:
APL Materials features original, experimental research on significant topical issues within the field of materials science. In order to highlight research at the forefront of materials science, emphasis is given to the quality and timeliness of the work. The journal considers theory or calculation when the work is particularly timely and relevant to applications.
In addition to regular articles, the journal also publishes Special Topics, which report on cutting-edge areas in materials science, such as Perovskite Solar Cells, 2D Materials, and Beyond Lithium Ion Batteries.