Pickering emulsion stabilized by cellulose nanofibril from pineapple leaves for biofoam manufacture

IF 5.45 Q1 Physics and Astronomy Nano-Structures & Nano-Objects Pub Date : 2024-06-21 DOI:10.1016/j.nanoso.2024.101223
Devi Nurani , Nanang Masruchin , Bernadeta Ayu Widyaningrum , Sukma Surya Kusumah , Riska Surya Ningrum , Handoko Darmokoesoemo , Heri Septya Kusuma
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Abstract

Cellulose nano fibril (CNF) can be selected as an agent of pickering emulsion in biofoam manufacture. This study thoroughly investigates the pickering emulsion method for producing biofoam, the characterization of CNF from pineapple leaves, the production of biofoam with various concentration of CNF and surfactant, and the effect of these parameters on the properties of wet foam and dry foam. CNF was created by mechanical grinding then the stability and morphology were evaluated. The pickering emulsion mechanism in biofoam manufacture was investigated using foamability and foam stability with various CNF and surfactant concentration. As the results, CNF concentrations will create varying zeta potential values. The morphology of CNF shows that it has a structure-like entangled network. The stability test demonstrates that adding CNF improves the stability and foamability of biofoam by the pickering effect. Biofoam without CNF has an unstable structure and is easily collapse when dried in an oven. The concentration of CNF and the amount of surfactant utilized altered the qualities of both wet and dry foam. The lower concentration of CNF and the addition of surfactant could increases foamability, high porosity, water absorption, and biodegradability; as well as low density, contact angle and bending characteristics. In biofoam that consists of 2 % CNF, the stability of wet foam increases as the amount of surfactant added, resulting in a biofoam with low tensile strength.

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用菠萝叶纤维素纳米纤维稳定的皮克林乳液用于生物泡沫制造
纤维素纳米纤维(CNF)可被选为生物泡沫生产中的浸提乳剂。本研究深入探讨了生产生物泡沫的酸洗乳液法、菠萝叶中纤维素纳米纤维的表征、不同浓度的纤维素纳米纤维和表面活性剂对生物泡沫生产的影响,以及这些参数对湿泡沫和干泡沫性能的影响。CNF 通过机械研磨制成,然后对其稳定性和形态进行评估。利用不同浓度 CNF 和表面活性剂的发泡性和泡沫稳定性,研究了生物泡沫制造中的萃取乳化机制。结果表明,不同浓度的 CNF 会产生不同的 zeta 电位值。CNF 的形态显示其具有类似结构的缠结网络。稳定性测试表明,添加 CNF 后,生物泡沫的稳定性和可发泡性得到了改善。不添加 CNF 的生物泡沫结构不稳定,在烘箱中干燥时容易坍塌。CNF 的浓度和表面活性剂的用量会改变湿泡沫和干泡沫的质量。氯化萘纤维的浓度越低,表面活性剂的添加量越多,泡沫的可发性、高孔隙率、吸水性和生物降解性就越好;同时密度、接触角和弯曲特性也越低。在含有 2% CNF 的生物泡沫中,湿泡沫的稳定性随着表面活性剂添加量的增加而增加,导致生物泡沫的拉伸强度较低。
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来源期刊
Nano-Structures & Nano-Objects
Nano-Structures & Nano-Objects Physics and Astronomy-Condensed Matter Physics
CiteScore
9.20
自引率
0.00%
发文量
60
审稿时长
22 days
期刊介绍: Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .
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