Libo Xiang, Alexander Matler, Leibo Tan and Qing Ye
{"title":"Reactivity study of Lewis superacidic carborane-based analogue of 9-bromo-9-borafluorene towards Lewis bases†","authors":"Libo Xiang, Alexander Matler, Leibo Tan and Qing Ye","doi":"10.1039/D4DT01615G","DOIUrl":null,"url":null,"abstract":"<p >In this contribution, we present the reactions of the <em>o</em>-carborane-based analogue of 9-bromo-9-borafluorene, a Lewis superacid, with diverse Lewis bases. A range of acid–base adducts, along with an intramolecular C–H activation product, were generated. All new compounds have been fully characterized.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 28","pages":" 11655-11658"},"PeriodicalIF":3.3000,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt01615g","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
In this contribution, we present the reactions of the o-carborane-based analogue of 9-bromo-9-borafluorene, a Lewis superacid, with diverse Lewis bases. A range of acid–base adducts, along with an intramolecular C–H activation product, were generated. All new compounds have been fully characterized.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.