Wenjing Dai, Boge Zhang, Jian Ji, Tianle Zhu, Biyuan Liu, Yanling Gan, Fei Xiao, Jiarui Zhang and Haibao Huang*,
{"title":"Efficient Ozone Elimination Over MnO2 via Double Moisture-Resistance Protection of Active Carbon and CeO2","authors":"Wenjing Dai, Boge Zhang, Jian Ji, Tianle Zhu, Biyuan Liu, Yanling Gan, Fei Xiao, Jiarui Zhang and Haibao Huang*, ","doi":"10.1021/acs.est.4c02482","DOIUrl":null,"url":null,"abstract":"<p >The widespread ozone (O<sub>3</sub>) pollution is extremely hazardous to human health and ecosystems. Catalytic decomposition into O<sub>2</sub> is the most promising method to eliminate ambient O<sub>3</sub>, while the fast deactivation of catalysts under humid conditions remains the primary challenge for their application. Herein, we elaborately developed a splendidly active and stable Mn-based catalyst with double hydrophobic protection of active carbon (AC) and CeO<sub>2</sub> (CeMn@AC), which possessed abundant interfacial oxygen vacancies and excellent desorption of peroxide intermediates (O<sub>2</sub><sup>2–</sup>). Under extremely humid (RH = 90%) conditions and a high space velocity of 1200 L h<sup>–1</sup> g<sup>–1</sup>, the optimized CeMn@AC achieved nearly 100% O<sub>3</sub> conversion (140 h) at 5 ppm, showing unprecedented catalytic activity and moisture resistance toward O<sub>3</sub> decomposition. <i>In situ</i> DRIFTS and theory calculations confirmed that the exceptional moisture resistance of CeMn@AC was ascribed to the double protection effect of AC and CeO<sub>2</sub>, which cooperatively prevented the competitive adsorption of H<sub>2</sub>O molecules and their accumulation on the active sites of MnO<sub>2</sub>. AC provided a hydrophobic reaction environment, and CeO<sub>2</sub> further alleviated moisture deterioration of the MnO<sub>2</sub> particles exposed on the catalyst surface via the moisture-resistant oxygen vacancies of MnO<sub>2</sub>–CeO<sub>2</sub> crystal boundaries. This work offers a simple and efficient strategy for designing moisture-resistant materials and facilitates the practical application of the O<sub>3</sub> decomposition catalysts in various environments.</p>","PeriodicalId":36,"journal":{"name":"环境科学与技术","volume":null,"pages":null},"PeriodicalIF":10.8000,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"环境科学与技术","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.est.4c02482","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0
Abstract
The widespread ozone (O3) pollution is extremely hazardous to human health and ecosystems. Catalytic decomposition into O2 is the most promising method to eliminate ambient O3, while the fast deactivation of catalysts under humid conditions remains the primary challenge for their application. Herein, we elaborately developed a splendidly active and stable Mn-based catalyst with double hydrophobic protection of active carbon (AC) and CeO2 (CeMn@AC), which possessed abundant interfacial oxygen vacancies and excellent desorption of peroxide intermediates (O22–). Under extremely humid (RH = 90%) conditions and a high space velocity of 1200 L h–1 g–1, the optimized CeMn@AC achieved nearly 100% O3 conversion (140 h) at 5 ppm, showing unprecedented catalytic activity and moisture resistance toward O3 decomposition. In situ DRIFTS and theory calculations confirmed that the exceptional moisture resistance of CeMn@AC was ascribed to the double protection effect of AC and CeO2, which cooperatively prevented the competitive adsorption of H2O molecules and their accumulation on the active sites of MnO2. AC provided a hydrophobic reaction environment, and CeO2 further alleviated moisture deterioration of the MnO2 particles exposed on the catalyst surface via the moisture-resistant oxygen vacancies of MnO2–CeO2 crystal boundaries. This work offers a simple and efficient strategy for designing moisture-resistant materials and facilitates the practical application of the O3 decomposition catalysts in various environments.
期刊介绍:
Environmental Science & Technology (ES&T) is a co-sponsored academic and technical magazine by the Hubei Provincial Environmental Protection Bureau and the Hubei Provincial Academy of Environmental Sciences.
Environmental Science & Technology (ES&T) holds the status of Chinese core journals, scientific papers source journals of China, Chinese Science Citation Database source journals, and Chinese Academic Journal Comprehensive Evaluation Database source journals. This publication focuses on the academic field of environmental protection, featuring articles related to environmental protection and technical advancements.