{"title":"Emerging investigator series: quantitative insights into the relationship between the concentrations and SERS intensities of neonicotinoids in water†","authors":"Shengdong Liu, James Lazarcik and Haoran Wei","doi":"10.1039/D4EN00221K","DOIUrl":null,"url":null,"abstract":"<p >This study explores the theoretical foundation behind the application of surface-enhanced Raman spectroscopy (SERS) for neonicotinoid quantification. Our findings demonstrate that SERS intensities are determined by the thermodynamic adsorption behaviors of neonicotinoid molecules transitioning from aqueous phases to gold nanoparticle (AuNP) surfaces. The dynamic ranges and limits of detection can be accurately predicted by classic adsorption isotherms.</p>","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":" 8","pages":" 3294-3300"},"PeriodicalIF":5.1000,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science: Nano","FirstCategoryId":"6","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/en/d4en00221k","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
This study explores the theoretical foundation behind the application of surface-enhanced Raman spectroscopy (SERS) for neonicotinoid quantification. Our findings demonstrate that SERS intensities are determined by the thermodynamic adsorption behaviors of neonicotinoid molecules transitioning from aqueous phases to gold nanoparticle (AuNP) surfaces. The dynamic ranges and limits of detection can be accurately predicted by classic adsorption isotherms.
期刊介绍：
Environmental Science: Nano serves as a comprehensive and high-impact peer-reviewed source of information on the design and demonstration of engineered nanomaterials for environment-based applications. It also covers the interactions between engineered, natural, and incidental nanomaterials with biological and environmental systems. This scope includes, but is not limited to, the following topic areas:
Novel nanomaterial-based applications for water, air, soil, food, and energy sustainability
Nanomaterial interactions with biological systems and nanotoxicology
Environmental fate, reactivity, and transformations of nanoscale materials
Nanoscale processes in the environment
Sustainable nanotechnology including rational nanomaterial design, life cycle assessment, risk/benefit analysis
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