{"title":"In-situ charge polarization effect of copper(II) ion-coordination covalent organic framework induced aerobic PET-ATRP in aqueous phase","authors":"Jinfeng Wang, Hongjie Yang, Rui Zhao, Linxi Hou","doi":"10.1016/j.jcat.2024.115616","DOIUrl":null,"url":null,"abstract":"Covalent organic frameworks (COFs) are ideal heterogeneous photocatalytic platforms offering fascinating spaces for manipulation given their clearly defined structures along with pre-customizable skeletons. Herein, an imine-based COF Im-oMe featuring N and O sites allowing the integration of Cu ions via coordination bonds in local regions of the skeleton is reported for aerobic photoinduced electron/energy transfer atom transfer radical polymerization (PET-ATRP) in the aqueous phase. Cu@Im-oMe of anchored Cu ions is capable of triggering skeleton localized polarization effects, producing greater dipole moment driving force and facilitating the charge separation and transport to enhance its photopolymerization performance. Meanwhile, the system does not require additional addition of transition metal halides, and remains highly active after 3 cycles. The present work expands the feasible design methods and strategies of heterogeneous photocatalysts available for precision production of polymers in open-air environments.","PeriodicalId":346,"journal":{"name":"Journal of Catalysis","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Catalysis","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.jcat.2024.115616","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Covalent organic frameworks (COFs) are ideal heterogeneous photocatalytic platforms offering fascinating spaces for manipulation given their clearly defined structures along with pre-customizable skeletons. Herein, an imine-based COF Im-oMe featuring N and O sites allowing the integration of Cu ions via coordination bonds in local regions of the skeleton is reported for aerobic photoinduced electron/energy transfer atom transfer radical polymerization (PET-ATRP) in the aqueous phase. Cu@Im-oMe of anchored Cu ions is capable of triggering skeleton localized polarization effects, producing greater dipole moment driving force and facilitating the charge separation and transport to enhance its photopolymerization performance. Meanwhile, the system does not require additional addition of transition metal halides, and remains highly active after 3 cycles. The present work expands the feasible design methods and strategies of heterogeneous photocatalysts available for precision production of polymers in open-air environments.
期刊介绍:
The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes.
The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods.
The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.