Novel utilization of waste concrete powder in alkali-activated binder

IF 7.2 2区 工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of CO2 Utilization Pub Date : 2024-06-01 DOI:10.1016/j.jcou.2024.102859
Aidarus Yonis , Prabhat Vashistha , Yanchen Oinam , Martin Cyr , Sukhoon Pyo
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Abstract

This experimental study investigates a novel approach to utilize waste concrete powder (WCP) in conjunction with metakaolin as a precursor in the production of alkali-activated binder for sustainable consumption of construction and demolition waste. A Chapelle test confirms the presence of reactive silica in thermo-mechanically activated WCP. Different alkali-activated mixtures with metakaolin replacement ranging from 0 % to 80 % were prepared. The mixture with 40 % activated WCP, with a sodium silicate to sodium hydroxide ratio of 2, achieved better compressive strength than the reference sample without WCP. Mineralogical analysis of the mixture pastes revealed that activated WCP-based mixtures developed geopolymer gel and C-S-H gel, contributing to better strength properties in the case of the mixture with 40 % activated WCP. Life cycle analysis demonstrated that incorporating 40 % thermo-mechanically activated WCP by replacing metakaolin reduces carbon dioxide emissions by 49.5 % and 2.2 % compared to Portland cement and metakaolin-based binder, respectively.

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废混凝土粉在碱活性粘结剂中的新型利用
本实验研究探讨了一种新方法,即利用废弃混凝土粉(WCP)和偏高岭土作为前体,生产碱活性粘结剂,以实现建筑和拆除废弃物的可持续利用。查佩尔试验证实了热机械活化 WCP 中活性二氧化硅的存在。我们制备了不同的碱活化混合物,其中偏高岭土的替代率从 0% 到 80%不等。在硅酸钠与氢氧化钠的比例为 2 的情况下,含有 40% 活性 WCP 的混合物的抗压强度优于不含 WCP 的参考样品。对混合物浆料的矿物学分析表明,基于活化五氯苯酚的混合物产生了土工聚合物凝胶和 C-S-H 凝胶,从而使含有 40% 活化五氯苯酚的混合物具有更好的强度特性。生命周期分析表明,与波特兰水泥和偏高岭土基粘结剂相比,加入 40% 的热机械活化水硬性聚氯乙烯替代偏高岭土,可分别减少 49.5% 和 2.2% 的二氧化碳排放量。
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来源期刊
Journal of CO2 Utilization
Journal of CO2 Utilization CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.90
自引率
10.40%
发文量
406
审稿时长
2.8 months
期刊介绍: The Journal of CO2 Utilization offers a single, multi-disciplinary, scholarly platform for the exchange of novel research in the field of CO2 re-use for scientists and engineers in chemicals, fuels and materials. The emphasis is on the dissemination of leading-edge research from basic science to the development of new processes, technologies and applications. The Journal of CO2 Utilization publishes original peer-reviewed research papers, reviews, and short communications, including experimental and theoretical work, and analytical models and simulations.
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