Apatite-hosted REE mineralization in the Eastern Ghats Mobile Belt: A future prospect for REE

Mousumi Bhattacharjee, Kallola Kumar Behera, Smaranika Priyadarsini Swain
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Abstract

The growing need of rare earth elements in different sectors of the modern-day world has led to their increasing demand, which is in accordance with their limited supply. In such a scenario, investigations related to search for potential zones of rare earths have become the need of the hour. In one such investigation, undertaken by Geological Survey of India, the authors report profuse intrusion of the apatite veins into the syenite-pyroxenite suite in the eastern part of the Eastern Ghats Mobile Belt (EGMB) in Nayagarh area of eastern Odisha. These apatite veins are anomalously rich in REEs, particularly LREEs, which on average ranges between 37,000 to 53,000 ppm. Rare earths and apatite are generally directly proportional, where apatites tend to carry sufficient REE budget, depending on the phosphorous fugacity and other ambient conditions inducing their genesis. The major-oxide chemistry of apatite veins indicates that apatites in the study area can be divided into two types based on SiO2 wt.% and their inverse relationship with P2O5 and CaO wt.%. Mineral chemistry data shows overall SiO2 depletion, with dominance of CaO, followed by P2O5. Apatite veins, as per mineral chemistry, contain numerous veinlets (identified microscopically), where one type is REE-bearing and another type is REE-free. The REE-bearing phases are rich in Ce, Nd, La and Pr and are represented by allanite, monazite, and bastnaesite. Thorite and zircon are prevalent. Earlier instances of apatite intrusions into granulite have been reported from parts of south India. On the contrary, in this area, the intrusion is typically restricted to the younger intrusive units of the EGMB, represented by syenite-pyroxenite suite. The intrusives also show moderately high values of REEs. In this paper, an attempt has been made to characterize the apatite veins and the syenite-pyroxenite suite, they have intruded, in respect to their mineralogy and tectonics and to elucidate the potentiality of the area in terms of future REE exploration.

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东高止山脉移动带中的磷灰石赋存型 REE 矿化:REE 的未来前景
当今世界各行各业对稀土元素的需求与日俱增,导致对稀土元素的需求与日俱增,而稀土元素的供应却十分有限。在这种情况下,寻找稀土潜在区域的相关调查已成为当务之急。在印度地质调查局进行的一项此类调查中,作者报告称,在奥迪沙邦东部纳亚加尔地区的东高止山脉移动带(EGMB)东部,有大量磷灰石矿脉侵入到正长岩-辉长岩岩体中。这些磷灰石矿脉异常富含稀土,尤其是稀土元素,平均含量在 37,000 至 53,000 ppm 之间。稀土和磷灰石一般成正比,磷灰石往往携带足够的稀土元素,这取决于磷的富集度和诱发其形成的其他环境条件。磷灰石矿脉的主要氧化物化学成分表明,研究区域的磷灰石可根据二氧化硅重量百分比及其与五氧化二磷和氧化钙重量百分比的反比关系分为两种类型。矿物化学数据显示,二氧化硅总体枯竭,氧化钙占主导地位,其次是五氧化二磷。根据矿物化学数据,磷灰石矿脉包含许多细脉(显微镜下可识别),其中一类含稀土元素,另一类不含稀土元素。含稀土元素的矿相富含铈、钕、镧和镨,代表矿物有绿帘石、独居石和姥石。钍岩和锆石非常普遍。据报道,印度南部部分地区曾出现过磷灰石侵入花岗岩的情况。相反,在这一地区,侵入体通常仅限于以正长岩-辉绿岩岩组为代表的较年轻的特大型侵入体单元。这些侵入体也显示出中等偏高的 REEs 值。本文试图从矿物学和构造学的角度,描述磷灰石矿脉及其侵入的正长岩-辉长岩组的特征,并阐明该地区未来在稀土元素勘探方面的潜力。
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