Investigating nuisance dust complaints: Combining high frequency dust deposition records and source identification using integrated microanalytical techniques

Abstract

While ducted dust emissions from industry are usually well regulated and controlled, fugitive dust emissions can be difficult to quantify or differentiate from off-site emissions, particularly where fugitive emissions are transient or intermittent. In this study, sources of nuisance dust were investigated using a novel dust deposition sampling methodology, followed by chemical and mineralogical analysis using optical microscopy, x-ray diffraction (XRD), scanning electron microscopy with energy dispersive x-ray spectrometry (SEM-EDS), and isotope ratio mass spectrometry analysis. Dust deposition over 24 h was collected on horizontally orientated 300 mm square glass panels at 6 sites in the region of interest. This method captured very small (<10 mg) masses of dust and could distinguish very small variations in dust deposition at different sites and on different days. Comparison samples collected from potential dust sources at a nearby lime manufacturing facility, and other potential fugitive dust sources in the region were differentiated using XRD mineralogy, visual appearance by optical microscopy and SEM-EDS analysis of individual particles. Comparison of selected dust samples to reference samples indicated most dust deposition at the study sites consisted of soil or sand. However, dust deposition at two sites was sometimes composed of a material that was similar in composition to lime that had been rehydrated to portlandite, but not yet fully carbonated to calcite. Subsequent analysis of δ¹³C and δ¹⁸O for selected dust samples from these two sites were consistent with rapid and recent carbonation of small particles in an alkaline environment, which could have occurred during the atmospheric release and transport of lime, and ruled out fugitive dust emission from lime stockpiles existing on site. Combining the information obtained from high frequency record of dust deposition with targeted mineralogical, isotopic and morphological examinations provided new insight into the source of fugitive dust emissions in this area.