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Concurrent measurements of atmospheric Hg in outdoor and indoor at a megacity in Southeast Asia: First insights from the region 在东南亚一个特大城市同时测量室外和室内的大气汞含量:来自该地区的第一手资料
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-05 DOI: 10.1016/j.apr.2024.102326
Ly Sy Phu Nguyen , Le Quoc Hau , Thi Dieu Huong Pham , Nguyen Thi Thuy , To Thi Hien
Atmospheric mercury (Hg) is a critical indoor (ID) air pollutant and necessitates stringent monitoring. However, studies have primarily focused on Hg outdoors (OD) compared to ID, with no investigations conducted within the Southeast Asia (SEA) region. In this study, total gaseous Hg (TGM) concentrations and human exposure levels were investigated across various site characteristics in Ho Chi Minh City (HCMC), a megacity in SEA. The measured TGM concentrations for OD and ID were 5.12 ± 6.87 ng m−3 (1.20–48.7 ng m−3) and 34.5 ± 60.3 ng m−3 (1.26–271.9 ng m−3). The overall ID/OD ratio was 5.01 (0.77–9.3), signifying markedly elevated ID TGM concentrations. This ratio increases in the following order: shopping malls (1.50) < hospitals (3.21) < chemical laboratories (5.76) < households (11.7). Notably, sites associated with Hg incidents and the utilization of Hg-contained chemicals demonstrate notably high ID/OD levels, ranging from 8.0 to 40.1. The use of Hg-containing chemicals within the chemical laboratory serves as a significant contributor to heightened ID TGM levels. Non-combustion Hg sources, therefore, play an important role in inducing the ID TGM level. The hazard index (HQ) values observed for ID and OD were 0.1 and 0.01, respectively, indicating a negligible risk of exposure to TGM within the study area. However, HQ values recorded within laboratory environments employing Hg-associated chemicals and dental hospitals were 1–17 times greater compared to other sites. The present work provides new insight into the non-combustion ID source of TGM and was helpful for upcoming studies in exploring potential sources of TGM in megacities.
大气汞(Hg)是一种重要的室内(ID)空气污染物,需要进行严格监测。然而,与室内相比,研究主要集中于室外(OD)的汞含量,在东南亚(SEA)地区还没有进行过调查。本研究调查了东南亚特大城市胡志明市(HCMC)不同地点的总气态汞(TGM)浓度和人体接触水平。测得的 OD 和 ID 的 TGM 浓度分别为 5.12 ± 6.87 纳克 m-3 (1.20-48.7 纳克 m-3)和 34.5 ± 60.3 纳克 m-3(1.26-271.9 纳克 m-3)。总的 ID/OD 比率为 5.01(0.77-9.3),表明 ID TGM 浓度明显升高。该比率依次为:商场(1.50);医院(3.21);化学实验室(5.76);家庭(11.7)。值得注意的是,与汞事故和使用含汞化学品有关的场所的 ID/OD 水平明显较高,从 8.0 到 40.1 不等。在化学实验室中使用含汞化学品是导致 ID TGM 水平升高的重要原因。因此,非燃烧汞源在引起 ID TGM 水平方面起着重要作用。在 ID 和 OD 中观察到的危险指数(HQ)值分别为 0.1 和 0.01,表明在研究区域内接触 TGM 的风险可以忽略不计。不过,在使用与汞有关的化学品的实验室环境和牙科医院中记录的 HQ 值是其他地点的 1-17 倍。本研究工作为我们提供了有关三卤甲烷非燃烧 ID 来源的新见解,有助于今后探索特大城市中三卤甲烷潜在来源的研究。
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引用次数: 0
Investigating the role of photochemistry and impact of regional and local contributions on gaseous pollutant concentrations (NO, NO2, O3, CO, and SO2) at urban and suburban sites 调查光化学的作用以及区域和地方因素对城市和郊区气态污染物(一氧化氮、二氧化氮、臭氧、一氧化碳和二氧化硫)浓度的影响
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-28 DOI: 10.1016/j.apr.2024.102322
Sofia Eirini Chatoutsidou, Mihalis Lazaridis
Gaseous pollutant concentrations were monitored for one year in urban (NO, NO2, O3, CO, and SO2) and suburban (NO, NO2, and O3) sites. Common characteristics were identified at both sites, such as higher concentrations during typical winter months for all pollutants except O3. Increased NO, NO2, CO and SO2 concentrations during wintertime were linked to residential heating emissions, with pairwise correlations showing CO as marker for the study site. O3 production was lower in wintertime but higher in summertime at both sites based on its seasonal cycle and the impact of sunlight. Furthermore, diurnal variations showed that traffic emissions during rush hours most profoundly affected CO and NO. Nevertheless, NOx were characteristically higher at the urban site based on the burdened environment, whereas O3 was higher at the suburban site due to the lower destruction rates. O3 was the dominant oxidant at both sites, with a linear regression between OX and NOx revealing a negative relationship. This observation suggested a dominant regional contribution to oxidant concentrations. In addition, abnormally high O3 concentrations in relation to the season were reported for the first time at the study sites. Elevated concentrations were measured in parallel with Sahara dust events indicating noteworthy atmospheric conditions that require further assessment. Other O3 burdened periods were driven by regional transport of polluted plumes from the northeast. Lastly, nocturnal increases in O3 were observed and associated with enhanced vertical mixing.
对市区(NO、NO2、O3、CO 和 SO2)和郊区(NO、NO2 和 O3)的气态污染物浓度进行了为期一年的监测。在这两个地点都发现了共同的特征,例如在典型的冬季月份,除 O3 外,所有污染物的浓度都较高。冬季一氧化氮、二氧化氮、一氧化碳和二氧化硫浓度的增加与居民取暖排放物有关,成对相关性表明一氧化碳是研究地点的标记物。根据臭氧的季节周期和阳光的影响,两个研究地点的臭氧产生量在冬季较低,而在夏季较高。此外,昼夜变化表明,高峰时段的交通排放对一氧化碳和氮氧化物的影响最大。尽管如此,由于环境负担沉重,市区的氮氧化物明显较高,而郊区的臭氧由于破坏率较低而较高。O3 是这两个地点的主要氧化剂,OX 与 NOx 之间的线性回归显示出负相关关系。这一观察结果表明,氧化剂浓度主要来自区域。此外,研究地点首次报告了与季节相关的异常高浓度的臭氧。浓度升高与撒哈拉沙尘事件同时发生,表明大气条件值得注意,需要进一步评估。其他臭氧浓度较高的时段则是由来自东北部的区域污染羽流造成的。最后,观测到夜间臭氧浓度升高,这与垂直混合增强有关。
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引用次数: 0
Sensitivity of AERMOD (V21112) RLINEXT dispersion model outputs by source type to variability in single noise barrier height and separation distance 按声源类型划分的 AERMOD (V21112) RLINEXT 扩散模式输出结果对单一噪声屏障高度和间隔距离变化的敏感性
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-26 DOI: 10.1016/j.apr.2024.102318
Hongyu Lu , Daejin Kim , Haobing Liu , Tian Xia , William Reichard , Michael O. Rodgers , Randall Guensler
The U.S. Environmental Protection Agency (USEPA) introduced the RLINEXT modeling feature in the latest versions of AERMOD (since version v21112) to predict traffic-induced pollutant concentration when noise barriers are present. The research presented in this paper explores the impacts of noise barrier characteristics on AERMOD-predicted concentrations. The research finds that because AERMOD can currently only attach one barrier to each road side, and because that barrier only impacts the source to which it is attached, it is also important to split links so that they properly pair with barriers. Given the sensitivity of AERMOD-predicted concentrations to barrier characteristics (i.e., barrier heights and distances to roadway), the research also concludes that barriers must be appropriately matched with input links. This study investigated the sensitivity of CO concentration predicted by the latest AERMOD under various noise barrier conditions (barrier heights and distances between road and barrier) and meteorological conditions (wind directions and wind speeds). The results indicate that ground-level concentration of downwind receptors decreases with increased barrier heights, and that distant barriers have less of an impact on predicted concentrations. This study also explored the impact of noise barrier on both horizontal and vertical concentration profiles, indicating that concentrations rise behind the barrier as plumes are predicted to loft over the barrier. The sensitivity analysis associated with splitting roadway links to match with barriers indicated an impact on predicted concentration for certain receptors of up to 10%, but the overall the impact on maximum concentrations was marginal.
美国环境保护局 (USEPA) 在最新版本的 AERMOD(自 v21112 版起)中引入了 RLINEXT 建模功能,用于预测存在隔音屏障时交通引起的污染物浓度。本文介绍的研究探讨了隔音屏障特性对 AERMOD 预测浓度的影响。研究发现,由于 AERMOD 目前只能在每条路的一侧附加一个隔音屏障,而隔音屏障只对其附加的声源产生影响,因此还必须拆分链接,使其与隔音屏障正确配对。鉴于 AERMOD 预测浓度对障碍物特征(即障碍物高度和与道路的距离)的敏感性,研究还得出结论,障碍物必须与输入链接适当匹配。本研究调查了在各种噪声屏障条件(屏障高度和道路与屏障之间的距离)和气象条件(风向和风速)下,最新 AERMOD 预测的一氧化碳浓度的敏感性。结果表明,下风向受体的地面浓度随着隔音屏障高度的增加而降低,远处的隔音屏障对预测浓度的影响较小。这项研究还探讨了噪声屏障对水平和垂直浓度剖面的影响,结果表明,由于预测羽流会飘过屏障,因此屏障后面的浓度会升高。与分割道路连接以与隔声屏障相匹配相关的敏感性分析表明,对某些受体的预测浓度的影响高达 10%,但总体而言,对最大浓度的影响微乎其微。
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引用次数: 0
Carbonaceous aerosol emissions from secondary lighting sources: Emission factors and optical properties 二次照明光源的碳质气溶胶排放:排放系数和光学特性
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-23 DOI: 10.1016/j.apr.2024.102321
Chimurkar Navinya , Taveen Singh Kapoor , Gupta Anurag , Chandra Venkataraman , Harish C. Phuleria
India is shifting towards cleaner residential fuels, but this transition does not fully address household lighting challenges. Power disruptions, especially in rural areas, lead to the use of secondary lighting sources such as kerosene lamps, edible oil lamps, and candles. Our previous work identified kerosene wick and hurricane lamps as major secondary lighting sources in Indian households. This study presents the emission factors (EF) and optical properties of carbonaceous aerosols from five major secondary lighting devices in India, measured using a laboratory extractor hood system. Dominant secondary lighting devices, such as simple wick lamps (61.4 ± 9.8 g kg⁻1) and hurricane lamps (17.2 ± 4.8 g kg⁻1), exhibit higher elemental carbon (EC) EFs than typical residential biomass burning. Sesame oil lamps, primarily used in India during the Diwali festival, also have significant EC emission potential, with an EC EF of 71.6 ± 16.9 g kg⁻1. The low absorption Angstrom exponent (AAE) of ∼1 at near-UV wavelengths indicates a dominance of black carbon (BC) and negligible brown carbon absorption, corroborated by very low organic carbon concentrations. India-wide EC emissions (12.5 Gg year⁻1) from residential kerosene lighting show a higher (∼50%) contribution from eastern India. Additionally, the use of oil lamps during the Diwali festival could emit ∼3 Gg of EC in two days, with a potential reduction of ∼90% if wax-based lamps replace oil lamps. These measured EFs, aerosol optical properties, and estimated emissions will help future studies derive more accurate climate and health impacts from these otherwise overlooked lighting devices.
印度正在转向使用更清洁的民用燃料,但这一转变并没有完全解决家庭照明的挑战。电力中断,尤其是在农村地区,导致人们使用煤油灯、食用油灯和蜡烛等二次照明光源。我们之前的研究发现,煤油灯芯和飓风灯是印度家庭的主要二次照明光源。本研究利用实验室抽气橱系统测量了印度五种主要二次照明设备产生的碳质气溶胶的排放因子(EF)和光学特性。主要的二次照明设备,如简易灯芯灯(61.4 ± 9.8 g kg-1)和飓风灯(17.2 ± 4.8 g kg-1),显示出比典型的住宅生物质燃烧更高的碳元素(EC)排放系数。主要在印度排灯节期间使用的芝麻油灯也有很大的碳元素排放潜力,其碳元素 EF 为 71.6 ± 16.9 g kg-1。近紫外波长的吸收角指数(AAE)较低,为 1 ∼ 1,这表明黑碳(BC)占主导地位,褐碳的吸收可忽略不计,有机碳浓度很低也证实了这一点。全印度居民煤油照明产生的EC排放量(12.5千兆克/年-1)显示,印度东部的EC排放量较高(∼50%)。此外,排灯节期间使用油灯可在两天内排放 3 千兆克氨基甲酸乙酯。这些测量的EFs、气溶胶光学特性和估计的排放量将有助于未来的研究更准确地得出这些被忽视的照明设备对气候和健康的影响。
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引用次数: 0
Environmental risk estimation of potentially toxic metal(loid)s (PTMs) in fine particulate dust on the surface of children's playgrounds in parks 公园儿童游乐场表面微粒尘埃中潜在有毒金属(PTMs)的环境风险评估
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-22 DOI: 10.1016/j.apr.2024.102319
Tong Zhu , Xinwei Lu , Zhenze Wang , Sijia Deng , Yingsen Zhang , Kai Lei , Shigang Chao , Bo Yu , Yufan Yang
To determine the priority control factors for risk control and management of potentially toxic metal(loid)s (PTMs) in fine particulate dust (FPD) on the surface of children's playgrounds in parks, a comprehensive study was conducted on the pollution, risks, and sources of 12 PTMs in the FPD, taking Xi'an, China as a case. The pollution, ecological and health risks of PTMs were assessed using Nemerow integrated enrichment factor, modified Nemerow integrated eco–risk index, and health risk evaluation model, combined with Monte Carlo simulation. The sources of PTMs in the FPD were quantitatively apportioned using a positive matrix factorization model. Priority control factors for PTMs risk control and management were determined based on the results of source–oriented pollution and risk assessment. The results showed that the average contents (mg kg−1) of Cd (1.9), Cr (99.8), Cu (96.3), Hg (0.2), Pb (61.1), and Zn (239.4) in the FPD were considerably greater than local background values. The sources of PTMs in the FPD are industrial emission, coal combustion and medical activities, mixed source, and natural source, contributing 24.7%, 18.2%, 35.1%, and 22.1% to the total content of PTMs in the FPD, respectively. PTMs in the FPD posed a certain cancer risk to the elderly and children. Industrial emissions and mixed sources are priority control sources, while Cd and Cr are priority PTMs. It is recommended that local eco–environmental departments strengthen environmental monitoring of playgrounds, as well as management of industrial and transportation emissions, to ensure the health of residents.
为确定公园儿童游乐场所表面细颗粒物中潜在有毒金属(PTMs)风险控制与管理的优先控制因子,以中国西安为例,对公园儿童游乐场所表面细颗粒物中 12 种潜在有毒金属(PTMs)的污染、风险和来源进行了综合研究。采用内默罗综合富集因子、修正的内默罗综合生态风险指数和健康风险评价模型,结合蒙特卡罗模拟,对 PTMs 的污染、生态和健康风险进行了评估。采用正矩阵因式分解模型对 FPD 中的 PTMs 来源进行了定量分配。根据污染源导向和风险评估结果,确定了 PTMs 风险控制和管理的优先控制因子。结果表明,FPD 中镉 (1.9)、铬 (99.8)、铜 (96.3)、汞 (0.2)、铅 (61.1) 和锌 (239.4) 的平均含量(毫克/千克-1)大大高于当地背景值。在 FPD 中,PTMs 的来源包括工业排放、燃煤和医疗活动、混合来源和自然来源,分别占 FPD 中 PTMs 总含量的 24.7%、18.2%、35.1% 和 22.1%。FPD 中的 PTMs 对老人和儿童有一定的致癌风险。工业排放和混合源是优先控制源,而镉和铬则是优先控制的 PTMs。建议各地生态环境部门加强对游乐场所的环境监测,加强对工业和交通排放的管理,确保居民健康。
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引用次数: 0
Health risks of PM2.5-bound metals at a street canyon: Implication for traffic non-exhaust emissions 街道峡谷中 PM2.5 所含金属的健康风险:对交通废气排放的影响
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-21 DOI: 10.1016/j.apr.2024.102317
Zhangsen Dong , Minghao Yuan , Yifei Xu , Shanshan Wang , Shenbo Wang
Traffic non-exhaust emissions are a significant source of toxic metals in fine particular matter (PM2.5), and thus pose adverse effects on human health. PM2.5-bound metals were sampled at a street canyon and urban background site during ozone and haze periods in Zhengzhou. Higher metal concentrations were observed at the street canyon than at the urban background site, which was more affected by traffic non-exhaust, oil combustion, and dust emissions. Consequently, PM2.5-bound metals may cause significant non-carcinogenic and carcinogenic hazards to residents at the street canyon. Traffic non-exhaust and oil combustion were the primary contributors to the non-carcinogenic and carcinogenic risk at the street canyon, respectively. Furthermore, the severe health risk of PM2.5-bound metals from traffic non-exhaust emissions will remain for a long time at street canyons. This work reveals the health risks from vehicles at street canyons, which is beneficial for further reduction of traffic-related emissions.
交通非尾气排放是细微颗粒物(PM2.5)中有毒金属的重要来源,从而对人体健康造成不利影响。在郑州的臭氧和灰霾天气期间,对街道峡谷和城市背景点的 PM2.5 中的金属进行了采样。在街道峡谷观察到的金属浓度高于城市背景点,因为城市背景点受交通废气、石油燃烧和粉尘排放的影响更大。因此,PM2.5 中的金属可能会对街道峡谷的居民造成严重的非致癌和致癌危害。交通废气和石油燃烧分别是造成街道峡谷非致癌和致癌风险的主要因素。此外,交通非废气排放中的 PM2.5 结合金属对健康的严重危害将长期存在于街道峡谷。这项研究揭示了车辆对街道峡谷的健康风险,有利于进一步减少与交通有关的排放。
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引用次数: 0
Mining of dynamic traffic-meteorology-atmospheric pollutant association rules based on Eclat method 基于 Eclat 方法的动态交通-气象-大气污染物关联规则挖掘
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-19 DOI: 10.1016/j.apr.2024.102305
Yonghong Liu, Xinru Yang, Kui Liu, Rui Xu, Yuzhuang Pian, Shikun Liu
With the rapid increase of urban vehicles, the atmospheric compound pollutants, notably PM2.5 and O3, have significantly increased and seriously affected public health. Traffic and meteorological conditions are the primary influencing factors of pollutant concentrations, and their spatial and temporal changes affect the dispersion of pollutants. Increasing use of high-resolution big data offers opportunities to explore these correlations. More extensive quantitative studies are essential for effective air pollution control. This study presents an Eclat algorithm to quantitatively reveal the relationship between traffic, meteorology and pollutants with hourly and 5-minute scale data in the urban area of Guangzhou. We establish a research framework covering temporal pollution analysis, multifactor rule mining, and spatial effects. The results show that PM2.5 and O3 exhibit coordinated trends on the daily scale influenced by traffic flow and meteorology conditions, but on the hourly scale, they are negatively correlated. At the 5-minute scale, synchronized variations occur only during specific periods. This finer scale better identifies association rules for high-concentration pollutant scenarios, and non-roadside sites outperform roadside sites in mining these associations. For example, when humidity is below 37%, atmospheric pressure is 1016.2–1020.3 Pa, wind speed is 1.7–2.6 m/s, and the traffic volume on Jiefang North Road exceeds 635 vehicles every 5 min, there is a 92.86% probability that the PM2.5 concentration at GYQ (a non-roadside monitoring site) will exceed 127 μg/m3. These findings enhance our understanding of how dynamic traffic and meteorological conditions impact atmospheric pollutants and provide a scientific basis for regional collaborative pollution prevention.
随着城市车辆的迅速增加,大气复合污染物,特别是 PM2.5 和 O3 显著增加,严重影响了公众健康。交通和气象条件是污染物浓度的主要影响因素,它们的时空变化影响着污染物的扩散。越来越多地使用高分辨率大数据为探索这些相关性提供了机会。更广泛的定量研究对于有效控制空气污染至关重要。本研究提出了一种 Eclat 算法,利用广州城区每小时和 5 分钟尺度的数据,定量揭示交通、气象和污染物之间的关系。我们建立了一个涵盖时空污染分析、多因素规则挖掘和空间效应的研究框架。结果表明,受交通流量和气象条件的影响,PM2.5 和 O3 在日尺度上呈现出协调的变化趋势,但在小时尺度上,两者呈负相关。在 5 分钟尺度上,只有在特定时段才会出现同步变化。这种更精细的尺度能更好地识别高浓度污染物情景的关联规则,非路边站点在挖掘这些关联方面优于路边站点。例如,当湿度低于 37%、气压为 1016.2-1020.3 Pa、风速为 1.7-2.6 m/s、解放北路每 5 分钟车流量超过 635 辆车时,GYQ(非路边监测点)PM2.5 浓度超过 127 μg/m3 的概率为 92.86%。这些发现加深了我们对动态交通和气象条件如何影响大气污染物的理解,为区域协同污染防治提供了科学依据。
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引用次数: 0
Winter atmospheric deposition of trace elements in the Arkhangelsk region (NW Russia): Insights into environmental effects 阿尔汉格尔斯克地区(俄罗斯西北部)冬季大气中痕量元素的沉积:洞察环境影响
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-14 DOI: 10.1016/j.apr.2024.102310
Dina P. Starodymova , Ekaterina I. Kotova , Vladimir P. Shevchenko , Ksenia V. Titova , Olga N. Lukyanova

Atmospheric precipitation is an important indicator of ecological status. Snow cover accumulates all atmospheric precipitation that occurs during the cold season and releases large amounts of matter into surface water streams during spring snowmelt. We measured chemical composition of suspended solids (>0.45 μm) and dissolved matter (<0.45 μm) of atmospheric precipitation sampled on a monthly basis in 4 stations of Arkhangelsk region in cold seasons of 2018–2021. The fluxes of insoluble particles increase consistently in the spring months. In winter, the largest fluxes of suspended solids from the atmosphere were observed in the urbanized areas (in Severodvinsk and Onega). Snow in Onega showed a significant enrichment in Mn as well as Rb, Sr, Cs, Ba and Pb, which is related to boiler house emissions. Severodvinsk snow is enriched in V, Ni in dissolved fraction and Al, V, Cu, Sr, Pb in suspended solids. The environmental risk assessment shows that Onega station is affected to high and extremely polluted conditions for Mn concentration and Severodvinsk station is affected to multi-element pollution from moderate to significant levels. Comparison with the composition of the river runoff of the Northern Dvina showed that the concentrations of Cu, Zn, Cd and Pb in the snow are equal to or even higher than the river concentrations, indicating that atmospheric precipitation accumulated during winter can significantly affect the geochemistry of river runoff with respect to these elements.

大气降水量是生态状况的一个重要指标。积雪积聚了寒冷季节的所有大气降水,并在春季融雪时将大量物质释放到地表水溪流中。我们测量了 2018-2021 年寒冷季节阿尔汉格尔斯克州 4 个站点每月采样的大气降水中悬浮固体(>0.45 μm)和溶解物(<0.45 μm)的化学成分。不溶性颗粒物的通量在春季持续增加。冬季,在城市化地区(谢廖文斯克市和奥涅加市)观测到的大气悬浮固体通量最大。奥涅加的雪显示出锰、铷、锶、铯、钡和铅的明显富集,这与锅炉房的排放有关。塞维罗德文斯克的雪溶解部分富含钒和镍,悬浮固体中富含铝、钒、铜、锶和铅。环境风险评估结果表明,奥涅加站受到锰浓度高和极度污染的影响,而谢韦罗德文斯克站受到中度到严重程度的多元素污染的影响。与北德维纳河(Northern Dvina)河流径流成分的比较显示,雪中铜、锌、镉和铅的浓度与河流浓度相当,甚至更高,这表明冬季累积的大气降水会对河流径流中这些元素的地球化学产生重大影响。
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引用次数: 0
A correlation study of road dust pollutants, tire wear particles, air quality, and traffic conditions in the Seoul (South Korea) 首尔(韩国)道路尘埃污染物、轮胎磨损颗粒、空气质量和交通状况的相关性研究
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-13 DOI: 10.1016/j.apr.2024.102309
Hyeokjin Shin , Minseung Hyun , Sohee Jeong , Hyeonjung Ryu , Min Gyu Lee , Woosuk Chung , Jaehwan Hong , Jung-Taek Kwon , Jaewoong Lee , Younghun Kim
The interdependence of traffic dynamics and air quality on the concentrations of tire wear particles (TWP), heavy metals, and carbon black (CB) in road dust collected from 15 locations in Seoul, South Korea, was assessed. Pearson correlation, principal component analysis, and network analysis were employed to evaluate the correlations among traffic volume, vehicle speed, air quality parameters (PM10, PM2.5, NOx, and CO), and the concentrations of TWP (5934 to 16,253 mg/kg, average 9581 ± 4086 mg/kg), CB (371–22,287 mg/kg, average 4291 ± 6096 mg/kg), and heavy metals (Cr, Mn, Fe, Ni, Cu, Zn, As, Cd, and Pb) in road dust. The enrichment factors for heavy metals and the pollution index of TWP and CB were also calculated to evaluate the contribution of vehicle-derived particulate substances to road dust contamination. It was found that Cluster B, characterized by traffic-related variables such as traffic volume, vehicle speed, and heavy metals (Zn, Cd, and Pb), was significantly correlated with these pollutants, with correlation coefficients reaching up to 0.933. TWP was identified as a significant mediator in the increase of Zn, Pb, and Cd concentrations linked to traffic activities, contributing to pollution levels that were 2–16 times higher than the geochemical background. The presence of TWP and CB in road dust was identified as an indicator of contamination from traffic-related activities, highlighting the importance of Zn, Pb, and Cd as emerging pollutants that require targeted management strategies.
本研究评估了交通动态和空气质量对韩国首尔 15 个地点收集的道路尘埃中轮胎磨损颗粒(TWP)、重金属和炭黑(CB)浓度的相互依存关系。采用了皮尔逊相关分析、主成分分析和网络分析来评估交通量、车速、空气质量参数(PM10、PM2.5、氮氧化物和一氧化碳)与道路尘埃中轮胎磨损颗粒(5934-16253 毫克/千克,平均 9581 ± 4086 毫克/千克)、炭黑(371-22287 毫克/千克,平均 4291 ± 6096 毫克/千克)和重金属(铬、锰、铁、镍、铜、锌、砷、镉和铅)浓度之间的相关性。此外,还计算了重金属富集因子以及 TWP 和 CB 的污染指数,以评估车辆产生的颗粒物质对道路扬尘污染的贡献。研究发现,以交通量、车速和重金属(锌、镉和铅)等交通相关变量为特征的群组 B 与这些污染物显著相关,相关系数高达 0.933。在与交通活动相关的锌、铅和镉浓度增加过程中,三氟化硫被认为是一个重要的中介因素,导致污染水平比地球化学背景高出 2-16 倍。道路尘埃中 TWP 和 CB 的存在被确定为交通相关活动造成污染的指标,突出了锌、铅和镉作为新出现的污染物的重要性,需要有针对性的管理策略。
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引用次数: 0
Ambient air pollution and stroke risk among different accumulation patterns of comorbidities: Casual inference study based on marginal ‘between-within’ model 不同合并症累积模式下的环境空气污染与中风风险:基于边际 "两病之间 "模型的随机推理研究
IF 3.9 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-12 DOI: 10.1016/j.apr.2024.102308
Zemeng Zhao , Moning Guo , Peng Tan , Xue Tian , Yuhan Zhao , Lulu Liu , Lili Luo , Hui Luo , Xiaonan Wang , Xiangtong Liu , Xiuhua Guo , Jing Wei , Yanxia Luo
Previous studies showed that ambient air pollution is a risk factor for stroke. But its effects on patients with different comorbidity accumulation patterns and the causal relationship remain unclear. Hospitalization data were collected from the Beijing Municipal Health Commission Information Center. Pollutant data, including particulate matter (PM2.5, PM10, PM1, PM1-2.5), sulfur dioxide (SO2), nitrogen dioxide (NO2), carbon monoxide (CO), and ozone (O3) from 2014 to 2017, were obtained from the widely-used ChinaHighAirPollutants dataset. An individual-level case-crossover design was employed to identify case days and control days. The exposure-response association was estimated by fitting conditional logistic regression models. The newly proposed marginal ‘between-within’ models were used to estimate counterfactual hospitalization probability. In a total of 237 487 stroke patients, 211 741 diagnosed with ischemic stroke (IS) and 25 641 with hemorrhagic stroke (HS). Except for SO2, the seven pollutants were associated with higher risk of overall stroke and IS. Particulate matter showed larger estimated effects in patients with hypertension and diabetes but without hyperlipidemia. NO2 and CO showed larger estimated effects in patients with hypertension but without diabetes. O3 showed larger estimated effects in patients with hypertension, diabetes, and hyperlipidemia. PM1, PM10, NO2, and CO had statistically significant and persistent causal relationships with stroke risk during the lag periods. This study highlighted the need for targeted interventions of air pollution. Prioritizing control measures for PM1, PM10, NO2, and CO is particularly crucial in stroke prevention efforts.
以往的研究表明,环境空气污染是脑卒中的一个危险因素。但其对不同合并症累积模式的患者的影响及其因果关系仍不清楚。住院数据来自北京市卫计委信息中心。2014年至2017年的污染物数据,包括颗粒物(PM2.5、PM10、PM1、PM1-2.5)、二氧化硫(SO2)、二氧化氮(NO2)、一氧化碳(CO)和臭氧(O3),来自广泛使用的中国高空气污染物数据集。采用个体水平的病例交叉设计来确定病例日和对照日。通过拟合条件逻辑回归模型来估计暴露-反应关联。新提出的边际 "同内 "模型用于估算反事实住院概率。在 237 487 名中风患者中,211 741 人确诊为缺血性中风(IS),25 641 人确诊为出血性中风(HS)。除二氧化硫外,其他七种污染物都与总体中风和 IS 的较高风险有关。颗粒物对患有高血压和糖尿病但无高脂血症的患者的估计效应较大。二氧化氮和一氧化碳对患有高血压但没有糖尿病的患者有较大的估计效应。O3 对高血压、糖尿病和高脂血症患者的估计影响较大。在滞后期,PM1、PM10、二氧化氮和一氧化碳与中风风险的因果关系具有统计学意义且持续存在。这项研究强调了有针对性地干预空气污染的必要性。在预防中风的工作中,优先采取 PM1、PM10、NO2 和 CO 的控制措施尤为重要。
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Atmospheric Pollution Research
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