An efficient Urea-formaldehyde resin degradation method by hydrogen peroxide and malic acid: At three-mole ratios

IF 2.7 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Letters Pub Date : 2024-06-25 DOI:10.1016/j.matlet.2024.136895
Shenglong Zheng , Wei Wang , Huilian Huang , Wenzhen Zhao , Zhu Tian , Yuan Li , Yuchen He , Cong Mao , Xinlong Su , Chenyu Han , Hui Wan
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Abstract

Urea-formaldehyde (UF) resin has a high annual output, but the used and waste UF resin poses a challenge for recycling due to the difficulty in effectively decomposition them. In this study, A novel one-step degradation method was proposed, i.e., using eco-friendly malic acid and hydrogen peroxide to degrade cured UF resin residues using carboxylic acid through the hydrothermal oxidation method (HPMA), which was proved to have high cured UF resin degradation efficiency. This method will offer a new path for effectively recycling the UF resin out of service.

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过氧化氢和苹果酸高效降解脲醛树脂的方法:在三摩尔比
脲醛树脂(UF)的年产量很高,但由于难以有效分解,废旧 UF 树脂给回收利用带来了挑战。本研究提出了一种新型的一步降解法,即使用环保的苹果酸和过氧化氢,通过水热氧化法(HPMA)降解使用羧酸固化的 UF 树脂残留物,该方法被证明具有很高的固化 UF 树脂降解效率。这种方法将为有效回收停用的超滤树脂提供一条新途径。
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来源期刊
Materials Letters
Materials Letters 工程技术-材料科学:综合
CiteScore
5.60
自引率
3.30%
发文量
1948
审稿时长
50 days
期刊介绍: Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials. Contributions include, but are not limited to, a variety of topics such as: • Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors • Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart • Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction • Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots. • Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing. • Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic • Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive
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