Evaluating signal bleaching of Al and Ti–Li centers in fluvio-lacustrine sediments of Datong, North China, and its implications for the volcanic eruption chronology

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-06-21 DOI:10.1016/j.quageo.2024.101568
Hao Ji , Chun-Ru Liu , Wen-Peng Li , Chuan-Yi Wei , Bhupati Neupane , Gong-Ming Yin
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Abstract

Assessing the adequate bleaching of quartz Electron Spin Resonance (ESR) signals at the time of deposition is essential for sediment ESR dating. In this study, we focus on the Datong volcanic group is situated in Datong City, Shanxi Province, and is among the most renowned volcanic groups in China. The eruption within the Datong volcanoes during a geological period resulted in extensive high-temperature lava flow that directly overlaid Quaternary lacustrine deposits and subjected the underlying lacustrine layers to high-temperature heating. Thus, an investigation of the field profile in the Yujiazhai area, southeast of the Datong Volcanic Group, shows a novel approach for assessing the bleaching extent of ESR centers. This is accomplished by comparison of the DE values of the Al and the Ti–Li centers in partly-heated layer sample. The result reveals that quartz Al and Ti–Li centers in the lacustrine sediments appear to undergo sufficient bleached during transportation and natural bleaching processes in the study area. Furthermore, this study provides insight into the chronology of volcanic eruption in the Yujiazhai area, estimating an eruption age of approximately 300 ka. This volcanic activity most likely corresponds to the third volcanic activity period in the Datong region.

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华北大同流积-湖积沉积物中铝、钛-锂中心信号漂白评估及其对火山喷发年代学的影响
评估沉积时石英电子自旋共振(ESR)信号的漂白程度对于沉积物的 ESR 测定至关重要。大同火山群位于山西省大同市,是中国最著名的火山群之一。大同火山群在某一地质时期的喷发造成了大面积的高温熔岩流,直接覆盖了第四纪湖相沉积,并使下伏湖相地层受到高温加热。因此,对大同火山群东南部于家寨地区野外剖面的调查显示了一种评估 ESR 中心漂白程度的新方法。这种方法是通过比较部分加热层样品中铝和钛锂中心的 DE 值来实现的。结果表明,在研究区域的运输和自然漂白过程中,湖沼沉积物中的石英铝和钛锂中心似乎经历了充分的漂白。此外,本研究还对余家寨地区的火山喷发年代学进行了深入研究,推测其喷发年代约为 300 ka。这一火山活动很可能与大同地区的第三次火山活动期相吻合。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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