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Luminescence dating of rock surfaces in challenging environments: The case of MIS5e gravelly transgressive lag deposit (Southern Sardinia, West Mediterranean Sea) 挑战性环境中岩石表面的发光测年:MIS5e砾质横切滞积层(南撒丁岛,西地中海)
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-09-21 DOI: 10.1016/j.quageo.2024.101630
Determining the age of precise sea level markers such as marine terraces is often difficult because of the inherent limitation of traditional dating methods. A novel method based on Optical Stimulated Luminescence applicable to rock surfaces has been showing great promise in dating boulder and cobble surfaces from various environments. We performed Optically Stimulated Luminescence Rock Surface Dating (OSL RSD) on five cobbles from a basal transgressive lag deposit sealing a marine terrace referred to as the Last Interglacial (Marine Isotopic Stage 5e). We applied a consistent and highly selective 3-step acceptance criteria on five cobbles and obtained that only one was sufficiently well-bleached prior to burial. The resulting ages of 131 ± 8 ka and 127 ± 8 ka (obtained on 22 analyzed aliquots, n = 22) derived from the post-infrared infrared stimulated signal at 225oC (pIRIR225) and the preceding infrared stimulated signal at 50oC (pIR50/225), respectively, are consistent with each other as well as with the conventional luminescence age of ∼135 ka from the same sequence and with the U/Th age of ∼130 ka obtained from coral fragments. This work demonstrates that the RSD is a promising method for dating gravel veneer deposits overlaying marine terraces, enabling new chronologies for similar Quaternary deposits.
由于传统测年方法的固有局限性,确定诸如海洋阶地等精确海平面标志物的年龄往往十分困难。一种适用于岩石表面的基于光学激发发光的新方法在对各种环境中的巨石和卵石表面进行年代测定方面显示出了巨大的前景。我们对五块鹅卵石进行了光学刺激发光岩石表面定年(OSL RSD),这些鹅卵石来自封存最后一个间冰期(海洋同位素阶段 5e)海洋阶地的基底横切滞积层。我们对五块鹅卵石采用了一致的、高度选择性的三步验收标准,结果发现只有一块鹅卵石在埋藏前经过了充分漂白。从 225 摄氏度的后红外刺激信号(pIRIR225)和 50 摄氏度的前红外刺激信号(pIR50/225)得出的年龄分别为 131 ± 8 ka 和 127 ± 8 ka(根据 22 个分析等分样品得出,n = 22)、分别与同一序列的常规发光年龄 ∼135 ka 相一致,也与从珊瑚碎片中获得的 U/Th 年龄 ∼130 ka 相一致。这项工作表明,RSD 是对覆盖在海洋阶地上的砾石表层沉积物进行年代测定的一种很有前途的方法,可以为类似的第四纪沉积物提供新的年代学依据。
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引用次数: 0
Single grain K-feldspar MET-IRSL sediment transport determination: Bleaching patterns and rates 单粒 K 长石 MET-IRSL 沉积物运移测定:漂白模式和漂白率
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-09-19 DOI: 10.1016/j.quageo.2024.101626
This paper describes ways that Infra-Red Stimulated Luminescence (IRSL) signals from K-feldspar grains can be used to determine patterns and rates of sediment transport. In particular, it focusses on the potential provided by single grains to reveal their individual exposure and burial histories by the application of multiple elevated temperature (MET) IRSL measurements. We examine similarities and differences in bleaching behaviour with different light sources and introduce the concept of an equilibrium bleach. We present data on the variability of bleaching parameters for grains from single sediment samples, and discuss different analysis approaches to best determine individual grain histories. We describe a single grain “bleach recovery” experiment, and the application of a combined growth-bleach protocol designed to allow optimal data collection of both aspects of grain behaviour. We discuss the development of a burial-bleach model using numerical simulations based on direct observations of sample characteristics.
本文介绍了利用钾长石晶粒的红外激发发光(IRSL)信号来确定沉积物迁移模式和速率的方法。特别是,它侧重于通过应用多个高温(MET)IRSL 测量来揭示单个晶粒的暴露和埋藏历史。我们研究了不同光源下漂白行为的异同,并引入了平衡漂白的概念。我们提供了单个沉积物样本中漂白参数的变化数据,并讨论了不同的分析方法,以最好地确定单个谷物的历史。我们介绍了单个谷物的 "漂白恢复 "实验,以及生长-漂白组合方案的应用,该方案旨在对谷物行为的两个方面进行最佳数据收集。我们讨论了在直接观察样品特征的基础上,利用数值模拟开发埋藏-漂白模型的情况。
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引用次数: 0
Downstream change of luminescence sensitivity in sedimentary quartz and the rearrangement of optically stimulated luminescence (OSL) components along two large rivers 两条大河沿岸沉积石英发光灵敏度的下游变化和光激发发光(OSL)成分的重新排列
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-09-18 DOI: 10.1016/j.quageo.2024.101629
Recently, it has been proposed that the luminescence sensitivity of quartz grains, i.e. their luminescence response to unit dose, might be used for sediment fingerprinting. Sensitivity is determined both by the origin of quartz grains and the sedimentary processes they underwent. However, a more detailed understanding of the factors influencing sensitivity is essential in order to expand and specify the applicability of the parameter in sediment sourcing and geomorphological studies alike. In the present research, we examined the spatial changes of sensitivity parameters of coarse grain quartz in modern sediments of the largest rivers of the Carpathian Basin, Central Europe, to determine the role of source areas and transportation distance.
Based on the luminescence analysis of 39 samples, quartz extracts with a Carpathian origin (catchment of the Tisza River) have a significantly higher sensitivity, except the LM-OSL medium component, than those originating from the Alpine domain (catchment of the Danube River). No clear relationship could be identified between natural sensitisation and transportation distance. In terms of the Tisza the observed downstream increase of quartz sensitivity is due to high sensitivity quartz grains supplied by its tributaries. In the meantime, a recurring change was observed along the Danube, which can be attributed mostly to local erosional processes. Consequently, tributaries and erosion can overprint the potential downstream sensitisation of quartz grains in large rivers.
Meanwhile, in terms of the Danube on sections where a significant downstream increase was detected in LM-OSL fast component sensitivity, LM-OSL medium component sensitivity systematically decreased. Additionally, during laboratory sensitisation, the CW-OSL sensitivity of Danube samples increased considerably, whereas changes were more moderate in the case of Tisza samples. Moreover, in the case of Tisza-related quartz extracts, the 110 °C TL sensitivity and the LM-OSL fast and medium components showed a strong correlation, indicating the stability of luminescence processes (trapping and recombination). Whereas, in the case of the Danube both LM-OSL components show a weak correlation with the 110 °C TL intensity. All these indicate that Alpine-origin quartz grains are more susceptible to the rearrangement of electron traps and/or recombination centres, which can also be an indicator of sediment sources in Quaternary studies in the region.
最近有人提出,石英颗粒的发光灵敏度(即其对单位剂量的发光响应)可用于沉积物指纹识别。灵敏度由石英颗粒的来源及其经历的沉积过程决定。然而,为了扩大和明确该参数在沉积物来源和地貌研究中的适用性,必须更详细地了解影响灵敏度的因素。在本研究中,我们考察了中欧喀尔巴阡山盆地最大河流现代沉积物中粗粒石英灵敏度参数的空间变化,以确定来源地区和运输距离的作用。根据对 39 个样本的发光分析,除 LM-OSL 中分量外,喀尔巴阡山(蒂萨河流域)来源的石英提取物的灵敏度明显高于阿尔卑斯山(多瑙河流域)来源的石英提取物。自然敏感度与运输距离之间没有明确的关系。就蒂萨河而言,观察到的下游石英敏感性增加是由于其支流提供了高敏感性石英颗粒。与此同时,多瑙河沿岸出现了反复变化,这主要归因于当地的侵蚀过程。因此,支流和侵蚀可能会对大河中石英颗粒的潜在下游敏感性产生影响。同时,在多瑙河上检测到 LM-OSL 快速组分敏感性显著增加的下游河段,LM-OSL 中等组分敏感性则系统性地降低。此外,在实验室敏化过程中,多瑙河样本的 CW-OSL 灵敏度大幅提高,而蒂萨河样本的变化则较为温和。此外,在与 Tisza 相关的石英提取物中,110 °C TL 灵敏度与 LM-OSL 快速和中等成分显示出很强的相关性,表明发光过程(捕获和重组)的稳定性。而多瑙河的两个 LM-OSL 分量与 110 °C TL 强度的相关性较弱。所有这些都表明,源自阿尔卑斯山的石英颗粒更容易受到电子捕获器和/或重组中心重新排列的影响,这也可以作为该地区第四纪研究中沉积物来源的一个指标。
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引用次数: 0
CosmoChron: A versatile age-depth modeling approach using cosmogenic nuclides and direct age constraints CosmoChron:利用宇宙成因核素和直接年龄约束的多功能年龄深度建模方法
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-09-04 DOI: 10.1016/j.quageo.2024.101618

We introduce a novel age-depth modeling approach called CosmoChron that integrates both cosmogenic nuclide concentrations and other age constraints, such as radiocarbon and OSL ages, from different depths in a sedimentary sequence. Based on probabilistic inverse modeling, CosmoChron constrains the age-depth relationship of a sedimentary sequence along with associated uncertainties. Knowledge about the sample origins and the accumulation process is incorporated in the prior model. The 26Al/10Be ratio is computed at different depths in the forward model by accounting for different pre-burial scenarios, radioactive decay and post-burial production of 26Al-10Be, which is directly tied to the age-depth relation itself. Synthetic test cases demonstrate the method's ability to construct accurate age-depth relationships given by the posterior distribution, even for complex scenarios that include slow and varying accumulation rates, complex pre-burial histories, hiatuses, and unconformities. Based on observed unconformities, users have the option to manually input hiatuses into the model at specific depths, which allows estimation of their durations. Application of CosmoChron to real 26Al/10Be data from the Laujunmiao section in China yields ages that are similar to those obtained with conventional burial dating methods for specific stratigraphic layers. However, the associated uncertainties are significantly reduced with CosmoChron (by ∼47 % on average) because it exploits the vertical coupling of data combined with knowledge of the relative age of the samples, which must become younger towards the top of the profile. Additionally, the age-depth model reflets the duration of three hiatuses inferred from unconformities observed in the field. When CosmoChron is applied to OSL-derived ages from Jingbian section A on the Chinese Loess Plateau, covering the last ∼140 ka, the method produces results that are almost identical to those obtained with the well-established Bacon age-depth modeling approach. CosmoChron consequently offers a new, versatile and reliable tool to construct age-depth models for Quaternary sediment sequences.

我们介绍了一种名为 CosmoChron 的新型年龄-深度建模方法,该方法综合了沉积序列中不同深度的宇宙成因核素浓度和其他年龄约束,如放射性碳年龄和 OSL 年龄。CosmoChron 以概率反演模型为基础,对沉积序列的年龄-深度关系以及相关的不确定性进行约束。有关样品来源和堆积过程的知识被纳入先验模型。通过考虑不同的埋藏前情况、26Al-10Be 的放射性衰变和埋藏后生成,在前向模型中计算不同深度的 26Al/10Be 比率,这与年龄-深度关系本身直接相关。合成测试案例表明,该方法能够根据后验分布构建准确的年龄-深度关系,即使是在包括缓慢和变化的累积率、复杂的埋藏前历史、间断和不整合等复杂情况下也是如此。根据观测到的不整合现象,用户可以选择在特定深度手动将间断输入模型,从而估计其持续时间。将 CosmoChron 应用于中国刘军庙剖面的实际 26Al/10Be 数据,得到的年龄与特定地层的传统埋藏年代测定方法相似。然而,由于 CosmoChron 利用了数据的垂直耦合和样品相对年龄的知识,其相关的不确定性大大降低(平均降低 47%),而样品的相对年龄必须向剖面顶部变年轻。此外,年龄-深度模型还反推了根据实地观察到的不整合推断出的三个间断的持续时间。当将 CosmoChron 应用于中国黄土高原靖边 A 段的 OSL 年龄时,该方法得出的结果与培根年龄-深度模型方法得出的结果几乎相同。因此,CosmoChron 为构建第四纪沉积序列的年龄-深度模型提供了一种新的、多功能和可靠的工具。
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引用次数: 0
Integrating age modeling into a hierarchical Bayesian framework for inferring the pattern and rate of past sea-level changes from uncertainty-prone proxy data 将年龄建模纳入分层贝叶斯框架,从易受不确定性影响的代用数据中推断过去海平面变化的模式和速度
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-29 DOI: 10.1016/j.quageo.2024.101617

Inferring the pattern and rate of past sea-level changes from uncertainty-prone proxy records requires formal statistical analyses, preferably in a hierarchical framework. The commonly used error-in-variables method treats the relative sea level as a collection of random variables drawn from the multivariate Gaussian distribution. However, this method does not make any use of prior information about the sea-level index points as constraints in the inferential process, thereby leading to anomalously large uncertainties for the time periods when observational data are absent. Here, a hierarchical Bayesian model of past sea-level changes is presented. Specifically, the stochastically varying relative sea level is modeled as a piecewise linear process with an additive independent Brownian increment arriving in a Gaussian fashion. The treatment of temporal uncertainties associated with the sea-level index points in the partially observed proxy records also differs from the existing methods. Instead of calibrating the radiocarbon ages individually, the corresponding calendar ages are treated as random variables and inferred recursively according to their temporal order. Illustrative studies using synthetic and real-world data demonstrate the promise of this model.

从容易产生不确定性的代用记录中推断过去海平面变化的模式和速率,需要进行正式的统计分析,最好是在分层框架中进行。常用的变量误差法将相对海平面视为从多元高斯分布中抽取的随机变量集合。然而,这种方法在推论过程中没有利用海平面指数点的先验信息作为约束条件,因此导致在缺乏观测数据的时段出现异常大的不确定性。这里提出了一个过去海平面变化的分层贝叶斯模型。具体地说,随机变化的相对海平面被建模为一个以高斯方式到达的加性独立布朗增量的片断线性过程。对部分观测代用记录中与海平面指数点相关的时间不确定性的处理也与现有方法不同。不是单独校准放射性碳年龄,而是将相应的日历年龄视为随机变量,并根据其时间顺序递归推断。利用合成数据和实际数据进行的说明性研究证明了这一模型的前景。
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引用次数: 0
ESR chronology of the Quaternary sedimentary sequence of the Shinaimiao borehole in Hebi City, Henan Province, China 河南省鹤壁市石乃庙钻孔第四纪沉积序列的ESR年代学研究
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-26 DOI: 10.1016/j.quageo.2024.101616

It is very important to distinguish the strata of different periods in the Quaternary period, especially the Middle Pleistocene and Late Pleistocene strata, for stratigraphic division, depositional environmental analysis and climate evolution analysis. In this study, the Shinaimiao (SNM) borehole sequence in Hebi City, Henan Province (China) was established by both electron spin resonance (ESR) and magnetostratigraphy methods. Both Al (eighteen samples) and Ti-Li (eight out of the eighteen samples) centers were measured using the Multiple Aliquots Additive Dose (MAAD) method. In addition, hundreds of magnetostratigraphic samples were measured to determine the precise position of the Matuyama/Brunhes (M/B) boundary. The results show that: (1) The equivalent dose (DE) values of the Al and Ti-Li centers are consistent within the error range, demonstrating that the Multiple Center (MC) approach has worked. (2) The ESR dating results are consistent with the order of sedimentation (the ages get older with depths) and with magnetostratigraphic results of the B/M boundary within the error range, indicating that the ESR ages obtained from the Al and Ti-Li centers are reliable in this study. (3) By comprehensive analysis of the dating results and lithology characteristics, the stratigraphic ages of the SNM borehole with a depth of 126.93 m spans from Neogene to Holocene, but part of the early Pleistocene strata are missing.

区分第四纪不同时期的地层,尤其是中更新世和晚更新世地层,对于地层划分、沉积环境分析和气候演化分析具有十分重要的意义。本研究采用电子自旋共振(ESR)和磁地层学方法建立了河南省鹤壁市石乃庙钻孔序列。采用多样品加剂量(MAAD)法测量了铝中心(18 个样品)和钛锂中心(18 个样品中的 8 个)。此外,还测量了数百个磁地层样本,以确定松山/布鲁内斯(M/B)边界的精确位置。结果表明(1) 铝中心和钛-李中心的等效剂量(DE)值在误差范围内是一致的,表明多中心(MC)方法是有效的。(2) 在误差范围内,ESR 测年结果与沉积顺序一致(年龄随深度增加而变老),与 B/M 边界的磁地层学结果一致,表明本研究从 Al 和 Ti-Li 中心获得的 ESR 年龄是可靠的。(3)通过对测年结果和岩性特征的综合分析,126.93 m 深的 SNM 钻孔的地层年龄跨度为新近纪至全新世,但缺少部分早更新世地层。
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引用次数: 0
Validating ex210Pb sediment dating methods applied to a large anthropogenically-impacted river basin 验证适用于受人类活动影响的大型河流流域的外210Pb沉积物测年方法
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-24 DOI: 10.1016/j.quageo.2024.101615

Sediment dynamics in five sites within the Mobile River Basin, Alabama, impacted by (i) dam-and-lock use, (ii) urbanization, (iii) industrial/mining practices, (iv) flooding, and (v) storm surge events were evaluated to understand better anthropogenic impacts on regional sediment budgets. Three widely used sediment dating models based on excess 210Pb (ex210Pb) (i.e., Constant Rate of Supply, CRS, Constant Initial Concentration, CIC, and Advective Dispersion Equation, ADE) and two recently developed ones (i.e., Porosity Variation, PV and Porosity Variation Without Diffusion, PVWD) were tested to determine their applicability to these anthropogenically altered lacustrine and coastal areas. To verify results from ex210Pb models, we used conventional time markers, including regional hydrograph records and historical aerial images. We found that the traditionally used time-marker 137Cs is no longer useful due to its current low inventories in the sediments. Drainage-to-lake area ratios were used to determine relative runoff and atmospheric radionuclide contributions. Statistical analysis of physical properties such as porosity, bulk and dry density, water content, and sediment geochemical compositions were utilized to support sediment transport and site development hypotheses. When constructing the sediment history at each site using these proxies, we found that the CIC and ADE models produced unreliable ages because of violation of requirements for exponentially decreasing porosity and ex210Pb activity with depth. We found that two new models, PV and PVWD, that account for heterogeneous porosity, produced more reliable sediment depositional ages. These two models produced ages with lower uncertainties than the CRS model, outperforming the other conventional models tested. We conclude that the PV and PVWD models are more applicable for environments experiencing erosional and abrupt depositional events, which in our study resulted from dam construction and storm-surge events. Model sensitivity analysis showed that decreasing average particle density produces younger sediment ages by the PV and PVWD models. Higher ex210Pb activity analytical uncertainty resulted in lower sedimentation rates and higher estimated ages by all five models.

对阿拉巴马州莫比尔河流域内受以下因素影响的五个地点的沉积物动态进行了评估:(i) 水坝和水闸的使用;(ii) 城市化;(iii) 工业/采矿作业;(iv) 洪水;以及 (v) 风暴潮事件。对三种广泛使用的基于过量 210Pb(ex210Pb)的沉积物定年模型(即恒定供给率模型 CRS、恒定初始浓度模型 CIC 和平流扩散方程 ADE)和两种最新开发的模型(即孔隙度变化模型 PV 和无扩散孔隙度变化模型 PVWD)进行了测试,以确定它们是否适用于这些人为改变的湖泊和沿岸地区。为了验证外 210Pb 模型的结果,我们使用了传统的时间标记,包括区域水文记录和历史航空 图像。我们发现,由于目前 137Cs 在沉积物中的存量较低,传统使用的时间标记已不再有用。我们利用排水与湖泊面积之比来确定径流和大气中放射性核素的相对贡献。利用对物理特性(如孔隙度、体积密度和干密度、含水量以及沉积物地球化学成分)的统计分析来支持沉积物迁移和遗址开发假设。在利用这些代用指标构建每个地点的沉积物历史时,我们发现 CIC 和 ADE 模型产生的年龄不可靠,因为它们违反了孔隙度和 ex210Pb 活性随深度呈指数递减的要求。我们发现 PV 和 PVWD 这两个考虑了异质孔隙度的新模型产生了更可靠的沉积沉积年龄。与 CRS 模型相比,这两个模型产生的年龄的不确定性更低,优于所测试的其他传统模型。我们的结论是,PV 和 PVWD 模型更适用于经历侵蚀和突然沉积事件的环境,在我们的研究中,这些事件是由大坝建设和风暴潮事件造成的。模型敏感性分析表明,PV 和 PVWD 模型的平均颗粒密度越小,沉积物年龄越小。前 210Pb 活性分析不确定性越高,沉积速率越低,所有五个模型的估计年龄也越高。
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引用次数: 0
OSL and radiocarbon dating of core TBF-1 on the outer shelf of the East China Sea and implications for late Quaternary stratigraphic correlation 中国东海外陆架 TBF-1 号岩心的 OSL 和放射性碳年代测定及其对第四纪晚期地层相关性的影响
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-10 DOI: 10.1016/j.quageo.2024.101614

It is crucial to establish a robust chronology for understanding late Quaternary sedimentation processes and environment changes in response to sea-level fluctuation on shelves. The shelf of the East China Sea (ECS) is featured by huge terrigenous sediment input and striking land -sea interaction during the late Quaternary. However, there remains controversy in chronostratigraphic rebuilding of transgression and regression deposits during eustatic-glacial cycles, mainly due to a lack of reliable dating data. In this study, an extensive comparison of 17 optically stimulated luminescence (OSL) and 15 AMS 14C ages from core TBF-1 (upper 40 m) provides a constraint in chronostratigraphic reconstruction since Marine Isotope Stage (MIS) 5. OSL ages range from 9.5 ± 0.7 to 67.3 ± 4.8 ka at depths from 2.00 to 28.00 m, while 14C ages range from 6645 to 41435 cal a BP at depths from 0.02 to 17.52 m. Regression analysis demonstrates a high level of agreement between OSL and 14C ages, with r2 values of 0.91 and 0.90, respectively. For Holocene sediments (U1), both OSL and 14C methods are applicable in tidal sand ridges, however, it should be noted that 14C ages may exhibit a young bias of up to 3 ka. For pre-Holocene sediments (U6-U2), OSL ages are robust within saturation limitation of OSL signal (De up to ca. 166 Gy), cross-checked by feldspar post-IR IRSL (pIRIR) dating protocol. Nevertheless, the shell 14C ages (11620 and 10390 cal a BP at depths of 13.95–14.56 m) in Last Glacial Maximum (LGM) fluvial sediments of U2 are significantly underestimated, because of their susceptibility to recrystallization and overgrowth, resulting in carbon exchange with environment. While the peaty layer's14C age in deltaic deposition (17.50 m, U5) was determined to be 36420 cal a BP, coincided with OSL age of 39.6 ± 3.9 ka. The chronostratigraphy since MIS 5 for core TBF-1 exhibits a significant correlation with previously published cores SFK-1, DZQ4, and DH02, on the ECS outer shelf. Through the evaluation of those underestimated 14C ages and saturated OSL ages, we re-elucidated the primary sedimentary facies and their respective formation periods. This sedimentary stratigraphic illustration exhibits significant consistency with eustatic-glacial cycles. The renewed chronological framework for ECS shelf allows better correlation between the late Quaternary sedimentary evolution and the land-sea interaction on open shelves dominated by siliciclastic sedimentation.

为了解第四纪晚期沉积过程和陆架海平面波动引起的环境变化,建立可靠的年代学至关重要。中国东海陆架在第四纪晚期具有巨大的陆相沉积输入和显著的海陆相互作用特征。然而,由于缺乏可靠的测年数据,在对震旦纪-冰川期的横断沉积和回归沉积进行年代地层重建方面仍存在争议。本研究对 TBF-1(上部 40 米)岩心的 17 个光激发发光(OSL)年龄和 15 个 AMS 14C 年龄进行了广泛比较,为海洋同位素阶段(MIS)5 以来的年代地层重建提供了约束。回归分析表明,OSL 和 14C 年龄具有很高的一致性,r2 值分别为 0.91 和 0.90。对于全新世沉积物(U1),OSL 和 14C 方法都适用于潮汐沙脊,但需要注意的是,14C 年龄可能会出现长达 3 ka 的年轻偏差。对于全新世以前的沉积物(U6-U2),OSL 年龄在 OSL 信号饱和极限(De 高达约 166 Gy)范围内是可靠的,长石后红外 IRSL(pIR)测年规程对其进行了交叉检验。尽管如此,U2 的末次冰期(LGM)河流沉积物中贝壳的 14C 年龄(公元前 11620 年和公元前 10390 年,深度为 13.95-14.56 米)被严重低估,因为它们容易再结晶和过度生长,导致与环境进行碳交换。而三角洲沉积中泥炭层(17.50 米,U5)的 14C 年龄被测定为 36420 a BP,与 OSL 年龄 39.6 ± 3.9 ka 相吻合。TBF-1岩芯自MIS 5以来的年代地层与之前发表的位于ECS外大陆架的SFK-1、DZQ4和DH02岩芯具有显著的相关性。通过评估这些被低估的 14C 年龄和饱和 OSL 年龄,我们重新阐明了主要沉积层面及其各自的形成时期。这一沉积地层图示与震旦纪-冰川周期具有显著的一致性。更新的 ECS 陆架年代学框架使第四纪晚期沉积演化与硅质沉积为主的开放陆架上的海陆相互作用之间有了更好的关联。
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引用次数: 0
Quartz luminescence sensitivity enhanced by residence time in the critical zone 临界区停留时间提高了石英发光灵敏度
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-08 DOI: 10.1016/j.quageo.2024.101613

The emerging use of quartz luminescence properties to characterize Earth-surface processes shows promise, with optically stimulated luminescence (OSL) sensitivity proposed as a valuable tool for provenance or sediment history tracing. However, the geologic processes that lead to quartz sensitization remain unclear. Here we study the impact of source rock and surface processes on the luminescence properties of quartz sand from bedrock and modern and Late Pleistocene alluvium generated from a mountainous catchment in northern Utah, USA. Continuous wave and linear modulated OSL are used to characterize the luminescence sensitivity and intensity of the fast-decay component. We compare the OSL sensitivity with sand-grain provenance and with proxies for surface processes such as topographic metrics, cosmogenic 10Be-derived erosion rates, chemical weathering indices, and magnetic susceptibility. Late Pleistocene sediment has low OSL sensitivity and a weak fast-decay component, similar to bedrock samples from the source area. In contrast, modern alluvium is dominated by the fast-decay component and has higher and more variable OSL sensitivity, with no clear relationship to upstream bedrock source. There is, however, an inverse relationship between OSL sensitivity and catchment-averaged erosion rates and a positive relationship with chemical weathering indices and magnetic susceptibility. These metrics suggest that the modern alluvium has experienced increased residence time in the shallow critical zone compared to the Late Pleistocene sediments. We suggest that changes in hillslope processes between the effectively wetter, cooler Pleistocene and the dryer, warmer conditions of the Holocene enhanced the luminescence properties. The results suggest that climatic controls on rates and processes of chemical and mechanical weathering and sediment transport and residence within the critical zone are encoded in the luminescence properties of quartz sand.

新出现的利用石英发光特性来描述地球表面过程的方法前景广阔,其中光激发发光(OSL)灵敏度被认为是一种宝贵的原产地或沉积物历史追踪工具。然而,导致石英敏化的地质过程仍不清楚。在这里,我们研究了源岩和地表过程对来自美国犹他州北部山区集水区的基岩和现代及晚更新世冲积层石英砂发光特性的影响。我们使用连续波和线性调制 OSL 来描述快速衰变成分的发光灵敏度和强度。我们将 OSL 灵敏度与砂粒产地以及地表过程的代用指标(如地形指标、宇宙成因 10Be 衍生侵蚀速率、化学风化指数和磁感应强度)进行了比较。晚更新世沉积物的OSL灵敏度较低,快速衰变成分较弱,与源区的基岩样本相似。相比之下,现代冲积物以快速衰变成分为主,OSL 灵敏度较高且变化较大,与上游基岩源没有明显的关系。不过,OSL 灵敏度与流域平均侵蚀率之间存在反比关系,与化学风化指数和磁感应强度之间存在正比关系。这些指标表明,与晚更新世沉积物相比,现代冲积物在浅临界区的停留时间延长了。我们认为,在更湿润、更凉爽的更新世和更干燥、更温暖的全新世之间,山坡过程的变化增强了发光特性。研究结果表明,石英砂的发光特性反映了气候对化学和机械风化以及沉积物迁移和在临界区内停留的速率和过程的控制。
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引用次数: 0
Luminescence dating of the MIS 6 glaciation of the Pamir mountains (Central Asia) 帕米尔山脉(中亚)MIS 6 冰川作用的荧光年代测定
IF 1.7 2区 地球科学 Q3 GEOGRAPHY, PHYSICAL Pub Date : 2024-08-01 DOI: 10.1016/j.quageo.2024.101596

The Pamir Mountains are one of the highest mountain systems in the world; they act as sources of fresh water for the main rivers of Central Asia: the Amudaria and Syrdaria. Throughout the Quaternary, the Pamirs played a major role in controlling atmospheric circulation and land-surface processes, and provided great volumes of terrigenous sediments for transport by large rivers to the depressions in the Aral and Caspian regions. These ultimately provided broad aeolian cover in the sandy deserts, and finer dust for the widely distributed loess-palaeosol sequences. The glaciation history of this highly dynamic region provides an important basis for understanding climate change, sediment source and landscape evolution in Central Asia during the Quaternary. The question of the number, distribution, extent and timing of Pleistocene glaciations in the Pamir is debated. One of the main obstacles to research, together with difficulties of access and severity of current climate, is the varying degree of preservation of traces of previous glaciations in the western and eastern Pamir. As a result of a geological survey, we for the first time identified a thick lacustrine deposit at high altitudes in a tributary of the Panj – the valley of the Sary-Shitharv River – this records the damming of the Panj River valley by a large glacier. Luminescence measurements were undertaken to obtain the age of the Sary-Shitharv glacially-dammed lake. As often in mountain catchments the quartz OSL signal was unsuitable for dose estimation, and so the chronology of the Sary-Shitharv section is based entirely on post-IR IRSL signals from K-rich feldspar. We used pIRIR50,290 and pIRIR200,290 protocols and obtained indistinguishable ages from both protocols. Given the high sedimentation rates deduced from the structure of lacustrine deposits, the entire sequence must have been accumulated rather quickly, over a period of no more than a few thousand years. The average age over the whole series of dates is 165 ± 11 ka. This places the existence of the glacially-dammed lake at Sary-Shitharv in late MIS 6, a result that fits well with the general course of the glacial history of the Pamirs.

帕米尔山脉是世界上海拔最高的山系之一,是中亚主要河流阿姆河和锡尔河的淡水源头。在整个第四纪,帕米尔山脉在控制大气环流和地表过程方面发挥了重要作用,并为大河向咸海和里海地区的洼地运输提供了大量的土著沉积物。这些沉积物最终为沙质沙漠提供了广阔的风化层,并为广泛分布的黄土-古沉积层提供了更细的尘埃。这一高度动态地区的冰川历史为了解第四纪中亚地区的气候变化、沉积物来源和地貌演变提供了重要依据。关于帕米尔地区更新世冰川的数量、分布、范围和时间的问题存在争议。除了交通不便和当前气候的严酷性之外,研究的主要障碍之一是帕米尔西部和东部地区以往冰川的痕迹保存程度不一。通过地质调查,我们首次在潘杰河的一条支流--萨里-希塔尔夫河谷--的高海拔地区发现了厚厚的湖泊沉积物。为了确定 Sary-Shitharv 冰川堰塞湖的年龄,对其进行了发光测量。在山区集水区,石英 OSL 信号通常不适合剂量估算,因此 Sary-Shitharv 断面的年代学完全基于富含 K 的长石的后 IRSL 信号。我们使用了 pIR50,290 和 pIR200,290 两种方案,并从这两种方案中获得了无差别的年代。根据湖泊沉积的结构推断,沉积速率很高,因此整个序列的积累速度肯定很快,不会超过几千年。整个序列的平均年龄为 165 ± 11 ka。因此,萨里-希塔勒夫冰川堰塞湖出现的时间应在 MIS 6 晚期,这一结果与帕米尔冰川历史的总体进程十分吻合。
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引用次数: 0
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Quaternary Geochronology
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