Magnetic properties and magnetocaloric effect in the multiple rare-earth-containing MRE2Cu2In compounds

IF 4.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Intermetallics Pub Date : 2024-06-27 DOI:10.1016/j.intermet.2024.108393
Longfei Wang, Zhaoxing Wang, Shuo Li, Yikun Zhang
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Abstract

In this study, two Mo2FeB2-type multiple rare-earth-containing MRE2Cu2In (MRE = Dy1/3Ho1/3Er1/3 and Ho1/3Er1/3Tm1/3; space group P4/mbm, No. 127) compounds are prepared via arc-melting method and systematically determined regarding their structural and magnetic properties, magnetic phase transition (MPT), and magnetocaloric (MC) performances. They undergo typical second-order MPT at low temperatures. The MC effect and MC performances of the present MRE2Cu2In compounds at low temperatures are assessed using magnetic entropy changes, refrigerant capacity, and temperature-averaged entropy changes. The values of these parameters are comparable to most updated candidate materials for low-temperature magnetic cooling, making the present MRE2Cu2In compounds considerable for practical applications.

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多种含稀土的 MRE2Cu2In 化合物的磁性能和磁致效应
本研究通过电弧熔融法制备了两种 Mo2FeB2- 型含多重稀土的 MRE2Cu2In(MRE = Dy1/3Ho1/3Er1/3 和 Ho1/3Er1/3Tm1/3;空间群 P4/mbm,编号 127)化合物,并系统测定了它们的结构和磁性能、磁相变(MPT)和磁致性(MC)性能。它们在低温下经历了典型的二阶 MPT。利用磁熵变、制冷剂容量和温度平均熵变评估了本 MRE2Cu2In 复合物在低温下的 MC 效应和 MC 性能。这些参数的值与大多数最新的低温磁制冷候选材料相当,使本 MRE2Cu2In 复合物在实际应用中具有可观的价值。
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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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