Spin coating on a budget: A 3D-Printed all-mechanical alternative for cost-effective thin-film deposition

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-06-25 DOI:10.1016/j.ohx.2024.e00547
Apostolos Kalafatis , Lazaros Theofylaktos , Thomas Stergiopoulos
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Abstract

Spin coating stands out as the most employed thin-film deposition technique across a variety of scientific fields. Particularly in the past two decades, spin coaters have become increasingly popular due to the emergence of solution-processed semiconductors such as quantum dots and perovskites. However, acquiring commercial spin coaters from reputable suppliers remains a significant financial burden for many laboratories, particularly for smaller research or educational facilities. Prompted by the simple mechanical principles of the device, in this work, we present a 3D-printed analogue that can be printed and assembled in under 10 h and costs less than 5 euros per device. The operating principle is fully mechanical since the rotating motion is induced by gas flow. It does not require any additional components such as DC motors, motor drivers, circuitry or software and thus it can be fully operational off the grid. Additionally, the gas flow generates a purging effect that was found to be rather advantageous for film formation. To prove the effectiveness of this device, we have employed it to fabricate planar thin-film antimony sulfide (Sb2S3) solar cells. The optoelectronic characteristics of solar cells revealed noteworthy improvements, particularly in terms of repeatability, when compared to those fabricated with a commercial spin coater.

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低成本旋转镀膜:用于经济高效薄膜沉积的三维打印全机械替代方案
自旋镀膜是各种科学领域最常用的薄膜沉积技术。特别是在过去的二十年里,由于量子点和过氧化物等溶液加工半导体的出现,旋涂仪变得越来越受欢迎。然而,对于许多实验室,尤其是规模较小的研究或教育机构来说,从知名供应商处购买商用自旋镀膜机仍然是一项沉重的经济负担。受该装置简单机械原理的启发,我们在这项工作中提出了一种三维打印的类似装置,可在 10 小时内完成打印和组装,每个装置的成本不到 5 欧元。由于旋转运动是由气体流动引起的,因此其工作原理完全是机械式的。它不需要直流电机、电机驱动器、电路或软件等任何额外组件,因此可以完全脱离电网运行。此外,气流还能产生净化效果,这对薄膜的形成非常有利。为了证明这种装置的有效性,我们利用它制造了平面薄膜硫化锑(Sb2S3)太阳能电池。与使用商用旋涂机制造的太阳能电池相比,太阳能电池的光电特性有了显著改善,特别是在可重复性方面。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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