Micromechanical properties of coals and the response to changes in nanocarbon structure

IF 6.7 1区 工程技术 Q2 ENERGY & FUELS Fuel Pub Date : 2024-07-02 DOI:10.1016/j.fuel.2024.132321
Hao Wang , Jianhua Xiang , Xiaopeng Deng , Wenxuan Gao , Xiaoqi Duan
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Abstract

The micromechanical properties of coals are key parameters affecting the development of coalbed methane (CBM). In order to understand the relationship between the micromechanical properties and the nanocarbon structure of coals, high resolution transmission electron microscopy (HRTEM) and nanoindentation were used to investigate the micromechanical properties of vitrinite in different coals and the response to changes in nanocarbon structure. Coals with higher coal rank have greater elastic modulus and hardness. The end-of-loading displacement and creep displacement decrease with the increase of coal rank, both of which have a good negative correlation with the elastic modulus and hardness. Fringe length, degree of orientation, proportion of straight fringes, and proportion of stacks all increase with increasing coal rank. The curvature of the fringes decreases with increasing coal rank. The variation of the nanocarbon structure has an important effect on the micromechanical properties. The nanocarbon structure parameters of fringe length, proportion of straight fringes, degree of orientation, and proportion of stacks have good linear relationships with the micromechanical parameters of elastic modulus and hardness. In addition, this study analyzes the effect of the micromechanical properties of coal on the effectiveness of the proppant. Therefore, the evolution of the nanocarbon structure should be emphasized in future studies on the micromechanical properties of coal.

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煤炭的微机械特性以及对纳米碳结构变化的响应
煤炭的微观力学性能是影响煤层气开发的关键参数。为了了解煤炭的微观力学性能与纳米碳结构之间的关系,研究人员采用高分辨透射电子显微镜(HRTEM)和纳米压痕法研究了不同煤炭中矾石的微观力学性能以及纳米碳结构变化的响应。煤的等级越高,弹性模量和硬度越大。加载末位移和蠕变位移随煤炭等级的增加而减小,两者与弹性模量和硬度呈良好的负相关。随着煤炭等级的增加,流纹长度、定向程度、直流纹比例和堆叠比例都会增加。随着煤炭等级的增加,流纹的曲率也会减小。纳米碳结构的变化对微机械性能有重要影响。纳米碳结构参数(流苏长度、直流苏比例、取向度和堆积比例)与微观力学参数(弹性模量和硬度)具有良好的线性关系。此外,本研究还分析了煤的微观力学性能对支撑剂有效性的影响。因此,在今后对煤的微观力学性能进行研究时,应重视纳米碳结构的演变。
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来源期刊
Fuel
Fuel 工程技术-工程:化工
CiteScore
12.80
自引率
20.30%
发文量
3506
审稿时长
64 days
期刊介绍: The exploration of energy sources remains a critical matter of study. For the past nine decades, fuel has consistently held the forefront in primary research efforts within the field of energy science. This area of investigation encompasses a wide range of subjects, with a particular emphasis on emerging concerns like environmental factors and pollution.
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