Nickel sulfide and potato-peel-derived carbon spheres composite for high-performance asymmetric supercapacitor electrodes

Energy Storage Pub Date : 2024-06-25 DOI:10.1002/est2.660
Mahima Sheoran, Rohit Sharma, Anit Dawar, Sunil Ojha, Anurag Srivastav, R K Sharma, Om Prakash Sinha
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Abstract

In the present work, a novel composite of nickel sulfide (NiS) and potato peel-derived carbon spheres (NiS/PPCS) with higher specific capacitance and cyclic performance was synthesized as electrode material for supercapacitor applications. The composite was deposited on a graphite rod to be use as an electrode. The electrochemical performance studies using CV, GCD, and EIS revealed that the prepared electrode showed an improved current response and higher specific capacitance than the pristine NiS electrode. The maximum specific capacitance for the NiS/PPCS electrode was found to be 2185 F/g at 0.2 A/g current density. More precisely, it was observed that the NiS/PPCS composite exhibited an excellent retention capacity of 95.04% after 20 000 continuous charge-discharge cycles, showing its exceptional cyclic performance. The impedance studies revealed that the reaction between the NiS/PPCS electrode and electrolyte was rapid and highly reversible. Based on the findings of the electrochemical performances, NiS/PPCS electrode appears to be a potential candidate for highly efficient and economical asymmetric supercapacitors.

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用于高性能不对称超级电容器电极的硫化镍和马铃薯皮衍生碳球复合材料
本研究合成了一种硫化镍(NiS)和马铃薯皮衍生碳球(NiS/PPCS)的新型复合材料,作为超级电容器应用的电极材料,具有更高的比电容和循环性能。复合材料沉积在石墨棒上用作电极。使用 CV、GCD 和 EIS 进行的电化学性能研究表明,与原始 NiS 电极相比,制备的电极显示出更好的电流响应和更高的比电容。在 0.2 A/g 的电流密度下,NiS/PPCS 电极的最大比电容为 2185 F/g。更确切地说,经过 20,000 次连续充放电循环后,NiS/PPCS 复合材料显示出 95.04% 的出色电容量保持率,显示出其卓越的循环性能。阻抗研究表明,NiS/PPCS 电极与电解液之间的反应迅速且高度可逆。根据电化学性能的研究结果,NiS/PPCS 电极似乎是高效、经济的不对称超级电容器的潜在候选材料。
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