Yoon Jun Kim, Trung Dinh Hoang, Su Cheol Han, Joo An Bang, Ho Won Kang, Jaehyun Kim, Heetaek Park, Jun-Ho Park, Jun-Woo Park, Gumjae Park, You-Jin Lee, Doohun Kim, Seung-Wook Eom, Jeong-Hee Choi, Seoung-Ki Lee, Janghyuk Moon, Yoon-Cheol Ha, Byung Gon Kim
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引用次数: 0
Abstract
All-solid-state batteries (ASSBs) have attracted considerable attention due to their high stability, offering a safer alternative to currently used batteries. Extensive research has been conducted to improve cathode part performance. However, the conventional hand mixing (HM) process results in inhomogeneous particle distribution, causing poor interparticle contact due to uneven stress distribution, and the solution process causes unwanted solid electrolyte (SE) deterioration when using a polar solvent although it ensures uniform SE distribution. To overcome these limitations, based on the design rule considering SE surface coverage of less than 100 %, we propose a cathode/SE composite, showing decent ionic/electronic conductivities, uniform SE distribution, and intimate interparticle contact, achievable through a mass-producible mechanical mixing (MM) process. Unlike the HM cell, the MM cell forms well-defined ionic percolating pathways and shows excellent structural stability. Consequently, the MM cell exhibits improved capacity retention during 1000 cycles and stable cyclability even under the harsh condition of 7 wt% SE. Finite element analysis theoretically demonstrates that uniform electrode and electrolyte currents are responsible for the improved performances including increased cathode utilization efficiency and reduced overpotentials. This study reveals the importance of composite design and uniform SE distribution in developing high-performance ASSBs at a practical cell level.
期刊介绍:
Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field.
Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy.
Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.