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Exfoliated Coal-Derived Hard Carbon Enabling the Trade-Off between Plateau Capacity and Fast Na+ Kinetics for Sodium-Ion Batteries 剥离煤衍生硬碳实现了钠离子电池平台容量和快速Na+动力学之间的权衡
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-09 DOI: 10.1016/j.ensm.2026.104974
Gaoxu Han, Shengle Hao, Yuxin Shi, Wei Lv, Ruitao Lv, Wanci Shen, Feiyu Kang, Deping Xu, Zheng-Hong Huang
Coal is an attractive precursor for hard carbon anodes in sodium-ion batteries. However, these carbons often face the challenge of achieving high capacity and fast Na⁺ kinetics simultaneously. Herein, we propose an oxidized-coal precursor-derived hard carbon that exhibits a sheet-like structure and a tunable interlayer spacing, which addresses the aforementioned problem. A H2O2/H2SO4 chemical oxidation-exfoliation produces an oxidized-coal precursor with nanosheet morphology enriched in -COOH/-OH groups. These functional groups induce premature crosslinking of organic macromolecules, constructing a turbostratic carbon framework that suppresses ordered layer growth and expands the interlayer spacing. As the carbonization temperature further increases, polycondensation and structural reorganization are enhanced, driving more compact stacking of carbon layers. This enables a controllable decrease in interlayer spacing accompanied by the evolution of closed pores. The result small microcrystallite size with expanded interlayer spacing reduces Na⁺ intercalation/diffusion resistance. The optimized sample exhibits a capacity of 327 mAh g-1, including a high plateau capacity of 191 mAh g-1. Note that the capacity of 214 mAh g-1 at an ultra-high current density of 10 A g-1 is retained, much higher than the previous reports. This work provides a new insight into the preparation of high-power, high-energy coal-based hard carbon for advanced sodium ion batteries.
{"title":"Exfoliated Coal-Derived Hard Carbon Enabling the Trade-Off between Plateau Capacity and Fast Na+ Kinetics for Sodium-Ion Batteries","authors":"Gaoxu Han, Shengle Hao, Yuxin Shi, Wei Lv, Ruitao Lv, Wanci Shen, Feiyu Kang, Deping Xu, Zheng-Hong Huang","doi":"10.1016/j.ensm.2026.104974","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104974","url":null,"abstract":"Coal is an attractive precursor for hard carbon anodes in sodium-ion batteries. However, these carbons often face the challenge of achieving high capacity and fast Na⁺ kinetics simultaneously. Herein, we propose an oxidized-coal precursor-derived hard carbon that exhibits a sheet-like structure and a tunable interlayer spacing, which addresses the aforementioned problem. A H<sub>2</sub>O<sub>2</sub>/H<sub>2</sub>SO<sub>4</sub> chemical oxidation-exfoliation produces an oxidized-coal precursor with nanosheet morphology enriched in -COOH/-OH groups. These functional groups induce premature crosslinking of organic macromolecules, constructing a turbostratic carbon framework that suppresses ordered layer growth and expands the interlayer spacing. As the carbonization temperature further increases, polycondensation and structural reorganization are enhanced, driving more compact stacking of carbon layers. This enables a controllable decrease in interlayer spacing accompanied by the evolution of closed pores. The result small microcrystallite size with expanded interlayer spacing reduces Na⁺ intercalation/diffusion resistance. The optimized sample exhibits a capacity of 327 mAh g<sup>-1</sup>, including a high plateau capacity of 191 mAh g<sup>-1</sup>. Note that the capacity of 214 mAh g<sup>-1</sup> at an ultra-high current density of 10 A g<sup>-1</sup> is retained, much higher than the previous reports. This work provides a new insight into the preparation of high-power, high-energy coal-based hard carbon for advanced sodium ion batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"244 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146138861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Siloxane Electrolyte Molecular Design for Lithium-Sulfur Batteries 锂硫电池硅氧烷电解质分子设计
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-07 DOI: 10.1016/j.ensm.2026.104970
Chong Xu, Gong Cheng, Shuang Liu, Guang Ma, Dongyuan Zhang, Junjie Fu, Ye Wang, Zhengkun Xie, Weihua Chen, Yongfeng Li
Lithium-sulfur (Li-S) batteries with sulfurized polyacrylonitrile (SPAN) cathodes hold promises for high energy density but face critical challenges in conventional ether/ester electrolytes, including polysulfide dissolution, shuttle effects and incompatibility with lithium metal anodes. To address these issues, a systematic siloxane electrolyte screening strategy serves as the core of this work. Here, we propose a siloxane-based localized high-concentration electrolyte (4M LiFSI PTTS/TTE (7:3 by volume), PT73) to address these issues. By leveraging the unique d-p orbital conjugation of siloxanes and tailored steric hindrance from propyl terminal groups, PT73 weakens Li⁺-solvent coordination while promoting anion-dominated solvation structures, thereby forming a robust inorganic-rich SEI and suppressing polysulfide dissolution. Electrochemically, Li||Cu cells with PT73 achieve 98.7% average Coulombic efficiency (CE) and retain 98.2% CE over 720 cycles. Li-SPAN full cells (4.4 mg cm-2 sulfur loading) maintain 91.1% capacity retention after 120 cycles. This screening paradigm provides a rational framework for siloxane electrolyte design, accelerating high-energy-density Li-S battery development.
{"title":"Siloxane Electrolyte Molecular Design for Lithium-Sulfur Batteries","authors":"Chong Xu, Gong Cheng, Shuang Liu, Guang Ma, Dongyuan Zhang, Junjie Fu, Ye Wang, Zhengkun Xie, Weihua Chen, Yongfeng Li","doi":"10.1016/j.ensm.2026.104970","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104970","url":null,"abstract":"Lithium-sulfur (Li-S) batteries with sulfurized polyacrylonitrile (SPAN) cathodes hold promises for high energy density but face critical challenges in conventional ether/ester electrolytes, including polysulfide dissolution, shuttle effects and incompatibility with lithium metal anodes. To address these issues, a systematic siloxane electrolyte screening strategy serves as the core of this work. Here, we propose a siloxane-based localized high-concentration electrolyte (4M LiFSI PTTS/TTE (7:3 by volume), PT73) to address these issues. By leveraging the unique <em>d-p</em> orbital conjugation of siloxanes and tailored steric hindrance from propyl terminal groups, PT73 weakens Li⁺-solvent coordination while promoting anion-dominated solvation structures, thereby forming a robust inorganic-rich SEI and suppressing polysulfide dissolution. Electrochemically, Li||Cu cells with PT73 achieve 98.7% average Coulombic efficiency (CE) and retain 98.2% CE over 720 cycles. Li-SPAN full cells (4.4 mg cm<sup>-2</sup> sulfur loading) maintain 91.1% capacity retention after 120 cycles. This screening paradigm provides a rational framework for siloxane electrolyte design, accelerating high-energy-density Li-S battery development.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"1 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interpretable enhanced-ECFP-guided deep learning for rational electrolyte design and Coulombic efficiency prediction in lithium metal batteries 可解释的增强ecfp引导深度学习用于锂金属电池的合理电解质设计和库仑效率预测
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-07 DOI: 10.1016/j.ensm.2026.104972
Doo Bong Lee, Jinwoo Park, Eunji Kim, Woong Kim
{"title":"Interpretable enhanced-ECFP-guided deep learning for rational electrolyte design and Coulombic efficiency prediction in lithium metal batteries","authors":"Doo Bong Lee, Jinwoo Park, Eunji Kim, Woong Kim","doi":"10.1016/j.ensm.2026.104972","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104972","url":null,"abstract":"","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"2 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Leaching Capacity and Industrial Scale for Critical Metals Recovery from Spent Lithium-ion Batteries via H2O-Temperature Regulation Method 水温调节法提高废锂离子电池中关键金属的浸出能力和工业规模
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-07 DOI: 10.1016/j.ensm.2026.104971
Libin Tang, Juanjian Ru, Mingqiang Cheng, Zhipeng Zhou, Yixin Hua, Ding Wang
{"title":"Enhanced Leaching Capacity and Industrial Scale for Critical Metals Recovery from Spent Lithium-ion Batteries via H2O-Temperature Regulation Method","authors":"Libin Tang, Juanjian Ru, Mingqiang Cheng, Zhipeng Zhou, Yixin Hua, Ding Wang","doi":"10.1016/j.ensm.2026.104971","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104971","url":null,"abstract":"","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"6 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen Bond Network Induced Interfacial Dipoles Enhance Built-in Electric Fields and Ion Transport in Vanadium Oxide Heterostructures 氢键网络诱导界面偶极子增强氧化钒异质结构内建电场和离子输运
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-05 DOI: 10.1016/j.ensm.2026.104969
Shuai Zhang, Zixuan Gao, Dongdong Zhang, Kittima Lolupiman, Wanwisa Limphirat, Xiang Wu, Jiaqian Qin, Jin Cao
Vanadium-based oxides are among the most promising cathodes for aqueous zinc-ion batteries (AZIBs), yet their practical deployment is hindered by severe vanadium dissolution and inefficient interfacial charge/ion transport. Herein, L-tartaric acid (L-TA) is made to self-assemble on a preconstructed V2O5/V3O7·H2O (V2V3) heterointerface, forming a hydrogen bond interfacial layer (HB-V2V3). The hydrogen-bond network reinforces interfacial cohesion and induces oriented dipoles, which cooperate with the heterojunction’s built-in electric field to enhance electronic coupling and accelerate Zn2+ transport. Meanwhile, the strengthened V-O interactions and regulated interfacial hydration environment effectively suppress vanadium dissolution and preserve lattice integrity. Functioning as a noninvasive and compliant molecular “sheath”, it regulates the local chemical environment while preserving the host lattice. As a result, HB-V2V3 delivers a reversible capacity of 464.53 mAh g-1 at 0.1 A g-1 within 0.2-1.6 V and exhibits outstanding durability, retaining 95.5% after 500 cycles at 2.0 A g-1 and 93.1% after 2200 cycles at 5.0 A g-1. It also maintains approximately 81% of its capacity after 300 cycles at 1 A g-1 in a pouch-cell configuration. These results establish hydrogen-bond-driven interfacial modulation as an effective and broadly applicable route to stabilize vanadium cathodes and enhance the performance of AZIBs.
{"title":"Hydrogen Bond Network Induced Interfacial Dipoles Enhance Built-in Electric Fields and Ion Transport in Vanadium Oxide Heterostructures","authors":"Shuai Zhang, Zixuan Gao, Dongdong Zhang, Kittima Lolupiman, Wanwisa Limphirat, Xiang Wu, Jiaqian Qin, Jin Cao","doi":"10.1016/j.ensm.2026.104969","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104969","url":null,"abstract":"Vanadium-based oxides are among the most promising cathodes for aqueous zinc-ion batteries (AZIBs), yet their practical deployment is hindered by severe vanadium dissolution and inefficient interfacial charge/ion transport. Herein, L-tartaric acid (L-TA) is made to self-assemble on a preconstructed V<sub>2</sub>O<sub>5</sub>/V<sub>3</sub>O<sub>7</sub>·H<sub>2</sub>O (V<sub>2</sub>V<sub>3</sub>) heterointerface, forming a hydrogen bond interfacial layer (HB-V<sub>2</sub>V<sub>3</sub>). The hydrogen-bond network reinforces interfacial cohesion and induces oriented dipoles, which cooperate with the heterojunction’s built-in electric field to enhance electronic coupling and accelerate Zn<sup>2+</sup> transport. Meanwhile, the strengthened V-O interactions and regulated interfacial hydration environment effectively suppress vanadium dissolution and preserve lattice integrity. Functioning as a noninvasive and compliant molecular “sheath”, it regulates the local chemical environment while preserving the host lattice. As a result, HB-V<sub>2</sub>V<sub>3</sub> delivers a reversible capacity of 464.53 mAh g<sup>-1</sup> at 0.1 A g<sup>-1</sup> within 0.2-1.6 V and exhibits outstanding durability, retaining 95.5% after 500 cycles at 2.0 A g<sup>-1</sup> and 93.1% after 2200 cycles at 5.0 A g<sup>-1</sup>. It also maintains approximately 81% of its capacity after 300 cycles at 1 A g<sup>-1</sup> in a pouch-cell configuration. These results establish hydrogen-bond-driven interfacial modulation as an effective and broadly applicable route to stabilize vanadium cathodes and enhance the performance of AZIBs.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"311 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Charge Redistribution and Local Crystal Reconstruction in Fe-Based Polyanion Cathodes towards All-Climate Sodium-Ion Batteries 用于全天候钠离子电池的铁基聚阴离子阴极的电荷重分布和局部晶体重构
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-05 DOI: 10.1016/j.ensm.2026.104968
Yutian Yang, Shuang Zhou, Yuying Zhang, Yuan Zhou, Hang Li, Yining Chen, Yun Liu, Penghui Cao, Shangyong Lin, Anqiang Pan
Na2FeP2O7 (NFPO) has attracted widespread attention owning to its superior thermal stability and uniformity. However, its practical application is hindered by limited rate performance, rapid capacity fading and poor all-climate adaptability, which are closely related to electrode kinetics and structural stability. Herein, a synergistic strategy combining charge redistribution with local crystal reconstruction is proposed by the introduction of rare earth (RE) elements, enhancing the charge transport kinetics and structural stability of NFPO, thereby boosting its comprehensive performance and all-climate adaptability. Specifically, by introducing RE that are more prone to losing electrons at the Fe sites, the pinning effect of RE could reconstruct the local structure of TMO6, thus enhancing the structural stability of NFPO for high-temperature tolerance. Meanwhile, RE can tailor charge distribution and expand Na+ diffusion channels, thus improving the kinetics of NFPO for low-temperature tolerance. As a result, the advanced NFPO-Sc cathode delivers a superior capacity (reaching the theoretical capacity of 97 mAh g−1 at 0.1C), extra-long cycling performance (over 4000 cycles at 10C) and a wide temperature adaptability (-45 to 60°C). Notably, the pouch cell with high mass loading (18.33 mg cm−2) cathodes achieves a competitive capacity retention with 93% over 220 cycles at 1C.
{"title":"Charge Redistribution and Local Crystal Reconstruction in Fe-Based Polyanion Cathodes towards All-Climate Sodium-Ion Batteries","authors":"Yutian Yang, Shuang Zhou, Yuying Zhang, Yuan Zhou, Hang Li, Yining Chen, Yun Liu, Penghui Cao, Shangyong Lin, Anqiang Pan","doi":"10.1016/j.ensm.2026.104968","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104968","url":null,"abstract":"Na<sub>2</sub>FeP<sub>2</sub>O<sub>7</sub> (NFPO) has attracted widespread attention owning to its superior thermal stability and uniformity. However, its practical application is hindered by limited rate performance, rapid capacity fading and poor all-climate adaptability, which are closely related to electrode kinetics and structural stability. Herein, a synergistic strategy combining charge redistribution with local crystal reconstruction is proposed by the introduction of rare earth (RE) elements, enhancing the charge transport kinetics and structural stability of NFPO, thereby boosting its comprehensive performance and all-climate adaptability. Specifically, by introducing RE that are more prone to losing electrons at the Fe sites, the pinning effect of RE could reconstruct the local structure of TMO<sub>6</sub>, thus enhancing the structural stability of NFPO for high-temperature tolerance. Meanwhile, RE can tailor charge distribution and expand Na<sup>+</sup> diffusion channels, thus improving the kinetics of NFPO for low-temperature tolerance. As a result, the advanced NFPO-Sc cathode delivers a superior capacity (reaching the theoretical capacity of 97 mAh g<sup>−1</sup> at 0.1C), extra-long cycling performance (over 4000 cycles at 10C) and a wide temperature adaptability (-45 to 60°C). Notably, the pouch cell with high mass loading (18.33 mg cm<sup>−2</sup>) cathodes achieves a competitive capacity retention with 93% over 220 cycles at 1C.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"9 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging of dual-atom electrocatalysts advancing lithium-sulfur batteries: recent advances, challenges and perspectives 推进锂硫电池的双原子电催化剂的出现:最新进展、挑战和展望
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104965
Xuting Li, Zhenxiang Zhao, Shuheng Yuan, Junhao Cheng, Wenshuo Hou, Linrui Hou, Fengwei Liu, Changzhou Yuan
The practical implementation of lithium-sulfur (Li-S) batteries with high energy density and low cost faces significant challenges stemming from the inherent sluggish redox kinetics and inefficient conversion reactions of lithium polysulfides (LiPSs). Recent breakthroughs in dual-atom catalysts (DACs) have opened new avenues for addressing these limitations, as these materials exhibit uniquely tailored electronic configurations, pronounced synergistic effects between active sites, and unparalleled atomic utilization efficiency. This comprehensive review critically examines the latest advancements in DACs applications for Li-S batteries, with particular emphasis on their multifunctional roles in LiPSs adsorption/conversion, shuttle mitigation and Li+ deposition. Through meticulous engineering of coordination environments, spatial distributions of active centers, and substrate structures, DACs verify extraordinary capabilities in accelerating sulfur conversion kinetics, facilitating charge transfer processes, and enhancing long-term cycling stability. Combining state-of-the-art theoretical calculation with characterization techniques, the discussion further unravels the fundamental catalytic mechanisms of DACs under extreme operating conditions. Finally, the review concludes by identifying existing challenges and future research directions. Most importantly, by establishing clear structure-performance correlations and synthesizing latest developments in DACs frontier, the contribution not only provides actionable guidelines for catalyst design but lays a theoretical foundation for rational development of advanced energy storage technologies.
{"title":"Emerging of dual-atom electrocatalysts advancing lithium-sulfur batteries: recent advances, challenges and perspectives","authors":"Xuting Li, Zhenxiang Zhao, Shuheng Yuan, Junhao Cheng, Wenshuo Hou, Linrui Hou, Fengwei Liu, Changzhou Yuan","doi":"10.1016/j.ensm.2026.104965","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104965","url":null,"abstract":"The practical implementation of lithium-sulfur (Li-S) batteries with high energy density and low cost faces significant challenges stemming from the inherent sluggish redox kinetics and inefficient conversion reactions of lithium polysulfides (LiPSs). Recent breakthroughs in dual-atom catalysts (DACs) have opened new avenues for addressing these limitations, as these materials exhibit uniquely tailored electronic configurations, pronounced synergistic effects between active sites, and unparalleled atomic utilization efficiency. This comprehensive review critically examines the latest advancements in DACs applications for Li-S batteries, with particular emphasis on their multifunctional roles in LiPSs adsorption/conversion, shuttle mitigation and Li<sup>+</sup> deposition. Through meticulous engineering of coordination environments, spatial distributions of active centers, and substrate structures, DACs verify extraordinary capabilities in accelerating sulfur conversion kinetics, facilitating charge transfer processes, and enhancing long-term cycling stability. Combining state-of-the-art theoretical calculation with characterization techniques, the discussion further unravels the fundamental catalytic mechanisms of DACs under extreme operating conditions. Finally, the review concludes by identifying existing challenges and future research directions. Most importantly, by establishing clear structure-performance correlations and synthesizing latest developments in DACs frontier, the contribution not only provides actionable guidelines for catalyst design but lays a theoretical foundation for rational development of advanced energy storage technologies.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"28 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Entropy-Stabilized Engineering Enables Stable High-Voltage Phosphate Cathode Materials for Sodium-Ion Batteries 熵稳定工程为钠离子电池提供稳定的高压磷酸盐正极材料
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104964
Xiaohao Liu, Xiaoyue Zhang, Longhai Zhang, Xin Tan, Li Li, Weibo Hua, Chaofeng Zhang, Shulei Chou
{"title":"Entropy-Stabilized Engineering Enables Stable High-Voltage Phosphate Cathode Materials for Sodium-Ion Batteries","authors":"Xiaohao Liu, Xiaoyue Zhang, Longhai Zhang, Xin Tan, Li Li, Weibo Hua, Chaofeng Zhang, Shulei Chou","doi":"10.1016/j.ensm.2026.104964","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104964","url":null,"abstract":"","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"83 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146135325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailored Material Design and Scalable Integration of 3D-Printed Flexible Batteries for Wearable Electronics: A Comprehensive Review 可穿戴电子产品3d打印柔性电池的定制材料设计和可扩展集成:综合综述
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104966
Wenting Li, Diquan Xu, Rui Wang, Mohsen Shakouri, Huan Pang
The burgeoning field of wearable flexible electronics has generated a pressing need for electrochemical energy storage (EES) systems that combine high electrochemical performance with excellent mechanical compliance. Additive manufacturing (AM), also known as 3D printing, has emerged as a transformative approach, offering unparalleled advantages in structural design freedom, material efficiency, and device customization. These capabilities make AM a disruptive technology for the production of next-generation flexible batteries. This article systematically reviews recent advancements in 3D-printed flexible energy storage devices, providing a comprehensive overview of the most widely used AM techniques in the field of flexible electronics. Each technique is rigorously evaluated in terms of its technological distinctiveness and suitability for specific applications. Furthermore, the review discusses material selection strategies for 3D-printed flexible batteries, with critical assessment of advanced functional materials for use in electrodes, separators, and electrolytes. Finally, based on persistent challenges—such as the limited synergy between materials and processes, and the trade-off between printing resolution and efficiency—future research directions are proposed.
{"title":"Tailored Material Design and Scalable Integration of 3D-Printed Flexible Batteries for Wearable Electronics: A Comprehensive Review","authors":"Wenting Li, Diquan Xu, Rui Wang, Mohsen Shakouri, Huan Pang","doi":"10.1016/j.ensm.2026.104966","DOIUrl":"https://doi.org/10.1016/j.ensm.2026.104966","url":null,"abstract":"The burgeoning field of wearable flexible electronics has generated a pressing need for electrochemical energy storage (EES) systems that combine high electrochemical performance with excellent mechanical compliance. Additive manufacturing (AM), also known as 3D printing, has emerged as a transformative approach, offering unparalleled advantages in structural design freedom, material efficiency, and device customization. These capabilities make AM a disruptive technology for the production of next-generation flexible batteries. This article systematically reviews recent advancements in 3D-printed flexible energy storage devices, providing a comprehensive overview of the most widely used AM techniques in the field of flexible electronics. Each technique is rigorously evaluated in terms of its technological distinctiveness and suitability for specific applications. Furthermore, the review discusses material selection strategies for 3D-printed flexible batteries, with critical assessment of advanced functional materials for use in electrodes, separators, and electrolytes. Finally, based on persistent challenges—such as the limited synergy between materials and processes, and the trade-off between printing resolution and efficiency—future research directions are proposed.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"288 1","pages":""},"PeriodicalIF":20.4,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Farewell Message from the Founding Editor-in-Chief, Prof. Hui-Ming Cheng 创刊总编辑郑慧明教授的告别辞
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104962
Hui-Ming Cheng
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Energy Storage Materials
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