Tribological Effects of Quaternary Ammonium-Functionalized Montmorillonite as Water-Based Additives

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2024-07-03 DOI:10.1021/acs.langmuir.4c01799
Zekun Kang, Xiaoxiao Du, Keying Hua, Xiangyu Zuo, Dongmei Xu* and Xia Zhang*, 
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Abstract

In this study, a water-soluble quaternary ammonium salt (QAS)-functionalized montmorillonite (MMT) was fabricated using a mechanochemical method as a high-performance water lubrication additive. The intercalation of QAS into the MMT layer expands the layer spacing of MMT, but does not affect the hydrophilicity of MMT. The ultrathin layer QAS-functionalized montmorillonite (QAS-MMT) demonstrated excellent water-stable dispersion and can be used as a water-based lubrication additive. Only 0.1% addition can reduce the friction coefficient by more than 71.4% and the wear volume by about 58.8% when compared to water, demonstrating its excellent friction reduction and antiwear performance. The frictional mechanism indicates that the physical adsorption film, together with the chemical reaction film, endows the QAS-MMT additives with outstanding tribological performance, provides excellent lubrication for the contact of steel/steel pairs, and prevents the steel surface from being further worn.

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季铵官能化蒙脱石作为水基添加剂的摩擦学效应。
本研究采用机械化学方法制备了一种水溶性季铵盐(QAS)功能化蒙脱石(MMT),作为一种高性能水润滑添加剂。将 QAS 插层到 MMT 层中可扩大 MMT 的层间距,但不会影响 MMT 的亲水性。超薄层 QAS 功能化蒙脱石(QAS-MMT)具有出色的水稳定分散性,可用作水基润滑添加剂。与水相比,仅 0.1% 的添加量就能使摩擦系数降低 71.4% 以上,磨损体积减少约 58.8%,显示出其卓越的减摩抗磨性能。摩擦机理表明,物理吸附膜和化学反应膜赋予了 QAS-MMT 添加剂出色的摩擦学性能,为钢/钢对的接触提供了良好的润滑,并防止钢表面进一步磨损。
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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