{"title":"Heterogenization of [Ru(bpy)3]Cl2 on Ordered Mesoporous Silica Materials for Photocatalytic Applications","authors":"Malik Sebbat, Anish Lazar, Claire Laurent, Christelle Despas, Neus Vilà, Alain Walcarius, Nathan McClenaghan, Emmanuel Oheix, Bénédicte Lebeau, Morgan Cormier, Jean-Philippe Goddard","doi":"10.1055/a-2317-3672","DOIUrl":null,"url":null,"abstract":"<p>Herein, the preparation and characterization of three Ru-based heterogeneous photocatalysts supported on ordered mesoporous silica materials are reported. The photocatalytic activity of these catalysts was evaluated through oxidation, reduction, cycloaddition, and carboxylation reactions and their efficiencies are comparable to the parent [Ru(bpy)<sub>3</sub>]Cl<sub>2</sub> under homogeneous conditions. These photocatalysts are efficiently recovered even after five reaction cycles offering new opportunities in sustainable chemistry.</p> ","PeriodicalId":22319,"journal":{"name":"Synlett","volume":"69 1","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synlett","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1055/a-2317-3672","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
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Abstract
Herein, the preparation and characterization of three Ru-based heterogeneous photocatalysts supported on ordered mesoporous silica materials are reported. The photocatalytic activity of these catalysts was evaluated through oxidation, reduction, cycloaddition, and carboxylation reactions and their efficiencies are comparable to the parent [Ru(bpy)3]Cl2 under homogeneous conditions. These photocatalysts are efficiently recovered even after five reaction cycles offering new opportunities in sustainable chemistry.
期刊介绍：
SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.
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