The Merensky-Bastard interval at Hackney, eastern Bushveld Complex: results of a combined Sr–Nd-isotopic investigation

IF 3.5 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Contributions to Mineralogy and Petrology Pub Date : 2024-06-24 DOI:10.1007/s00410-024-02155-8
Justine Magson, Frederick Roelofse, Grant Bybee, Robert Bolhar
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Abstract

The Merensky and Bastard reefs of the Bushveld Complex occur within what has been called a transitional macro-unit along the boundary of the Critical and Main zones. The transitional unit is characterised by a geochemical hiatus recording distinct inflections in mineral chemistry and isotopic compositions. Previously these inflections in mineral chemistry and changes in isotopic compositions were attributed mostly to the influx of a magma that was compositionally distinct from the resident magma and that was parental to the Main Zone of the complex. Sr-isotopic variations across this interval have been particularly well-studied, but despite this, little consensus exists regarding the petrogenesis and metallogenesis of this economically important interval. Here we report whole-rock Sr–Nd-isotopic, major- and trace element geochemical and mineral chemical data across the Merensky-Bastard interval as intersected by borehole BH8172 on the farm Hackney in the eastern Bushveld Complex. Variations in whole-rock Cr/MgO values and initial Sr isotopic ratios across the interval are consistent with the results of previous studies that argued for the co-accumulation of minerals from compositionally and isotopically distinct magmas, of Critical and Main Zone lineages, respectively. In our model, a magma of Critical Zone affinity enters the chamber causing erosion along the chamber floor. Orthopyroxene and plagioclase crystallise from the Critical Zone magma to form the Merensky Reef, as suggested by high whole-rock Cr/MgO ratios (> 80) and unradiogenic Sr-isotopic compositions (87Sr/86Sri < 0.7068). A plagioclase-laden magma of Main Zone affinity subsequently intruded the chamber as a basal flow, elevating the resident Critical Zone magma. Plagioclase within the former floated, forming a solid raft onto which the Bastard Reef was deposited, a model that is entirely consistent with density considerations and an upward increase in the An-content of plagioclase as observed in the anorthositic package between the Merensky and Bastard reefs. From a metallogenetic viewpoint, this would imply that the Main Zone could not have been the source of the PGEs within the Merensky Reef.

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布什维尔德复合体东部哈克尼的 Merensky-Bastard 区间:锶-钕-同位素联合调查的结果
布什维尔德岩群的梅伦斯基礁和巴斯塔德礁位于临界区和主区交界处的过渡大单元内。过渡单元的特点是地球化学间断,记录了矿物化学和同位素组成的明显变化。以前,这些矿物化学成分的变化和同位素组成的变化主要归因于岩浆的涌入,这种岩浆在成分上与常住岩浆不同,是该复合体主区的亲岩浆。对这一区间的锶同位素变化研究尤为深入,但尽管如此,人们对这一具有重要经济价值的区间的岩石成因和金属生成仍缺乏共识。在此,我们报告了布什维尔德复合体东部哈克尼农场 BH8172 号钻孔与 Merensky-Bastard 区间的全岩 Sr-Nd- 同位素、主要和痕量元素地球化学及矿物化学数据。整个区间的全岩 Cr/MgO 值和初始 Sr 同位素比值的变化与之前的研究结果一致,之前的研究认为矿物来自成分和同位素不同的岩浆,分别属于临界区和主区系。在我们的模型中,临界区的岩浆进入岩室,造成岩室底部的侵蚀。正辉石和斜长石从临界区岩浆中结晶出来,形成梅伦斯基礁,这一点可以从高的全岩Cr/MgO比值(80)和非辐射成因的Sr-同位素组成(87Sr/86Sri 0.7068)中得到证实。随后,与主区亲缘关系密切的富含斜长石的岩浆以基底流的形式侵入岩室,抬升了临界区的岩浆。前者中的斜长石漂浮起来,形成了一个固体筏,巴斯塔德礁就沉积在这个固体筏上。这个模型完全符合密度方面的考虑,也符合在梅伦斯基礁和巴斯塔德礁之间的正长岩包裹体中观察到的斜长石An含量向上增加的情况。从金属成因的角度来看,这意味着主区不可能是梅伦斯基礁内PGEs的来源。
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来源期刊
Contributions to Mineralogy and Petrology
Contributions to Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
6.50
自引率
5.70%
发文量
94
审稿时长
1.7 months
期刊介绍: Contributions to Mineralogy and Petrology is an international journal that accepts high quality research papers in the fields of igneous and metamorphic petrology, geochemistry and mineralogy. Topics of interest include: major element, trace element and isotope geochemistry, geochronology, experimental petrology, igneous and metamorphic petrology, mineralogy, major and trace element mineral chemistry and thermodynamic modeling of petrologic and geochemical processes.
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