Christian Rolf, Susanne Rohs, Herman G.J. Smit, Martina Krämer, Zoltán Bozóki, Stefan Hofmann, Harald Franke, Rolf Maser, Peter Hoor, Andreas Petzold
{"title":"Evaluation of compact hygrometers for continuous airborne measurements","authors":"Christian Rolf, Susanne Rohs, Herman G.J. Smit, Martina Krämer, Zoltán Bozóki, Stefan Hofmann, Harald Franke, Rolf Maser, Peter Hoor, Andreas Petzold","doi":"10.1127/metz/2023/1187","DOIUrl":null,"url":null,"abstract":"Continuous water vapour measurements in the troposphere and lowermost stratosphere are crucial for the understanding of global water transport processes and climate impact. In the course of the ‘Development and Evaluation of Novel and Compact Hygrometer for Airborne Research’ (DENCHAR) project, water vapour instruments (WaSuL, WVSS‑II, ICH) have been partly newly developed and/or extensively tested in the laboratory as well as onboard of research aircraft. For the blind intercomparisons of the instruments, an MBW DP30 frostpoint mirror and the established FISH Lyman‑α instrument (calibrated versus the MBW DP30) served as reference hygrometers in the laboratory and during the flights, respectively. All DENCHAR-instruments show very consistent behaviour in their respective measuring ranges with deviations of less than about 5–10 %, in‑flight with respect to FISH and in the laboratory with respect to DP30 in the range between 100 and 1000 ppmv, as well as among each other in the range of 100 to 20000 ppmv. At mixing ratios below 100 ppmv, differences between the instruments appear which depend on the individual response times and calibrations. In summary, the WaSul, ICH and WVSS‑II hygrometers can be recommended for continuous water vapour measurements at mixing ratios larger than 10, 30, and 30 ppmv, respectively. For an accurate, reliable, and stable measurement of lower water vapour mixing ratios with a compact hygrometer suitable for autonomous operation, either these instruments need to be improved or new technology would have to be developed. In addition to the instrument evaluation, the performance of different water vapour inlet systems is addressed by comparing a forward-facing Rosemount (TAT housing) and a wall plate inlet. From all in‑flight tests, no measurement artifacts caused by specific characteristics of an inlet could be identified, i.e., forward-facing Rosemount and wall plate inlets can be recommended for use on aircraft for water vapour mixing ratios above 30 ppmv.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1127/metz/2023/1187","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Continuous water vapour measurements in the troposphere and lowermost stratosphere are crucial for the understanding of global water transport processes and climate impact. In the course of the ‘Development and Evaluation of Novel and Compact Hygrometer for Airborne Research’ (DENCHAR) project, water vapour instruments (WaSuL, WVSS‑II, ICH) have been partly newly developed and/or extensively tested in the laboratory as well as onboard of research aircraft. For the blind intercomparisons of the instruments, an MBW DP30 frostpoint mirror and the established FISH Lyman‑α instrument (calibrated versus the MBW DP30) served as reference hygrometers in the laboratory and during the flights, respectively. All DENCHAR-instruments show very consistent behaviour in their respective measuring ranges with deviations of less than about 5–10 %, in‑flight with respect to FISH and in the laboratory with respect to DP30 in the range between 100 and 1000 ppmv, as well as among each other in the range of 100 to 20000 ppmv. At mixing ratios below 100 ppmv, differences between the instruments appear which depend on the individual response times and calibrations. In summary, the WaSul, ICH and WVSS‑II hygrometers can be recommended for continuous water vapour measurements at mixing ratios larger than 10, 30, and 30 ppmv, respectively. For an accurate, reliable, and stable measurement of lower water vapour mixing ratios with a compact hygrometer suitable for autonomous operation, either these instruments need to be improved or new technology would have to be developed. In addition to the instrument evaluation, the performance of different water vapour inlet systems is addressed by comparing a forward-facing Rosemount (TAT housing) and a wall plate inlet. From all in‑flight tests, no measurement artifacts caused by specific characteristics of an inlet could be identified, i.e., forward-facing Rosemount and wall plate inlets can be recommended for use on aircraft for water vapour mixing ratios above 30 ppmv.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.