M. P. Kurlykin, M. A. Golovina, M. M. Dudkina, A. V. Ten’kovtsev
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引用次数: 0
Abstract
A new approach to the synthesis of polyrotaxanes from the polyethylenimine‒block‒poly(ethylene glycol)‒block‒polyethylenimine copolymer and alpha-cyclodextrin has been proposed. It has been shown that the acylation of free amino groups of polypseudorotaxane effectively blocks decomposition of the complex in solution. The structure of the synthesized copolymers has been studied in detail by 1Н and 13С NMR spectroscopy, IR analysis, and GPC. It is assumed that the observed abnormally high optical activity of the resulting rotaxanes is probably associated with the formation of chiral helical supramolecular structures.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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