Effect of Ni-W Morphology on the Catalytic Ethylbenzene Hydrogenation

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL Catalysis Letters Pub Date : 2024-06-21 DOI:10.1007/s10562-024-04740-9
Nan Zheng, Yunyun Dong, Juan Xu, Wenqiang Lai
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Abstract

Ni-W catalysts find extensive application in catalysis; however, the impact of diverse morphologies on their catalytic activity remains a relatively unexplored area. Using hydrothermal/solvothermal synthesis methods, we successfully synthesized Ni-W catalysts with various morphologies, including sheet-like, sphere-like, rod-like, flower-like, and particulate-like structures. Comprehensive investigations into the influence of morphology on the catalytic activity of these Ni-W catalysts were conducted, employing techniques such as SEM, XRD, XPS, TG-DTG, BET, H2-TPR, and H2-TPD. Remarkably, the flower-like Ni-W catalyst displayed exceptional catalytic properties in ethylbenzene hydrogenation, exhibiting not only high hydrogenation activity but also superior sulfur resistance. Consequently, the flower-like Ni-W catalyst holds great potential for applications in industrial catalysis.

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Ni-W 形态对催化乙苯加氢的影响
镍-钨催化剂在催化领域有着广泛的应用,然而,不同形态对其催化活性的影响仍是一个相对未开发的领域。我们采用水热/溶热合成方法,成功合成了各种形态的 Ni-W 催化剂,包括片状、球状、棒状、花朵状和颗粒状结构。我们采用 SEM、XRD、XPS、TG-DTG、BET、H2-TPR 和 H2-TPD 等技术全面研究了形态对这些 Ni-W 催化剂催化活性的影响。值得注意的是,花状 Ni-W 催化剂在乙苯加氢过程中表现出优异的催化性能,不仅具有很高的加氢活性,而且还具有优异的抗硫性能。因此,花状 Ni-W 催化剂在工业催化领域具有巨大的应用潜力。
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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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