Wettability of non-metallic inclusions and its impact on bubble-induced flotation kinetics

IF 1.8 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS International Journal of Applied Ceramic Technology Pub Date : 2024-07-01 DOI:10.1111/ijac.14849
Luís Otávio Z. Falsetti, René Delfos, Florian Charruault, Bruno Luchini, Dirk Van Der Plas, Victor C. Pandolfelli
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Abstract

Ceramic refractory bubbling devices may be applied in the steel ladle to induce the flotation of non-metallic inclusions to the slag phase. These inclusions have many origins along the steelmaking process and induce a detrimental effect on the mechanical properties of these metals. Therefore, the design of high-performance ceramic plugs relies on understanding the fundamentals of non-metallic inclusions captured by the gas bubbles. This study investigated the flotation dynamics of hydrophobic and hydrophilic hollow glass particles through experimentation using a water model and quantifying the particle concentration via light scattering. Both types of particles exhibited a comparable natural flotation removal rate, whereas a 40% increase for hydrophobic particles was observed when introducing 1.1 mm bubbles (at 25 NL/h) enhancing the efficiency from 43.1% to 65.2%. For hydrophilic particles, the efficiency increased from 59.1% to 86.2% when bubbles were injected into the system, whereas the removal rate decreased by 2.1-fold. The consequence of the practice of inert gas purging to remove non-metallic inclusions is also discussed.

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非金属夹杂物的润湿性及其对气泡诱导浮选动力学的影响
陶瓷耐火鼓泡装置可用于钢包中,以诱导非金属夹杂物浮选到渣相中。这些夹杂物在炼钢过程中有许多来源,并对这些金属的机械性能产生不利影响。因此,高性能陶瓷塞的设计有赖于了解气泡捕获非金属夹杂物的基本原理。本研究通过使用水模型进行实验,并通过光散射量化颗粒浓度,研究了疏水性和亲水性中空玻璃颗粒的浮选动力学。两种颗粒的自然浮选去除率相当,而当引入 1.1 毫米气泡(25 NL/h)时,疏水性颗粒的去除率提高了 40%,从 43.1% 提高到 65.2%。对于亲水性颗粒,向系统中注入气泡后,效率从 59.1%提高到 86.2%,而去除率却降低了 2.1 倍。此外,还讨论了用惰性气体吹扫去除非金属夹杂物的做法所产生的后果。
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来源期刊
International Journal of Applied Ceramic Technology
International Journal of Applied Ceramic Technology 工程技术-材料科学:硅酸盐
CiteScore
3.90
自引率
9.50%
发文量
280
审稿时长
4.5 months
期刊介绍: The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas: Nanotechnology applications; Ceramic Armor; Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors); Ceramic Matrix Composites; Functional Materials; Thermal and Environmental Barrier Coatings; Bioceramic Applications; Green Manufacturing; Ceramic Processing; Glass Technology; Fiber optics; Ceramics in Environmental Applications; Ceramics in Electronic, Photonic and Magnetic Applications;
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