Xin-Liang Han, Jie Zhang, Zuo-Shu Wang, Hussein A. Younus, De-Wei Wang
{"title":"Engineering the microstructures of manganese dioxide coupled with oxygen vacancies for boosting aqueous ammonium-ion storage in hybrid capacitors","authors":"Xin-Liang Han, Jie Zhang, Zuo-Shu Wang, Hussein A. Younus, De-Wei Wang","doi":"10.1007/s12598-024-02818-2","DOIUrl":null,"url":null,"abstract":"<p>The aqueous ammonium ion (NH<sub>4</sub><sup>+</sup>) is a promising charge carrier in virtue of its safety, environmental friendliness, abundant resources and small hydrated ionic size. The exploration of NH<sub>4</sub><sup>+</sup> host electrodes with good reversibility and large storage capacity to construct high-performance ammonium-ion hybrid capacitors (AIHCs), however, is still in its infancy. Herein, a facile etching technique is put forward to produce oxygen-deficient MnO<sub>2</sub> (O<sub>d</sub>-MnO<sub>2</sub>) as the electrode material for NH<sub>4</sub><sup>+</sup> storage. According to the experimental and theoretical calculation results, the etching process not only creates more porosity, offering abundant active sites, but also generates abundant oxygen vacancies, which modify the structure of pristine MnO<sub>2</sub>, enhance charge storage capacity and boost ion diffusion kinetics. Consequently, O<sub>d</sub>-MnO<sub>2</sub> can deliver a specific capacity of 155 mAh·g<sup>−1</sup> at 0.5 A·g<sup>−1</sup> and a good long-term cycling stability with 86.8% capacity maintained after 10,000 cycles at 5.0 A·g<sup>−1</sup>. Additionally, the NH<sub>4</sub><sup>+</sup> storage mechanism was evidenced by several ex-situ characterization analyses. To examine the actual implementation of O<sub>d</sub>-MnO<sub>2</sub> as a positive electrode for NH<sub>4</sub><sup>+</sup> full device, AIHCs are assembled with activated carbon functionalized with Fe<sub>3</sub>O<sub>4</sub> nanoparticles (Fe<sub>3</sub>O<sub>4</sub>@AC) as a negative electrode. A high specific capacitance of 184 F·g<sup>−1</sup> at 0.5 A·g<sup>−1</sup>, satisfactory energy density of 102 Wh·kg<sup>−1</sup> at 500 W·kg<sup>−1</sup>, a low self-discharge rate and good cycling durability after 10,000 cycles are attained. The electrochemical performance of these AIHCs is comparable to or surpass those of traditional supercapacitors with metal ions as charge carriers, highlighting the advantages of structural modification in enhancing the NH<sub>4</sub><sup>+</sup> storage performance.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":null,"pages":null},"PeriodicalIF":9.6000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Rare Metals","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s12598-024-02818-2","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The aqueous ammonium ion (NH4+) is a promising charge carrier in virtue of its safety, environmental friendliness, abundant resources and small hydrated ionic size. The exploration of NH4+ host electrodes with good reversibility and large storage capacity to construct high-performance ammonium-ion hybrid capacitors (AIHCs), however, is still in its infancy. Herein, a facile etching technique is put forward to produce oxygen-deficient MnO2 (Od-MnO2) as the electrode material for NH4+ storage. According to the experimental and theoretical calculation results, the etching process not only creates more porosity, offering abundant active sites, but also generates abundant oxygen vacancies, which modify the structure of pristine MnO2, enhance charge storage capacity and boost ion diffusion kinetics. Consequently, Od-MnO2 can deliver a specific capacity of 155 mAh·g−1 at 0.5 A·g−1 and a good long-term cycling stability with 86.8% capacity maintained after 10,000 cycles at 5.0 A·g−1. Additionally, the NH4+ storage mechanism was evidenced by several ex-situ characterization analyses. To examine the actual implementation of Od-MnO2 as a positive electrode for NH4+ full device, AIHCs are assembled with activated carbon functionalized with Fe3O4 nanoparticles (Fe3O4@AC) as a negative electrode. A high specific capacitance of 184 F·g−1 at 0.5 A·g−1, satisfactory energy density of 102 Wh·kg−1 at 500 W·kg−1, a low self-discharge rate and good cycling durability after 10,000 cycles are attained. The electrochemical performance of these AIHCs is comparable to or surpass those of traditional supercapacitors with metal ions as charge carriers, highlighting the advantages of structural modification in enhancing the NH4+ storage performance.
期刊介绍:
Rare Metals is a monthly peer-reviewed journal published by the Nonferrous Metals Society of China. It serves as a platform for engineers and scientists to communicate and disseminate original research articles in the field of rare metals. The journal focuses on a wide range of topics including metallurgy, processing, and determination of rare metals. Additionally, it showcases the application of rare metals in advanced materials such as superconductors, semiconductors, composites, and ceramics.