CuTiO3/TiO2 MSM UV Photodetector with a Type-I Heterojunction for Rapid and Low-Power Detection

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-06-26 DOI:10.1021/acsaelm.4c00950
Yupeng Zhang, Zhengyu Bi, Xinyan Liu, Yan Ma, Shengping Ruan, Ruiliang Xu, Jingran Zhou
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Abstract

Dark current and response speed matter a lot in UV detection. TiO2 MSM UV detectors offer many positive attributes, including chemical stability and excellent absorption in the UV region. However, they also have a high dark current and a poor response time. To get around these drawbacks, an MSM UV detector based on the CuTiO3/TiO2 type-I heterojunction was created in this work. The introduction of high-dielectric perovskite CuTiO3 reduces carriers and thus leads to a low dark current (8.06 × 10–12 A). Furthermore, type-I heterojunction properties of the CuTiO3/TiO2 heterojunction significantly restrict the recombination process of photogenerated carriers in TiO2, improving response and recovery times (78 and 93 ms). The findings suggested that high-performance UV photodetectors might be created by combining conventional wide-band-gap semiconductor materials with high-dielectric perovskite CuTiO3.

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采用 I 型异质结的 CuTiO3/TiO2 MSM 紫外线光电探测器,用于快速和低功耗检测
暗电流和响应速度对紫外检测非常重要。TiO2 MSM 紫外线检测器具有许多优点,包括化学稳定性和在紫外线区域的出色吸收能力。但是,它们的暗电流较高,响应速度较慢。为了克服这些缺点,本研究创建了一种基于 CuTiO3/TiO2 I 型异质结的 MSM 紫外探测器。高介电过氧化物 CuTiO3 的引入减少了载流子,从而降低了暗电流(8.06 × 10-12 A)。此外,CuTiO3/TiO2 异质结的 I 型异质结特性极大地限制了 TiO2 中光生载流子的重组过程,从而改善了响应和恢复时间(78 和 93 毫秒)。研究结果表明,将传统的宽带隙半导体材料与高介电的包晶 CuTiO3 结合在一起,可以制造出高性能的紫外光检测器。
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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