CuTiO3/TiO2 MSM UV Photodetector with a Type-I Heterojunction for Rapid and Low-Power Detection

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-06-26 DOI:10.1021/acsaelm.4c00950
Yupeng Zhang, Zhengyu Bi, Xinyan Liu, Yan Ma, Shengping Ruan, Ruiliang Xu, Jingran Zhou
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Abstract

Dark current and response speed matter a lot in UV detection. TiO2 MSM UV detectors offer many positive attributes, including chemical stability and excellent absorption in the UV region. However, they also have a high dark current and a poor response time. To get around these drawbacks, an MSM UV detector based on the CuTiO3/TiO2 type-I heterojunction was created in this work. The introduction of high-dielectric perovskite CuTiO3 reduces carriers and thus leads to a low dark current (8.06 × 10–12 A). Furthermore, type-I heterojunction properties of the CuTiO3/TiO2 heterojunction significantly restrict the recombination process of photogenerated carriers in TiO2, improving response and recovery times (78 and 93 ms). The findings suggested that high-performance UV photodetectors might be created by combining conventional wide-band-gap semiconductor materials with high-dielectric perovskite CuTiO3.

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采用 I 型异质结的 CuTiO3/TiO2 MSM 紫外线光电探测器,用于快速和低功耗检测
暗电流和响应速度对紫外检测非常重要。TiO2 MSM 紫外线检测器具有许多优点,包括化学稳定性和在紫外线区域的出色吸收能力。但是,它们的暗电流较高,响应速度较慢。为了克服这些缺点,本研究创建了一种基于 CuTiO3/TiO2 I 型异质结的 MSM 紫外探测器。高介电过氧化物 CuTiO3 的引入减少了载流子,从而降低了暗电流(8.06 × 10-12 A)。此外,CuTiO3/TiO2 异质结的 I 型异质结特性极大地限制了 TiO2 中光生载流子的重组过程,从而改善了响应和恢复时间(78 和 93 毫秒)。研究结果表明,将传统的宽带隙半导体材料与高介电的包晶 CuTiO3 结合在一起,可以制造出高性能的紫外光检测器。
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4.30%
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567
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