{"title":"CuTiO3/TiO2 MSM UV Photodetector with a Type-I Heterojunction for Rapid and Low-Power Detection","authors":"Yupeng Zhang, Zhengyu Bi, Xinyan Liu, Yan Ma, Shengping Ruan, Ruiliang Xu, Jingran Zhou","doi":"10.1021/acsaelm.4c00950","DOIUrl":null,"url":null,"abstract":"Dark current and response speed matter a lot in UV detection. TiO<sub>2</sub> MSM UV detectors offer many positive attributes, including chemical stability and excellent absorption in the UV region. However, they also have a high dark current and a poor response time. To get around these drawbacks, an MSM UV detector based on the CuTiO<sub>3</sub>/TiO<sub>2</sub> type-I heterojunction was created in this work. The introduction of high-dielectric perovskite CuTiO<sub>3</sub> reduces carriers and thus leads to a low dark current (8.06 × 10<sup>–12</sup> A). Furthermore, type-I heterojunction properties of the CuTiO<sub>3</sub>/TiO<sub>2</sub> heterojunction significantly restrict the recombination process of photogenerated carriers in TiO<sub>2</sub>, improving response and recovery times (78 and 93 ms). The findings suggested that high-performance UV photodetectors might be created by combining conventional wide-band-gap semiconductor materials with high-dielectric perovskite CuTiO<sub>3</sub>.","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsaelm.4c00950","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Dark current and response speed matter a lot in UV detection. TiO2 MSM UV detectors offer many positive attributes, including chemical stability and excellent absorption in the UV region. However, they also have a high dark current and a poor response time. To get around these drawbacks, an MSM UV detector based on the CuTiO3/TiO2 type-I heterojunction was created in this work. The introduction of high-dielectric perovskite CuTiO3 reduces carriers and thus leads to a low dark current (8.06 × 10–12 A). Furthermore, type-I heterojunction properties of the CuTiO3/TiO2 heterojunction significantly restrict the recombination process of photogenerated carriers in TiO2, improving response and recovery times (78 and 93 ms). The findings suggested that high-performance UV photodetectors might be created by combining conventional wide-band-gap semiconductor materials with high-dielectric perovskite CuTiO3.