Microstructure and Tribological Behavior of Low-Temperature HVAF Ti6Al4V Coatings

IF 3.2 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Journal of Thermal Spray Technology Pub Date : 2024-07-02 DOI:10.1007/s11666-024-01800-9
P. Khamsepour, P. Stoyanov, A. Dolatabad, C. Moreau
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Abstract

Ti-6Al-4 V is commonly used in gas turbine engines and is sometimes subject to wear during operation. To address this, cost-effective and environmentally friendly solutions are being explored, with a focus on solid-state additive manufacturing techniques such as cold spray (CS). CS can create a dense structure; however, the existing porosity adversely affects the mechanical properties. To reduce the need for post-heat-treatment, this paper considers inner-diameter high- velocity air-fuel (ID_HVAF) as an alternative repair method which is a relatively low-temperature HVAF process that can deposit coatings with microstructures close to those observed in CS coatings. ID_HVAF process can deposit particles at high velocities and relatively low temperatures so that a significant portion of the particles forming the coatings are deposited in the solid state. This work is based on the deposition of Ti-6Al-4 V coatings using the ID_HVAF gun. During deposition, increasing the nozzle length increases the particle velocity and substrate temperature. The particles hit a softer surface with higher kinetic energy, thus increasing the density of the samples. However, HVAF will still oxidize some Ti-6Al-4 V particles and produce vanadium oxide. To study the tribological behavior, Ti-6Al-4 V counterballs were used to simulate the dovetail interface. According to the result, the top deposited layers were densified by the application of counterbalance force. Compared to an α-β Ti-6Al-4 V bulk sample, the coatings have a smaller wear track width and a greater wear depth, resulting in less wear on the counterballs. Each of the three samples shows a combination of abrasive and adhesive wear. The low cohesion between the particles in the coatings results in smaller oxide debris with a greater amount on the wear track of the coatings. By acting as a roller between the counter ball and the coating, this debris can slightly reduce the coefficient of friction.

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低温 HVAF Ti6Al4V 涂层的微观结构和摩擦学行为
Ti-6Al-4 V 常用于燃气涡轮发动机,在运行过程中有时会出现磨损。为解决这一问题,人们正在探索具有成本效益且环保的解决方案,重点是冷喷(CS)等固态添加制造技术。冷喷技术可以形成致密的结构,但现有的孔隙率会对机械性能产生不利影响。为了减少后热处理的需要,本文考虑将内径高速空气燃料(ID_HVAF)作为一种替代修复方法,这是一种温度相对较低的 HVAF 工艺,可以沉积出微观结构接近 CS 涂层的涂层。ID_HVAF 工艺可以在高速和相对较低的温度下沉积颗粒,因此形成涂层的大部分颗粒都是以固态沉积的。这项工作基于使用 ID_HVAF 喷枪沉积 Ti-6Al-4 V 涂层。在沉积过程中,增加喷嘴长度可提高颗粒速度和基底温度。颗粒以更高的动能撞击到更软的表面,从而增加了样品的密度。不过,HVAF 仍会氧化一些 Ti-6Al-4 V 颗粒,产生氧化钒。为了研究摩擦学行为,使用 Ti-6Al-4 V 对球模拟燕尾槽界面。结果表明,在施加平衡力的作用下,顶部沉积层被致密化。与 α-β Ti-6Al-4 V 块状样品相比,涂层的磨损轨迹宽度较小,磨损深度较大,因此对反球的磨损较小。这三种样品中的每一种都显示出磨料磨损和粘着磨损的结合。涂层中颗粒之间的内聚力较低,导致涂层磨损轨迹上的氧化物碎片较小,数量较多。这些碎屑在滚珠和涂层之间起滚动作用,可略微降低摩擦系数。
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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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