{"title":"Color trajectories of natural pigments for model fresco samples under heating","authors":"I.A. Balakhnina , A.S. Pushistova , A.Yu. Chikishev , E.M. Kononova , T.I. Anisimova , N.N. Brandt","doi":"10.1016/j.dyepig.2024.112318","DOIUrl":null,"url":null,"abstract":"<div><p>The paper presents a concept of color trajectories as used to characterize fresco pigments and their color changes with increasing temperature. Color trajectories have shapes characteristic of certain colors or individual pigments. For 15 pigments, the minimum temperatures at which changes in their color coordinates become significant are determined. For several samples, heating can significantly change the color coordinates, but the integral color changes can be insignificant. The integral effect under heating of most samples to 740 °C is that the a* and b* color coordinates tend to zero and the lightness decreases. The exceptions are volkonskoite, the color of which becomes brighter after heating, and red lead, the lightness of which becomes greater due to the transformation of orange into light yellow. The results of this work can be used to construct an evolutionary line of real images under an increase in temperature.</p></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dyes and Pigments","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0143720824003838","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
The paper presents a concept of color trajectories as used to characterize fresco pigments and their color changes with increasing temperature. Color trajectories have shapes characteristic of certain colors or individual pigments. For 15 pigments, the minimum temperatures at which changes in their color coordinates become significant are determined. For several samples, heating can significantly change the color coordinates, but the integral color changes can be insignificant. The integral effect under heating of most samples to 740 °C is that the a* and b* color coordinates tend to zero and the lightness decreases. The exceptions are volkonskoite, the color of which becomes brighter after heating, and red lead, the lightness of which becomes greater due to the transformation of orange into light yellow. The results of this work can be used to construct an evolutionary line of real images under an increase in temperature.
期刊介绍:
Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied.
Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media.
The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.