Gas sensing properties of WO3 based materials with hierarchical structural features

IF 5.1 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Ceramics International Pub Date : 2024-07-04 DOI:10.1016/j.ceramint.2024.07.047
Chuanxuan Zhou, Mengyun Wang, Fuchao Yang
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Abstract

With the increasing requirements from toxic and hazardous gas detection technologies, WO3-based gas sensors have garnered tremendous interest on account of their low operating temperatures, good cycling stability, and short response/recovery time. So far, considerable progress has been made in the design and preparation of different architectures of WO3. The sensing mechanism of WO3-based gas sensors is relatively complex. To further optimize the capabilities of WO3-based gas sensors, the influencing factors of the sensing mechanism need to be deeply understood to seek more effective enhanced strategies. This review probes the application of WO3-based sensors for various dangerous gases and contrastively analyses the sensing behavior of WO3 in detail. In addition, we pay special attention to the interfacial interaction pathways between the sensing material and the target gas. Nowadays, more efforts are being made to strengthen the sensing properties of WO3-based materials so that they can be used in more smart demanding and complex environments. The authors focus on four approaches, namely, morphology control, hybridization, defect engineering, and photoactivation, for enhancing gas sensors and providing a comprehensive study of WO3 for gas-sensing applications. Finally, we discuss the current problems and improvement methods and provide an outlook on the development trend of WO3-based gas sensors.

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具有分层结构特征的 WO3 基材料的气体传感特性
随着有毒有害气体检测技术要求的不断提高,基于 WO3 的气体传感器因其工作温度低、循环稳定性好、响应/恢复时间短等优点而引起了人们的极大兴趣。迄今为止,在设计和制备不同结构的 WO3 方面已经取得了相当大的进展。基于 WO3 的气体传感器的传感机制相对复杂。为了进一步优化基于 WO3 的气体传感器的功能,需要深入了解传感机制的影响因素,以寻求更有效的增强策略。本综述探讨了基于 WO3 的传感器在各种危险气体中的应用,并详细对比分析了 WO3 的传感行为。此外,我们还特别关注了传感材料与目标气体之间的界面相互作用途径。如今,人们正努力加强基于 WO3 的材料的传感性能,使其能够应用于更多智能要求更高的复杂环境中。作者重点介绍了增强气体传感器的四种方法,即形态控制、杂化、缺陷工程和光激活,并对 WO3 在气体传感方面的应用进行了全面研究。最后,我们讨论了目前存在的问题和改进方法,并对基于 WO3 的气体传感器的发展趋势进行了展望。
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来源期刊
Ceramics International
Ceramics International 工程技术-材料科学:硅酸盐
CiteScore
9.40
自引率
15.40%
发文量
4558
审稿时长
25 days
期刊介绍: Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.
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