Towards a sector-specific CO∕CO2 emission ratio: satellite-based observations of CO release from steel production in Germany

IF 5.2 1区 地球科学 Q1 ENVIRONMENTAL SCIENCES Atmospheric Chemistry and Physics Pub Date : 2024-07-05 DOI:10.5194/acp-24-7609-2024
Oliver Schneising, Michael Buchwitz, Maximilian Reuter, Michael Weimer, Heinrich Bovensmann, John P. Burrows, Hartmut Bösch
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Abstract

Abstract. Global crude steel production is expected to continue to increase in the coming decades to meet the demands of the growing world population. Currently, the dominant steelmaking technology worldwide is the conventional highly CO2-intensive blast furnace–basic oxygen furnace production route (also known as the Linz–Donawitz process), which uses iron ore as raw material and coke as a reducing agent. As a result, large quantities of special gases that are rich in carbon monoxide (CO) are by-products of the various stages of the steelmaking process. Given the challenges associated with satellite-based estimates of carbon dioxide (CO2) emissions at the scale of emitting installations due to significant background levels, co-emitted CO may serve as a valuable indicator of the carbon footprint of steel plants. We show that regional CO release from steel production sites can be monitored from space using 5 years of measurements (2018–2022) from the TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5 Precursor satellite, benefiting from its relatively high spatial resolution and daily global coverage. We analyse all German steel plants with blast furnaces and basic oxygen furnaces and obtain associated CO emissions in the range of 50–400 kt yr−1 per site. A comparison with the respective CO2 emissions on the level of emitting installations available from emissions trading data of the European Union Emissions Trading System yields a linear relationship with a sector-specific CO/CO2 emission ratio for the analysed steelworks of 3.24 % [2.73–3.89; 1σ], suggesting the feasibility of using CO as a proxy for CO2 emissions from comparable steel production sites. An evaluation at other steel production sites indicates that the derived CO/CO2 emission ratio is also representative of other highly optimised state-of-the-art Linz–Donawitz steelworks outside Germany and that the emission ratio is potentially valuable for estimating sector-specific CO2 emissions from remotely sensed CO emissions, provided that the underlying CO emission estimate is not affected by other sources.
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实现特定行业的 CO∕CO2 排放比:基于卫星的德国钢铁生产 CO 释放观测数据
摘要未来几十年,全球粗钢产量预计将继续增加,以满足不断增长的世界人口的需求。目前,全球最主要的炼钢技术是传统的高炉--碱性氧气炉生产工艺(又称林茨-多纳维茨工艺),该工艺以铁矿石为原料,焦炭为还原剂,是一种高度二氧化碳密集型工艺。因此,炼钢过程的各个阶段都会产生大量富含一氧化碳(CO)的特殊气体副产品。由于大量的背景水平,基于卫星的二氧化碳(CO2)排放量估算在排放装置的规模上面临挑战,因此共同排放的 CO 可以作为衡量钢铁厂碳足迹的重要指标。我们利用哨兵-5 号前兆卫星上的 TROPOspheric Monitoring Instrument(TROPOMI)进行了为期 5 年(2018-2022 年)的测量,结果表明,利用其相对较高的空间分辨率和每日全球覆盖范围,可以从太空监测钢铁生产基地的区域性二氧化碳排放。我们对德国所有拥有高炉和氧气炉的钢铁厂进行了分析,获得了每个钢铁厂每年 50-400 kt-1 的相关二氧化碳排放量。根据欧盟排放交易系统的排放交易数据,我们将排放装置的二氧化碳排放量与相应的二氧化碳排放量进行了比较,结果发现,在所分析的钢铁厂中,特定行业的二氧化碳/一氧化碳排放比为 3.24 % [2.73-3.89; 1σ],这表明使用二氧化碳作为可比钢铁生产基地二氧化碳排放量的替代物是可行的。对其他钢铁生产基地的评估表明,推导出的 CO/CO2 排放比也能代表德国以外其他高度优化的林茨-多纳维茨(Linz-Donawitz)先进钢铁厂,并且只要基本的 CO 排放估算不受其他来源的影响,该排放比对于从遥感 CO 排放中估算特定行业的 CO2 排放量具有潜在价值。
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来源期刊
Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics 地学-气象与大气科学
CiteScore
10.70
自引率
20.60%
发文量
702
审稿时长
6 months
期刊介绍: Atmospheric Chemistry and Physics (ACP) is a not-for-profit international scientific journal dedicated to the publication and public discussion of high-quality studies investigating the Earth''s atmosphere and the underlying chemical and physical processes. It covers the altitude range from the land and ocean surface up to the turbopause, including the troposphere, stratosphere, and mesosphere. The main subject areas comprise atmospheric modelling, field measurements, remote sensing, and laboratory studies of gases, aerosols, clouds and precipitation, isotopes, radiation, dynamics, biosphere interactions, and hydrosphere interactions. The journal scope is focused on studies with general implications for atmospheric science rather than investigations that are primarily of local or technical interest.
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