Biopolymeric Composite Columns for Improving Water Quality in a Freshwater Stream Receiving Wastewater Treatment Plant Effluents

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL Journal of Polymers and the Environment Pub Date : 2024-07-09 DOI:10.1007/s10924-024-03335-0
Şahin Akpınar, Fatma Gurbuz, Samet Özcan, Mehmet Odabaşı
{"title":"Biopolymeric Composite Columns for Improving Water Quality in a Freshwater Stream Receiving Wastewater Treatment Plant Effluents","authors":"Şahin Akpınar,&nbsp;Fatma Gurbuz,&nbsp;Samet Özcan,&nbsp;Mehmet Odabaşı","doi":"10.1007/s10924-024-03335-0","DOIUrl":null,"url":null,"abstract":"<div><p>Inefficiently treated wastewater, which contains a high concentration of pollutants, is hazardous when it is mixed with the clean water of rivers and lakes. Nitrate in particular is a major global problem that leads to eutrophication and poses a threat to both aquatic ecosystems and human health. To address this issue, this work assessed the efficiency of polymeric cryogel (PC) and biopolymer (EPS)-blended composites (EPS@PC) in removing nitrates. Tests were also conducted to quantify the decrease in phosphate, chloride ions, and chemical oxygen demand (COD) in real water samples taken from the Ankara stream, which receives effluents from both urban (UWTP) and industrial (IWTP) wastewater treatment plants. Five different columns with varying adsorptive properties were prepared, some of which were combined with iron. The EPS-@PC-C5 column demonstrated the highest adsorption ratio for nitrate removal compared to the other tested columns. The EPS@PC-C5 achieved a high removal efficiency of 126.38 mg nitrate/g and showed COD reduction ranging from 60.2 to 94.1%. The removal ratio of chloride concentration varied between 56.0 and 75.7%, while the removal of phosphates ranged from 87 to 99%. Columns composed of EPS (EPS@PC) with both negatively and positively charged ligands are dependable and suitable options for water remediation.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":659,"journal":{"name":"Journal of Polymers and the Environment","volume":"32 11","pages":"5952 - 5964"},"PeriodicalIF":4.7000,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10924-024-03335-0.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymers and the Environment","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10924-024-03335-0","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0

Abstract

Inefficiently treated wastewater, which contains a high concentration of pollutants, is hazardous when it is mixed with the clean water of rivers and lakes. Nitrate in particular is a major global problem that leads to eutrophication and poses a threat to both aquatic ecosystems and human health. To address this issue, this work assessed the efficiency of polymeric cryogel (PC) and biopolymer (EPS)-blended composites (EPS@PC) in removing nitrates. Tests were also conducted to quantify the decrease in phosphate, chloride ions, and chemical oxygen demand (COD) in real water samples taken from the Ankara stream, which receives effluents from both urban (UWTP) and industrial (IWTP) wastewater treatment plants. Five different columns with varying adsorptive properties were prepared, some of which were combined with iron. The EPS-@PC-C5 column demonstrated the highest adsorption ratio for nitrate removal compared to the other tested columns. The EPS@PC-C5 achieved a high removal efficiency of 126.38 mg nitrate/g and showed COD reduction ranging from 60.2 to 94.1%. The removal ratio of chloride concentration varied between 56.0 and 75.7%, while the removal of phosphates ranged from 87 to 99%. Columns composed of EPS (EPS@PC) with both negatively and positively charged ligands are dependable and suitable options for water remediation.

Graphical Abstract

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
用于改善接受污水处理厂废水的淡水溪流水质的生物聚合物复合柱
未经充分处理的废水含有高浓度的污染物,当它与河流和湖泊的清洁水混合时,就会造成危害。尤其是硝酸盐,它是导致富营养化的一个主要全球性问题,对水生生态系统和人类健康都构成威胁。为解决这一问题,本研究评估了聚合物低温凝胶(PC)和生物聚合物(EPS)混合复合材料(EPS@PC)去除硝酸盐的效率。此外,还对安卡拉溪流的实际水样中磷酸盐、氯离子和化学需氧量(COD)的减少情况进行了量化测试,安卡拉溪流同时接收来自城市(UWTP)和工业(IWTP)污水处理厂的污水。我们制备了五种不同吸附性能的柱,其中一些还与铁结合在一起。与其他测试柱相比,EPS-@PC-C5 柱的硝酸盐去除吸附率最高。EPS@PC-C5 的硝酸盐去除效率高达 126.38 毫克/克,COD 的去除率为 60.2% 至 94.1%。氯化物浓度的去除率在 56.0% 到 75.7% 之间,而磷酸盐的去除率则在 87% 到 99% 之间。由带负电荷和正电荷配体的 EPS(EPS@PC)组成的色谱柱是可靠和合适的水处理选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
期刊最新文献
Graphene Derivatives Functionalized Polycaprolactone/Gelatin Electrospun Nanofibrous Membrane Through Mussel-Inspired Polydopamine: Multifunctional Scaffold with High Potential for Nerve Tissue Engineering Volatile Compounds and Off-odors Analysis of Recycled PLA for Packaging Applications: An Essential Factor for Ensuring Food Safety and Quality Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation Degradation of Cationic Polyacrylamide Flocculants upon Contact with Metal Surfaces During Rheological Measurements Green Synthesis of Silver Nanoparticles Using Cyto-compatible Polymer Derivative of Tara Gum for Gold (III) ion Detection in Water Samples
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1