Behavior of Nanocatalysts in Fischer–Tropsch Synthesis in Various Types of Three-Phase Slurry Reactors

IF 1.3 4区 工程技术 Q3 CHEMISTRY, ORGANIC Petroleum Chemistry Pub Date : 2024-07-08 DOI:10.1134/s096554412403006x
A. E. Kuz’min, O. S. Dementeva, M. V. Kulikova, Ya. V. Morozova, S. A. Svidersky, A. L. Maximov
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Abstract

The catalytic performance of iron-based nanodispersions in Fischer–Tropsch synthesis in two different slurry reactor types, specifically a continuous stirred-tank reactor (CSTR) and a slurry bubble column reactor (SBCR), was comparatively investigated. It was found that, at equal process temperatures, the CO conversion in the SBCR using a gas disperser with four equally spaced 1-mm holes was lower than that in the CSTR. However, this observation is inconsistent with other reports in the literature. Replacing this disperser with a plate with a single centered 2-mm hole enhanced the CO conversion up to values close to those obtained in the CSTR. The reaction rate constants were calculated for the different reactor types.

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纳米催化剂在不同类型三相淤浆反应器中进行费托合成的行为
摘要 比较研究了铁基纳米分散体在两种不同浆式反应器(即连续搅拌罐反应器(CSTR)和浆式气泡塔反应器(SBCR))中进行费托合成的催化性能。研究发现,在相同的工艺温度下,使用四个等间距 1 毫米孔的气体分散器的 SBCR 中的 CO 转化率低于 CSTR 中的转化率。然而,这一观察结果与文献中的其他报告并不一致。用一个中心开有 2 毫米孔的板代替气体分散器后,CO 转化率提高到接近 CSTR 中的数值。计算了不同类型反应器的反应速率常数。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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