Cold atmospheric pressure plasma-assisted aerosol deposition of multi-colored dual band electrochromic VOxCyNz thin films

IF 6.3 2区材料科学 Q2 ENERGY & FUELS Solar Energy Materials and Solar Cells Pub Date : 2024-07-08 DOI:10.1016/j.solmat.2024.113030

Yung-Sen Lin, Wei-Cheng Zhong, Gong-Min Zhang, Pei-Tsz Chen

{"title":"Cold atmospheric pressure plasma-assisted aerosol deposition of multi-colored dual band electrochromic VOxCyNz thin films","authors":"Yung-Sen Lin, Wei-Cheng Zhong, Gong-Min Zhang, Pei-Tsz Chen","doi":"10.1016/j.solmat.2024.113030","DOIUrl":null,"url":null,"abstract":"<div>Organo-vanadium oxynitrides (VOxCyNz) thin films, with multi-colored dual band electrochromic (EC) properties of individually selective visible (VIS) light-near-infrared (NIR) light regions, were synthesized by cold atmospheric pressure plasma assisted-aerosol deposition (CAPPA-AD) method. VOxCyNz films were deposited by injecting the liquid VOCl3 aerosols to cold atmospheric pressure air plasma jet, and spraying onto 10 Ω/□ glass/indium tin oxide substrates at substrate temperatures of 405–455 °C for a short exposure duration of 90 s, and post cured at 300 °C for 60 min. Oxygen deficiency dv in vanadium oxides (VO2.5-dv) and nano-crystalline grains of V2O5 (001) plane produced in VOxCyNz films by CAPPA-AD exhibit VIS and NIR dual band EC properties for VOxCyNz films. Different potentials applied on CAPPA-AD VOxCyNz films can regulate Li + intercalated into and de-intercalated out from the films for altering three different EC modes, including the switching warm to cool mode with NIR modulation at yellow color state for potentials turn from 0 V to −1.64 V, green and blue multi-colored states with VIS modulation for potentials change from −1.76 V to −2.4 V, and both VIS and NIR modulation for yellow and blue multi-colored states at the potentials of 0 V and −2.4 V, respectively.</div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":null,"pages":null},"PeriodicalIF":6.3000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024824003428","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}

引用次数: 0

Abstract

Organo-vanadium oxynitrides (VO_xC_yN_z) thin films, with multi-colored dual band electrochromic (EC) properties of individually selective visible (VIS) light-near-infrared (NIR) light regions, were synthesized by cold atmospheric pressure plasma assisted-aerosol deposition (CAPPA-AD) method. VO_xC_yN_z films were deposited by injecting the liquid VOCl₃ aerosols to cold atmospheric pressure air plasma jet, and spraying onto 10 Ω/□ glass/indium tin oxide substrates at substrate temperatures of 405–455 °C for a short exposure duration of 90 s, and post cured at 300 °C for 60 min. Oxygen deficiency dv in vanadium oxides (VO_2.5-dv) and nano-crystalline grains of V₂O₅ (001) plane produced in VO_xC_yN_z films by CAPPA-AD exhibit VIS and NIR dual band EC properties for VO_xC_yN_z films. Different potentials applied on CAPPA-AD VO_xC_yN_z films can regulate Li ⁺ intercalated into and de-intercalated out from the films for altering three different EC modes, including the switching warm to cool mode with NIR modulation at yellow color state for potentials turn from 0 V to −1.64 V, green and blue multi-colored states with VIS modulation for potentials change from −1.76 V to −2.4 V, and both VIS and NIR modulation for yellow and blue multi-colored states at the potentials of 0 V and −2.4 V, respectively.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

冷常压等离子体辅助气溶胶沉积多色双波段电致变色 VOxCyNz 薄膜

采用冷大气压等离子体辅助气溶胶沉积（CAPPA-AD）方法合成了具有多色双波段电致变色（EC）特性的有机钒氧氮化物（VOxCyNz）薄膜，这些薄膜可单独选择可见光（VIS）-近红外（NIR）光区。将液态 VOCl3 气溶胶注入冷常压空气等离子体射流，喷射到 10 Ω/□ 玻璃/氧化铟锡基底上，在 405-455 °C 的基底温度下短时间曝光 90 秒，然后在 300 °C 下固化 60 分钟，从而沉积出 VOxCyNz 薄膜。通过 CAPPA-AD 在 VOxCyNz 薄膜中生成的钒氧化物（VO2.5-dv）缺氧 dv 和 V2O5（001）面纳米晶粒显示出 VOxCyNz 薄膜的可见光和近红外双波段导电率特性。在 CAPPA-AD VOxCyNz 薄膜上施加不同的电位可以调节 Li + 在薄膜中的插层和脱插，从而改变三种不同的电致发光模式，包括在电位从 0 V 变为 -1.64 V 时，在黄色态的近红外调制下从暖到冷模式的切换；在电位从 -1.76 V 变为 -2.4 V 时，在 VIS 调制下的绿色和蓝色多彩态；以及在电位分别为 0 V 和 -2.4 V 时，在黄色和蓝色多彩态的 VIS 和近红外调制。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Solar Energy Materials and Solar Cells 工程技术-材料科学：综合

CiteScore

12.60

自引率

11.60%

发文量

513

审稿时长

47 days

期刊介绍： Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.