Preparation and property of PVA-based colorful coating composite reinforced with silica aerogel particles filled by high-loaded flame retardant

IF 2.2 4区 化学 Q3 CHEMISTRY, PHYSICAL Colloid and Polymer Science Pub Date : 2024-07-10 DOI:10.1007/s00396-024-05292-5
Yilin Feng, Ran Xu, Ying Li, Beibo Zhang, Jiali Wang, Zhi Chen, Luoxin Wang, Hua Wang
{"title":"Preparation and property of PVA-based colorful coating composite reinforced with silica aerogel particles filled by high-loaded flame retardant","authors":"Yilin Feng,&nbsp;Ran Xu,&nbsp;Ying Li,&nbsp;Beibo Zhang,&nbsp;Jiali Wang,&nbsp;Zhi Chen,&nbsp;Luoxin Wang,&nbsp;Hua Wang","doi":"10.1007/s00396-024-05292-5","DOIUrl":null,"url":null,"abstract":"<div><p>Hydrophilic mesoporous silica aerogel particles were synthesized via self-assembly of amphiphilic polymer (Ph8-PEG6-PEOS) and its instantaneous hydrolysis and condensation in the alkaline environment. Meanwhile, the capture and encapsulation of flame retardant (IPPP) and oil soluble dyes were successively completed during the two processes above. Observed by thermal field scanning electron microscopy (TFESEM), the average diameter of aerogel particles reached about 10 µm. BET surface area analysis displayed that the existence of oil-phase component (IPPP) can result in the expansion of pore diameter, and promote the evolution of mesopores into macropores. Then, IPPP@SiO<sub>2</sub> aerogel particles were utilized to improve the flame retardancy of polyvinyl alcohol (PVA) coatings implemented onto cotton yarns, by employing developed knife coating procedure in an aqueous suspension. The thermal stabilities and flammability behaviors of the samples were evaluated by thermogravimetric analysis (TGA), limiting oxygen index (LOI), and vertical burning test, respectively. Both thermal decomposition temperature and LOI value of coating composites gradually increased with the increment of IPPP@SiO<sub>2</sub>-n (<i>n</i> = 10, 30, 50, 70), attaching to the synchronous advancement in stretching property. Furthermore, coatings were thickened by degrees from 0.4 to 4 mm, based on knife coating in multi-stage layer-by-layer mode, to build an ordered porous structure with the assisted adhesion of PVA. The following sintering preserved the close packing of silica aerogel particles and facilitated the formation of a coherent porous monolithic material with excellent thermal insulation performance.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"302 10","pages":"1557 - 1571"},"PeriodicalIF":2.2000,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid and Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00396-024-05292-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Hydrophilic mesoporous silica aerogel particles were synthesized via self-assembly of amphiphilic polymer (Ph8-PEG6-PEOS) and its instantaneous hydrolysis and condensation in the alkaline environment. Meanwhile, the capture and encapsulation of flame retardant (IPPP) and oil soluble dyes were successively completed during the two processes above. Observed by thermal field scanning electron microscopy (TFESEM), the average diameter of aerogel particles reached about 10 µm. BET surface area analysis displayed that the existence of oil-phase component (IPPP) can result in the expansion of pore diameter, and promote the evolution of mesopores into macropores. Then, IPPP@SiO2 aerogel particles were utilized to improve the flame retardancy of polyvinyl alcohol (PVA) coatings implemented onto cotton yarns, by employing developed knife coating procedure in an aqueous suspension. The thermal stabilities and flammability behaviors of the samples were evaluated by thermogravimetric analysis (TGA), limiting oxygen index (LOI), and vertical burning test, respectively. Both thermal decomposition temperature and LOI value of coating composites gradually increased with the increment of IPPP@SiO2-n (n = 10, 30, 50, 70), attaching to the synchronous advancement in stretching property. Furthermore, coatings were thickened by degrees from 0.4 to 4 mm, based on knife coating in multi-stage layer-by-layer mode, to build an ordered porous structure with the assisted adhesion of PVA. The following sintering preserved the close packing of silica aerogel particles and facilitated the formation of a coherent porous monolithic material with excellent thermal insulation performance.

Graphical abstract

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
高负载阻燃剂填充二氧化硅气凝胶颗粒增强的 PVA 基多彩涂料复合材料的制备与性能
通过两亲性聚合物(Ph8-PEG6-PEOS)的自组装及其在碱性环境中的瞬时水解和缩合,合成了亲水性介孔二氧化硅气凝胶颗粒。与此同时,阻燃剂(IPPP)和油溶性染料的捕获和封装也在上述两个过程中相继完成。通过热场扫描电子显微镜(TFESEM)观察,气凝胶颗粒的平均直径约为 10 微米。BET 表面积分析表明,油相成分(IPPP)的存在会导致孔径扩大,并促进中孔向大孔演化。然后,通过在水悬浮液中采用开发的刀涂程序,利用 IPPP@SiO2 气凝胶颗粒提高了聚乙烯醇(PVA)涂层在棉纱上的阻燃性。样品的热稳定性和可燃性分别通过热重分析(TGA)、极限氧指数(LOI)和垂直燃烧试验进行了评估。涂层复合材料的热分解温度和 LOI 值都随着 IPPP@SiO2-n (n = 10、30、50、70)的增加而逐渐升高,这与拉伸性能的同步提高有关。此外,基于多级逐层模式的刀涂,涂层厚度从 0.4 毫米到 4 毫米不等,在 PVA 的辅助粘附下建立了有序的多孔结构。随后的烧结保留了二氧化硅气凝胶颗粒的紧密堆积,促进了具有优异隔热性能的多孔整体材料的形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Colloid and Polymer Science
Colloid and Polymer Science 化学-高分子科学
CiteScore
4.60
自引率
4.20%
发文量
111
审稿时长
2.2 months
期刊介绍: Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
期刊最新文献
Cellulose regenerated films obtained from the dissolution of cotton waste in ionic liquid Study on the efficient precipitation of germanium by Fe(OH)3 colloid generated by neutralization precipitation method Study on oil-in-water emulsions stabilized by SiO2 nanoparticles for enhancing oil recovery in harsh reservoirs A comparative experimental work on the drop-weight impact responses of thermoplastic polymers produced by additive manufacturing: combined influence of infill rate, test temperature, and filament material Multicompartment microparticles of SBM triblock terpolymers: Morphological transitions through homopolymer blending
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1