Synthesis and photocatalytic activity of zinc-doped copper sulfide with porous nanotubes structures

IF 5.3 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Research Bulletin Pub Date : 2024-07-05 DOI:10.1016/j.materresbull.2024.112990
Jinxing Cao, Dunpu Zhang, Hui Zhang
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Abstract

Zinc-doped copper sulfide (Zn-doped CuS) particles were synthesized by a hydrothermal method in EG (EG) solutions of different concentrations. The results showed that the concentration of EG could regulate the structural morphology of Zn-doped CuS, and the Zn-doped CuS formed in pure EG had a porous nanotubular structure, and its photocatalytic degradation efficiency of methylene blue was as high as 96 % under visible light with good stability. SEM and TEM imaging confirmed that the diameter of the Zn-doped CuS with porous nanotubular structure was 100 nm, and the wall thickness was 30 nm. This study presents a strategy to enhance the photocatalytic activity and performance of CuS for environmental applications through EG concentration and zinc doping.

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具有多孔纳米管结构的掺锌硫化铜的合成与光催化活性
采用水热法在不同浓度的EG溶液中合成了掺锌硫化铜(Zn-doped CuS)颗粒。结果表明,EG的浓度可以调节掺锌CuS的结构形态,在纯EG中形成的掺锌CuS具有多孔纳米管状结构,在可见光下对亚甲基蓝的光催化降解效率高达96%,且稳定性好。SEM 和 TEM 图像证实,具有多孔纳米管状结构的 Zn 掺杂 CuS 的直径为 100 nm,壁厚为 30 nm。本研究提出了一种通过 EG 浓度和锌掺杂来提高 CuS 光催化活性和性能以应用于环境的策略。
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来源期刊
Materials Research Bulletin
Materials Research Bulletin 工程技术-材料科学:综合
CiteScore
9.80
自引率
5.60%
发文量
372
审稿时长
42 days
期刊介绍: Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.
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