Preparation of efficient hydrochloric acid corrosion inhibitor from natural grease

IF 0.7 4区 工程技术 Q4 CHEMISTRY, APPLIED Polish Journal of Chemical Technology Pub Date : 2024-07-12 DOI:10.2478/pjct-2024-0021
Yi Luo, Zhongying Xu, Xuewen Cao, Yefei Wang, Shanjian Li, Gang Chen, Ying Tang
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Abstract

To alleviate the metal corrosion problem caused by incomplete acid discharge during pickling or acidification, a corrosion inhibitor, long chain fatty hydrazides (LCFH), with a significant corrosion inhibition effect was synthesized from natural grease. The corrosion inhibition and adsorption properties of LCFH on carbon steel in 1 M HCl solution were studied by static sample weight loss test, electrochemical impedance spectroscopy, and potentiodynamic polarization curve. The results showed that LCFH exhibits excellent corrosion inhibition performance in HCl solution. The inhibition efficiency increases with the increase of inhibitor concentration. When the concentration of LCFH is 40 mg/L, the inhibition efficiency can reach 97.9%. The potentiodynamic polarization curve shows that LCFH is a corrosion inhibitor that mainly inhibits the cathodic reaction. The corrosion inhibitor is spontaneously adsorbed on the surface of low-carbon steel in physical form, which conforms to the Langmuir isothermal adsorption model.
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利用天然油脂制备高效盐酸缓蚀剂
为了缓解酸洗或酸化过程中酸性物质排出不完全而导致的金属腐蚀问题,研究人员从天然油脂中合成了一种缓蚀效果显著的缓蚀剂--长链脂肪酰肼(LCFH)。通过静态样品失重测试、电化学阻抗光谱和电位极化曲线研究了 LCFH 在 1 M HCl 溶液中对碳钢的缓蚀和吸附性能。结果表明,LCFH 在盐酸溶液中表现出优异的缓蚀性能。抑制效率随抑制剂浓度的增加而提高。当 LCFH 的浓度为 40 mg/L 时,缓蚀效率可达 97.9%。电位极化曲线表明,LCFH 是一种主要抑制阴极反应的缓蚀剂。缓蚀剂以物理形式自发吸附在低碳钢表面,符合 Langmuir 等温吸附模型。
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来源期刊
Polish Journal of Chemical Technology
Polish Journal of Chemical Technology CHEMISTRY, APPLIED-ENGINEERING, CHEMICAL
CiteScore
1.70
自引率
10.00%
发文量
22
审稿时长
4.5 months
期刊介绍: Polish Journal of Chemical Technology is a peer-reviewed, international journal devoted to fundamental and applied chemistry, as well as chemical engineering and biotechnology research. It has a very broad scope but favors interdisciplinary research that bring chemical technology together with other disciplines. All authors receive very fast and comprehensive peer-review. Additionally, every published article is promoted to researchers working in the same field.
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