{"title":"Harnessing triplet excitons: Advances in luminescence metal coordination compounds","authors":"","doi":"10.1016/j.ccr.2024.216066","DOIUrl":null,"url":null,"abstract":"<div><p>The efficient utilization of triplet excitons serves as a key driver for the advancement of luminescence materials. Therefore, coordination compounds based on phosphorescence (PL) and thermally activated delayed fluorescence (TADF) mechanisms play a crucial role in effectively harnessing and transforming triplet excitons. Further exploration of their synthesis strategies and modulation methods for performance would be valuable in advancing the field of luminescence materials. In this review, the synthesis strategy, performance optimization, and research progress of metal complexes, clusters, and coordination polymers (CPs) with PL and TADF properties are summarized in detail. Moreover, leveraging the effective utilization of triplet excitons, these materials’ applications in photoelectric devices, information encryptions scintillators, sensing technologies, photocatalysis, and biological fields are also discussed.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004120","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The efficient utilization of triplet excitons serves as a key driver for the advancement of luminescence materials. Therefore, coordination compounds based on phosphorescence (PL) and thermally activated delayed fluorescence (TADF) mechanisms play a crucial role in effectively harnessing and transforming triplet excitons. Further exploration of their synthesis strategies and modulation methods for performance would be valuable in advancing the field of luminescence materials. In this review, the synthesis strategy, performance optimization, and research progress of metal complexes, clusters, and coordination polymers (CPs) with PL and TADF properties are summarized in detail. Moreover, leveraging the effective utilization of triplet excitons, these materials’ applications in photoelectric devices, information encryptions scintillators, sensing technologies, photocatalysis, and biological fields are also discussed.
期刊介绍：
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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