Pub Date : 2024-11-20DOI: 10.1016/j.ccr.2024.216327
Lin Lv, Tianpeng Zheng, Lu Tang, Zhaoran Wang, Wukun Liu
The successful clinical application of Pt-based drugs in anticancer therapy has stimulated interest in the development of metallodrugs. Numerous metal complexes with significant anticancer activity and fewer side effects have been reported. However, lack of stability is one of the problems restricting the development of metallodrugs. Schiff bases attract a lot of interest because of their excellent properties. They can stabilize various oxidation states of metals and be synthesized easily. Therefore, Schiff bases are known as “privileged ligands” for transition metals. Schiff base metal complexes have a wide range of activities, among which anticancer activity is remarkable and has a large potential for development. In this review, various Schiff base metal complexes with anticancer activities from 2015 to the present are summarized. Their structures, biological activities, targets, and mechanisms of action are discussed in depth. These complexes display a diverse array of structures and have been shown to possess significant anticancer activity. Notably, Schiff base metal complexes demonstrated anticancer activity through various mechanisms, including deoxyribonucleic acid (DNA) damage, reactive oxygen species (ROS) generation, mitochondrial pathway, endoplasmic reticulum stress (ERS), inhibition of epidermal growth factor receptor (EGFR), activation of immunogenic cell death (ICD), and the induction of apoptosis. This review may provide guidance to the development and mechanistic investigations of future anticancer metallodrugs.
{"title":"Recent advances of Schiff base metal complexes as potential anticancer agents","authors":"Lin Lv, Tianpeng Zheng, Lu Tang, Zhaoran Wang, Wukun Liu","doi":"10.1016/j.ccr.2024.216327","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216327","url":null,"abstract":"The successful clinical application of Pt-based drugs in anticancer therapy has stimulated interest in the development of metallodrugs. Numerous metal complexes with significant anticancer activity and fewer side effects have been reported. However, lack of stability is one of the problems restricting the development of metallodrugs. Schiff bases attract a lot of interest because of their excellent properties. They can stabilize various oxidation states of metals and be synthesized easily. Therefore, Schiff bases are known as “privileged ligands” for transition metals. Schiff base metal complexes have a wide range of activities, among which anticancer activity is remarkable and has a large potential for development. In this review, various Schiff base metal complexes with anticancer activities from 2015 to the present are summarized. Their structures, biological activities, targets, and mechanisms of action are discussed in depth. These complexes display a diverse array of structures and have been shown to possess significant anticancer activity. Notably, Schiff base metal complexes demonstrated anticancer activity through various mechanisms, including deoxyribonucleic acid (DNA) damage, reactive oxygen species (ROS) generation, mitochondrial pathway, endoplasmic reticulum stress (ERS), inhibition of epidermal growth factor receptor (EGFR), activation of immunogenic cell death (ICD), and the induction of apoptosis. This review may provide guidance to the development and mechanistic investigations of future anticancer metallodrugs.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"23 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142678784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-20DOI: 10.1016/j.ccr.2024.216316
Leila Khalili, Gholamreza Dehghan, Hamed Hamishehkar, Leonid G. Voskressensky, Alireza Khataee
The requirements for non-invasive visualization and precise treatment of cancers are ongoing, demanding continuous efforts to enhance the development of potent theranostic modalities. Notably, groundbreaking advancements in nanotechnology have positioned layered double hydroxides (LDHs) at the forefront of biomedical research. LDH carriers are highly valued in medicinal applications due to their ability to integrate the benefits of multiple modalities, thus paving a promising path to clinical use. Recent breakthroughs in the rational design of theranostics have underscored the potential of gadolinium (Gd)-doped LDHs, which are particularly well-suited for the diagnosis of diseases. This review focuses on providing a comprehensive overview of the latest significant advances in Gd-LDH assemblies in cancer theranostics, with an emphasis on a bottom-up intercalation strategy, influential factors, and formulation methodologies. These aspects are crucial for researchers developing innovative intercalation processes and novel multi-component materials. Additionally, we address the kinetic inertness and colloidal stability of Gd-intercalated LDHs, which are essential for advanced theranostic applications. Finally, we present a forward-looking discussion on the challenges and future opportunities related to Gd-LDH complexes, aiming to identify the obstacles researchers encounter in advancing the clinical application of Gd-LDHs and to offer potential insights for further research.
{"title":"Development of theranostic nanoplatforms based on gadolinium-layered double hydroxides for magnetic resonance imaging-guided stimuli-enhanced chemotherapy","authors":"Leila Khalili, Gholamreza Dehghan, Hamed Hamishehkar, Leonid G. Voskressensky, Alireza Khataee","doi":"10.1016/j.ccr.2024.216316","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216316","url":null,"abstract":"The requirements for non-invasive visualization and precise treatment of cancers are ongoing, demanding continuous efforts to enhance the development of potent theranostic modalities. Notably, groundbreaking advancements in nanotechnology have positioned layered double hydroxides (LDHs) at the forefront of biomedical research. LDH carriers are highly valued in medicinal applications due to their ability to integrate the benefits of multiple modalities, thus paving a promising path to clinical use. Recent breakthroughs in the rational design of theranostics have underscored the potential of gadolinium (Gd)-doped LDHs, which are particularly well-suited for the diagnosis of diseases. This review focuses on providing a comprehensive overview of the latest significant advances in Gd-LDH assemblies in cancer theranostics, with an emphasis on a bottom-up intercalation strategy, influential factors, and formulation methodologies. These aspects are crucial for researchers developing innovative intercalation processes and novel multi-component materials. Additionally, we address the kinetic inertness and colloidal stability of Gd-intercalated LDHs, which are essential for advanced theranostic applications. Finally, we present a forward-looking discussion on the challenges and future opportunities related to Gd-LDH complexes, aiming to identify the obstacles researchers encounter in advancing the clinical application of Gd-LDHs and to offer potential insights for further research.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"19 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142678786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-20DOI: 10.1016/j.ccr.2024.216295
Muhammad Zahid, Ahmed Ismail, Muhammad Farooq Khan, Nauman Ali, Syedul Hasnain Bakhtiar, Atef El Jery, Basem Al Alwan, Rizwan Ullah, Fazal Raziq, Weidong He, K.H.L. Zhang, Jiabao Yi, Xiaoqiang Wu, Sharafat Ali, Liang Qiao
The superior hydrogenation of carbonyl (C=O) bonds in α, β-unsaturated aldehydes (UAL) has attracted considerable attention from economic and industrial perspectives. Several efforts have been made because hydrogenation of the olefin (CC) bond is kinetically and thermodynamically preferred over CO bond hydrogenation. Hence, to achieve superior hydrogenation of the targeted CO bond, highly active and durable catalysts are required. Herein, functional hydrogenation catalytic materials and their working principles are thoroughly discussed and apprehended. The active role of noble, non-noble mono/bi-metal catalysts and support materials along with the key factors arising from the structure of catalysts that promotes the CO bond selectivity were thoroughly disclosed. Essential techniques and strategies, such as tuning the surface electronic properties and generating electro-nucleophilic sites via synergistic effects, geometric effects, and applying a confinement or steric effect for improved CO bond hydrogenation, are briefly apprehended. The aggregate analysis suggested two crucial approaches for the engineering of a vastly selective and stable hydrogenation catalytic material: (1) tuning the electronic number of an active noble metal and (2) stabilizing the active noble metal by selecting distinctive support materials, especially metal-organic frameworks (MOFs) owing to its special physiochemical features, to construct robust metal-support interactions. In the end, various crucial key factors and additional active sites that are also encountered to attain the desired selectivity of the CO bond are concisely reviewed. Regardless of the numerous successes, significant development is still essential to expand our understanding of the preferential hydrogenation of challenging CO bonds in UAL.
从经济和工业的角度来看，α、β-不饱和醛（UAL）中羰基（C=O）键的氢化性能优越，引起了广泛关注。由于烯烃（CC）键的氢化在动力学和热力学上都优于 CO 键的氢化，因此人们做出了许多努力。因此，要实现目标 CO 键的良好氢化，需要高活性和耐久性催化剂。本文对功能性氢化催化材料及其工作原理进行了深入探讨和理解。深入揭示了惰性、非惰性单/双金属催化剂和支撑材料的活性作用，以及催化剂结构中促进 CO 键选择性的关键因素。此外，还简要介绍了一些重要的技术和策略，如通过协同效应、几何效应和应用限制或立体效应来调整表面电子特性和产生亲电核位点，以改善 CO 键氢化。综合分析表明了设计具有高度选择性和稳定性的氢化催化材料的两个关键方法：(1) 调节活性贵金属的电子数；(2) 通过选择独特的支撑材料，尤其是具有特殊理化特性的金属有机框架（MOFs）来稳定活性贵金属，从而构建稳健的金属-支撑相互作用。最后，还简明扼要地回顾了为获得理想的一氧化碳键选择性而遇到的各种关键因素和额外的活性位点。尽管取得了众多成功，但要加深我们对 UAL 中具有挑战性的 CO 键优先氢化的理解，仍有必要取得重大进展。
{"title":"Understanding the working principle of sustainable catalytic materials for selective hydrogenation of carbonyls bond in α, β-unsaturated aldehydes","authors":"Muhammad Zahid, Ahmed Ismail, Muhammad Farooq Khan, Nauman Ali, Syedul Hasnain Bakhtiar, Atef El Jery, Basem Al Alwan, Rizwan Ullah, Fazal Raziq, Weidong He, K.H.L. Zhang, Jiabao Yi, Xiaoqiang Wu, Sharafat Ali, Liang Qiao","doi":"10.1016/j.ccr.2024.216295","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216295","url":null,"abstract":"The superior hydrogenation of carbonyl (C=O) bonds in α, β-unsaturated aldehydes (UAL) has attracted considerable attention from economic and industrial perspectives. Several efforts have been made because hydrogenation of the olefin (C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>C) bond is kinetically and thermodynamically preferred over C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond hydrogenation. Hence, to achieve superior hydrogenation of the targeted C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond, highly active and durable catalysts are required. Herein, functional hydrogenation catalytic materials and their working principles are thoroughly discussed and apprehended. The active role of noble, non-noble mono/bi-metal catalysts and support materials along with the key factors arising from the structure of catalysts that promotes the C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond selectivity were thoroughly disclosed. Essential techniques and strategies, such as tuning the surface electronic properties and generating electro-nucleophilic sites via synergistic effects, geometric effects, and applying a confinement or steric effect for improved C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond hydrogenation, are briefly apprehended. The aggregate analysis suggested two crucial approaches for the engineering of a vastly selective and stable hydrogenation catalytic material: (1) tuning the electronic number of an active noble metal and (2) stabilizing the active noble metal by selecting distinctive support materials, especially metal-organic frameworks (MOFs) owing to its special physiochemical features, to construct robust metal-support interactions. In the end, various crucial key factors and additional active sites that are also encountered to attain the desired selectivity of the C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bond are concisely reviewed. Regardless of the numerous successes, significant development is still essential to expand our understanding of the preferential hydrogenation of challenging C<img alt=\"double bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/dbnd.gif\" style=\"vertical-align:middle\"/>O bonds in UAL.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"11 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142673495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-19DOI: 10.1016/j.ccr.2024.216320
Yu Cui, Kuan Chang, Qinzhi Wang, Yijian Zhao
Gas detection technology has assumed an increasingly pivotal role within human society, spanning domains from biomedicine to environmental monitoring, food safety, and national defense. Compared with solid and liquid samples, gas molecules at lower concentrations can be difficult recognized and have always been a challenge. Surface-enhanced Raman scattering (SERS) has gained widespread adoption for trace analysis by virtue of their good selectivity, high sensitivity and superior enrichment performance of enhanced substrates, which also has significant advantages in gas detection. However, few works have focused on the critical reviews of this fascinating SERS method applied in the field of gas sensing. It is worth noting that some of the reviews seem to be similar in that they all focus on a specific topic, either on environmental monitoring or related to human health. Thus, in this work, recent advances and future challenges of SERS in gas sensing are firstly and systematically reviewed. The basic principles of SERS and its application in gas sensing were comprehensively summarized. Subsequently, SERS substrates applied in gas sensing, including plasmonic metal nanoparticles (PMNPs), metal oxide semiconductor (MOS), metal-organic framework (MOF), MXene, etc. were systematically reviewed. In addition, the applications of SERS method used in the detection of toxic, hazardous gases and gaseous biomarkers were emphasized, such as environmental monitoring, human health and disease diagnosis, food safety, and national defense security. Finally, this paper also discussed the challenges and perspectives of SERS method, which will provide innovative ideas for design, construction and application of SERS sensors in the gas sensing.
{"title":"Advances of surface-enhanced Raman scattering in gas sensing","authors":"Yu Cui, Kuan Chang, Qinzhi Wang, Yijian Zhao","doi":"10.1016/j.ccr.2024.216320","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216320","url":null,"abstract":"Gas detection technology has assumed an increasingly pivotal role within human society, spanning domains from biomedicine to environmental monitoring, food safety, and national defense. Compared with solid and liquid samples, gas molecules at lower concentrations can be difficult recognized and have always been a challenge. Surface-enhanced Raman scattering (SERS) has gained widespread adoption for trace analysis by virtue of their good selectivity, high sensitivity and superior enrichment performance of enhanced substrates, which also has significant advantages in gas detection. However, few works have focused on the critical reviews of this fascinating SERS method applied in the field of gas sensing. It is worth noting that some of the reviews seem to be similar in that they all focus on a specific topic, either on environmental monitoring or related to human health. Thus, in this work, recent advances and future challenges of SERS in gas sensing are firstly and systematically reviewed. The basic principles of SERS and its application in gas sensing were comprehensively summarized. Subsequently, SERS substrates applied in gas sensing, including plasmonic metal nanoparticles (PMNPs), metal oxide semiconductor (MOS), metal-organic framework (MOF), MXene, etc. were systematically reviewed. In addition, the applications of SERS method used in the detection of toxic, hazardous gases and gaseous biomarkers were emphasized, such as environmental monitoring, human health and disease diagnosis, food safety, and national defense security. Finally, this paper also discussed the challenges and perspectives of SERS method, which will provide innovative ideas for design, construction and application of SERS sensors in the gas sensing.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"174 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142670990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-19DOI: 10.1016/j.ccr.2024.216326
Writakshi Mandal, Sahel Fajal, Aamod V. Desai, Sujit K. Ghosh
In recent years, environmental pollution and its effects have demanded attention from all over the world. In this context, water pollution has been regarded as one of the biggest threats to all living forms among all types of pollution in recent years, and things are forecasted to get worse if remediating steps are not adopted soon. Water recycling has gained importance in the twenty-first century as more areas of the world experience a water crisis. Given this, ground-water pollution by heavy metal-based toxic oxo-pollutants such as CrO42−, Cr2O72−, AsO43−, SeO32−, SeO42−, TcO4−, ReO4− etc. have been becoming rapidly growing global concerns and pose a major risk to both human health and the environment. These hazardous and persistent chemicals have been designated as priority pollutants by the US Environmental Protection Agency (EPA) due to their extreme toxicity following bioaccumulation. Therefore, it is crucial to get rid of them from contaminated water in an efficient manner. In this regard, now a days, Advanced Functional Porous Materials (AFPMs) such as metal-organic frameworks (MOFs), porous organic polymers (POPs), covalent organic frameworks (COFs), and porous hybrid composite have drawn significant attention from researchers looking into wastewater treatment owing to their advantages of tunable porosity, high surface area, and an abundance of functional groups over traditional adsorbents. This review provides an overview of the latest advancements in Advanced Functional Porous Materials, including MOFs and related porous materials, used as effective adsorbents to remove harmful oxoanions derived from heavy metals from contaminated water. Additionally, the review suggests practical solutions for ensuring the safety and cleanliness of drinking water. Furthermore, their adsorption mechanisms are discussed which may enable better designing of new MOFs/AFPMs-based adsorbents with superior performance for future study as well as for understanding the adsorption process between MOFs/AFPMs and heavy metal oxoanions contaminants. Lastly, in order to fully comprehend the developing prospects for the future, the potential and challenges of MOFs/AFPMs were thoroughly discussed.
{"title":"Metal-organic frameworks (MOFs) and related other advanced porous materials for sequestration of heavy metal-based toxic oxo-pollutants from water","authors":"Writakshi Mandal, Sahel Fajal, Aamod V. Desai, Sujit K. Ghosh","doi":"10.1016/j.ccr.2024.216326","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216326","url":null,"abstract":"In recent years, environmental pollution and its effects have demanded attention from all over the world. In this context, water pollution has been regarded as one of the biggest threats to all living forms among all types of pollution in recent years, and things are forecasted to get worse if remediating steps are not adopted soon. Water recycling has gained importance in the twenty-first century as more areas of the world experience a water crisis. Given this, ground-water pollution by heavy metal-based toxic oxo-pollutants such as CrO<sub>4</sub><sup>2−</sup>, Cr<sub>2</sub>O<sub>7</sub><sup>2−</sup>, AsO<sub>4</sub><sup>3−</sup>, SeO<sub>3</sub><sup>2−</sup>, SeO<sub>4</sub><sup>2−</sup>, TcO<sub>4</sub><sup>−</sup>, ReO<sub>4</sub><sup>−</sup> etc. have been becoming rapidly growing global concerns and pose a major risk to both human health and the environment. These hazardous and persistent chemicals have been designated as priority pollutants by the US Environmental Protection Agency (EPA) due to their extreme toxicity following bioaccumulation. Therefore, it is crucial to get rid of them from contaminated water in an efficient manner. In this regard, now a days, Advanced Functional Porous Materials (AFPMs) such as metal-organic frameworks (MOFs), porous organic polymers (POPs), covalent organic frameworks (COFs), and porous hybrid composite have drawn significant attention from researchers looking into wastewater treatment owing to their advantages of tunable porosity, high surface area, and an abundance of functional groups over traditional adsorbents. This review provides an overview of the latest advancements in Advanced Functional Porous Materials, including MOFs and related porous materials, used as effective adsorbents to remove harmful oxoanions derived from heavy metals from contaminated water. Additionally, the review suggests practical solutions for ensuring the safety and cleanliness of drinking water. Furthermore, their adsorption mechanisms are discussed which may enable better designing of new MOFs/AFPMs-based adsorbents with superior performance for future study as well as for understanding the adsorption process between MOFs/AFPMs and heavy metal oxoanions contaminants. Lastly, in order to fully comprehend the developing prospects for the future, the potential and challenges of MOFs/AFPMs were thoroughly discussed.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"112 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142671098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Black phosphorene (BP), an exciting allotrope of phosphorus, has sparked widespread attention owing to its unique physicochemical characteristics and numerous potentials in the environmental, energy, and biological sectors. The current review delves further into BP, concentrating on its layered structure, unusual features, and broad applications. Methods of synthesis of BP, such as liquid exfoliation, chemical vapor deposition, and mechanical exfoliation, are reviewed, and characterization procedures critical to ensuring the quality of BP are described. Its anisotropic mechanical, electrical, and optical properties are investigated using insights gained from its hexagonal lattice atomic structure and puckered layers. In environmental contexts, BP shows potential for water purification due to its strong adsorption and degradation capabilities against various contaminants, including dyes, medicines, pesticides, heavy metals, and organic compounds. Its potential in environmental sensing is also emphasized, notably for detecting gasses, heavy metals, and pollutants. Moving on to energy applications, BP is used in batteries, supercapacitors, and hydrogen generation, where its unique electrical and structural properties improve energy storage and conversion efficiency. BP improves medication delivery systems in biomedical applications by providing biocompatibility and customizable delivery capabilities. Furthermore, its biological imaging and diagnostics applications are reviewed, focusing on optical properties and contrast enhancement capabilities. Nonetheless, despite BP's significant potential, serious hurdles persist. Issues including stability under ambient settings, large-scale synthesis limits, and biocompatibility difficulties require resolution for more considerable practical use. The paper concludes by exploring future challenges and solutions to motivate readers. In summary, BP stands as a flexible material prepared to drive innovation in environmental, energy, and biological applications, although attaining its revolutionary influence will depend on overcoming present technological, scientific, and scaling limitations.
黑膦石（BP）是一种令人兴奋的磷的同素异形体，由于其独特的物理化学特性以及在环境、能源和生物领域的众多潜力，引发了广泛的关注。本综述将进一步深入探讨 BP，重点关注其层状结构、不寻常的特征和广泛的应用。文章回顾了 BP 的合成方法，如液体剥离、化学气相沉积和机械剥离，并介绍了对确保 BP 质量至关重要的表征程序。利用从六方晶格原子结构和皱褶层中获得的洞察力，对其各向异性的机械、电气和光学特性进行了研究。在环境方面，由于 BP 对各种污染物（包括染料、药物、杀虫剂、重金属和有机化合物）具有很强的吸附和降解能力，因此具有净化水的潜力。它在环境传感方面的潜力也得到了强调，特别是在检测气体、重金属和污染物方面。在能源应用方面，BP 可用于电池、超级电容器和制氢，其独特的电气和结构特性可提高能量存储和转换效率。英国石油公司通过提供生物兼容性和可定制的给药能力，改善了生物医学应用中的给药系统。此外，还对其生物成像和诊断应用进行了审查，重点关注其光学特性和对比度增强能力。然而，尽管 BP 具有巨大的潜力，但仍然存在严重的障碍。需要解决的问题包括环境下的稳定性、大规模合成的限制以及生物相容性方面的困难，以实现更广泛的实际应用。本文最后探讨了未来的挑战和解决方案，以激发读者的兴趣。总之，BP 是一种灵活的材料，可推动环境、能源和生物应用领域的创新，但要实现其革命性的影响，还需要克服目前的技术、科学和规模限制。
{"title":"Black phosphorene: A versatile allotrope revolutionizing environmental, energy, and biomedical applications","authors":"Soumya Ranjan Mishra, Vishal Gadore, Vishwajit Chavda, Subhasree Panda, Saptarshi Roy, Pooja Sahoo, Lipi Pradhan, Harshita Rai, Shyam S. Pandey, Md. Ahmaruzzaman","doi":"10.1016/j.ccr.2024.216345","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216345","url":null,"abstract":"Black phosphorene (BP), an exciting allotrope of phosphorus, has sparked widespread attention owing to its unique physicochemical characteristics and numerous potentials in the environmental, energy, and biological sectors. The current review delves further into BP, concentrating on its layered structure, unusual features, and broad applications. Methods of synthesis of BP, such as liquid exfoliation, chemical vapor deposition, and mechanical exfoliation, are reviewed, and characterization procedures critical to ensuring the quality of BP are described. Its anisotropic mechanical, electrical, and optical properties are investigated using insights gained from its hexagonal lattice atomic structure and puckered layers. In environmental contexts, BP shows potential for water purification due to its strong adsorption and degradation capabilities against various contaminants, including dyes, medicines, pesticides, heavy metals, and organic compounds. Its potential in environmental sensing is also emphasized, notably for detecting gasses, heavy metals, and pollutants. Moving on to energy applications, BP is used in batteries, supercapacitors, and hydrogen generation, where its unique electrical and structural properties improve energy storage and conversion efficiency. BP improves medication delivery systems in biomedical applications by providing biocompatibility and customizable delivery capabilities. Furthermore, its biological imaging and diagnostics applications are reviewed, focusing on optical properties and contrast enhancement capabilities. Nonetheless, despite BP's significant potential, serious hurdles persist. Issues including stability under ambient settings, large-scale synthesis limits, and biocompatibility difficulties require resolution for more considerable practical use. The paper concludes by exploring future challenges and solutions to motivate readers. In summary, BP stands as a flexible material prepared to drive innovation in environmental, energy, and biological applications, although attaining its revolutionary influence will depend on overcoming present technological, scientific, and scaling limitations.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"22 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142670989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Over the preceding years, nickel (Ni) and its compounds have been increasingly employed in various aspects of human social life, metallurgical/industrial manufactures, healthcare and chemical processes. Although Ni is considered as an essential trace element in biological system, excessive intake or metabolic deficiency of Ni2+ ions may cause detrimental health effects to the living organisms. Therefore, a facile and accurate detection of Ni2+, especially in environment and biological settings, is of huge significance. As an efficient detection method, assaying Ni2+ using optical (colorimetric and/or fluorogenic) sensors has experienced quite a vigorous growth period with large number of excellent researches. Nanomaterial-based optical sensors including metal nanoparticles (MNPs), quantum dots (QDs), and carbon dots (CDs) offer distinct advantages over conventional small-molecule organic and inorganic sensors. This study mainly provides an overview of the recent advancements and challenges related to the design strategies of various optical nanosensors to selectively detect Ni2+ ion. Emphasis has also been placed on comparing the sensing performance of various nanosensors along with exploring future perspectives.
{"title":"Nanoparticles and quantum dots as emerging optical sensing platforms for Ni(II) detection: Recent approaches and perspectives","authors":"Sudhanshu Naithani, , Pooja Sharma, Samar Layek, Franck Thetiot, Tapas Goswami, Sushil Kumar","doi":"10.1016/j.ccr.2024.216331","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216331","url":null,"abstract":"Over the preceding years, nickel (Ni) and its compounds have been increasingly employed in various aspects of human social life, metallurgical/industrial manufactures, healthcare and chemical processes. Although Ni is considered as an essential trace element in biological system, excessive intake or metabolic deficiency of Ni<sup>2+</sup> ions may cause detrimental health effects to the living organisms. Therefore, a facile and accurate detection of Ni<sup>2+</sup>, especially in environment and biological settings, is of huge significance. As an efficient detection method, assaying Ni<sup>2+</sup> using optical (colorimetric and/or fluorogenic) sensors has experienced quite a vigorous growth period with large number of excellent researches. Nanomaterial-based optical sensors including metal nanoparticles (MNPs), quantum dots (QDs), and carbon dots (CDs) offer distinct advantages over conventional small-molecule organic and inorganic sensors. This study mainly provides an overview of the recent advancements and challenges related to the design strategies of various optical nanosensors to selectively detect Ni<sup>2+</sup> ion. Emphasis has also been placed on comparing the sensing performance of various nanosensors along with exploring future perspectives.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"21 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-16DOI: 10.1016/j.ccr.2024.216328
Tian Liu , Qi Lu , Hao Zhang , Fudan Dong , Zhonggui He , Jin Sun , Bingjun Sun
Biomimetic carriers utilizing cells and cellular components revolutionize the field of anticancer drug delivery systems. Existing reviews in this field have predominantly approached biomimetic drug delivery systems by focusing on either the carrier or the payload. However, recognizing the intrinsic inseparability of the drug and the biomimetic carrier is imperative, as their mutual influences decisively shape the drug delivery system. This review delineated the recent progress in biomimetic carriers for antitumor therapeutics from a distinct perspective, concentrating on the relationship between the drug and the carrier. The relationship involves drug-loading mode, the loading position, and the mechanism of drug-release strategies. This review highlighted the crucial roles of drug loading morphologies and loading positions in enhancing the efficiency of carrier delivery and overcoming barriers to cancer treatment. Additionally, innovative strategies for controlled drug release from biomimetic carriers were summarized, and an extensive discussion on the future prospects and potential challenges in this field was provided.
{"title":"Biomimetic drug delivery for anticancer: Focusing on the relationship between drugs and biomimetic carriers","authors":"Tian Liu , Qi Lu , Hao Zhang , Fudan Dong , Zhonggui He , Jin Sun , Bingjun Sun","doi":"10.1016/j.ccr.2024.216328","DOIUrl":"10.1016/j.ccr.2024.216328","url":null,"abstract":"<div><div>Biomimetic carriers utilizing cells and cellular components revolutionize the field of anticancer drug delivery systems. Existing reviews in this field have predominantly approached biomimetic drug delivery systems by focusing on either the carrier or the payload. However, recognizing the intrinsic inseparability of the drug and the biomimetic carrier is imperative, as their mutual influences decisively shape the drug delivery system. This review delineated the recent progress in biomimetic carriers for antitumor therapeutics from a distinct perspective, concentrating on the relationship between the drug and the carrier. The relationship involves drug-loading mode, the loading position, and the mechanism of drug-release strategies. This review highlighted the crucial roles of drug loading morphologies and loading positions in enhancing the efficiency of carrier delivery and overcoming barriers to cancer treatment. Additionally, innovative strategies for controlled drug release from biomimetic carriers were summarized, and an extensive discussion on the future prospects and potential challenges in this field was provided.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216328"},"PeriodicalIF":20.3,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-15DOI: 10.1016/j.ccr.2024.216329
Peiyuan Liu , Xiaoyang Zhu , Xu Ran , Hengchang Bi , Xiao Huang , Ning Gu
Gas–solid interactions that involve various chemical and physical processes are important in various research fields such as gas storage and separation, catalysis, and gas sensing. The design and study of gas–interfacing materials and processes require thorough considerations on the structural, chemical and electrical properties at the gas–solid interfaces. However, due to the large number of materials available, conventional trial-and-error attempts take long development cycles and high costs. The recent advancement of machine learning (ML) for gas–solid interactions adequately addresses this challenge and provides new insights into materials design and property prediction, thus deserving a critical review and in-depth discussion. In this contribution, we reviewed the application of various ML methods in the development of materials and devices involving gas–solid interactions, focusing on the elaboration of the structure–property relationship established by ML models. We also discussed the potential opportunities and challenges for the future development in this field.
涉及各种化学和物理过程的气固相互作用在气体储存和分离、催化和气体传感等多个研究领域都非常重要。设计和研究气体界面材料和工艺需要对气固界面的结构、化学和电气特性进行全面考虑。然而，由于可用材料数量众多，传统的试错尝试需要耗费较长的开发周期和较高的成本。最近，针对气固相互作用的机器学习（ML）技术的发展充分应对了这一挑战，并为材料设计和性能预测提供了新的见解，因此值得我们进行深入研究和讨论。在这篇论文中，我们回顾了各种 ML 方法在涉及气固相互作用的材料和设备开发中的应用，重点阐述了 ML 模型建立的结构-性能关系。我们还讨论了该领域未来发展的潜在机遇和挑战。
{"title":"Machine learning for gas–solid interaction materials and devices","authors":"Peiyuan Liu , Xiaoyang Zhu , Xu Ran , Hengchang Bi , Xiao Huang , Ning Gu","doi":"10.1016/j.ccr.2024.216329","DOIUrl":"10.1016/j.ccr.2024.216329","url":null,"abstract":"<div><div>Gas–solid interactions that involve various chemical and physical processes are important in various research fields such as gas storage and separation, catalysis, and gas sensing. The design and study of gas–interfacing materials and processes require thorough considerations on the structural, chemical and electrical properties at the gas–solid interfaces. However, due to the large number of materials available, conventional trial-and-error attempts take long development cycles and high costs. The recent advancement of machine learning (ML) for gas–solid interactions adequately addresses this challenge and provides new insights into materials design and property prediction, thus deserving a critical review and in-depth discussion. In this contribution, we reviewed the application of various ML methods in the development of materials and devices involving gas–solid interactions, focusing on the elaboration of the structure–property relationship established by ML models. We also discussed the potential opportunities and challenges for the future development in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216329"},"PeriodicalIF":20.3,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-11-15DOI: 10.1016/j.ccr.2024.216325
Gyudong Lee, Imteaz Ahmed, Md Abul Hossain, Hye Jin Lee, Sung Hwa Jhung
Recently, metal-organic frameworks (MOFs) have attracted much attention because of their huge porosity, designable structure/pore, possible functionalization, and potential applications. Among them, a Zr, Hf, or Ce-benezenetricarboxylate named MOF-808 is very attractive thanks to its wide pore and good stability, together with the facile functionalization; therefore, the development of MOF-808 both in the synthesis and application is remarkable. However, to the best of our knowledge, there is no review paper on MOF-808. Here, we summarize the recent achievements in the preparation and modification/functionalization of MOF-808. Moreover, the application of MOF-808 in adsorption will also be analyzed. Finally, a future prospect will be given to readers who are interested in MOFs and relevant fields.
{"title":"Preparation and functionalization of metal-organic frameworks, MOF-808s, and their application in adsorption","authors":"Gyudong Lee, Imteaz Ahmed, Md Abul Hossain, Hye Jin Lee, Sung Hwa Jhung","doi":"10.1016/j.ccr.2024.216325","DOIUrl":"10.1016/j.ccr.2024.216325","url":null,"abstract":"<div><div>Recently, metal-organic frameworks (MOFs) have attracted much attention because of their huge porosity, designable structure/pore, possible functionalization, and potential applications. Among them, a Zr, Hf, or Ce-benezenetricarboxylate named MOF-808 is very attractive thanks to its wide pore and good stability, together with the facile functionalization; therefore, the development of MOF-808 both in the synthesis and application is remarkable. However, to the best of our knowledge, there is no review paper on MOF-808. Here, we summarize the recent achievements in the preparation and modification/functionalization of MOF-808. Moreover, the application of MOF-808 in adsorption will also be analyzed. Finally, a future prospect will be given to readers who are interested in MOFs and relevant fields.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"524 ","pages":"Article 216325"},"PeriodicalIF":20.3,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C) bond is kinetically and thermodynamically preferred over C
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