Coordination Chemistry Reviews最新文献

Luminescent lanthanide hybrid materials: from molecular design to anti-counterfeiting application 发光镧系杂化材料：从分子设计到防伪应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-13 DOI: 10.1016/j.ccr.2025.217474

Di Zhao , Xinyi Xu , Daqing Yang , Huanrong Li

Information security and anti-counterfeiting technologies are essential for protecting financial systems, brand integrity, and national security. Conventional anti-counterfeiting approaches, often static and single-functional, are increasingly inadequate against evolving counterfeiting strategies. Lanthanide luminescent materials, owing to their unique 4f-4f electronic transitions, long-lived emission, high color purity, and exceptional responsiveness to external stimuli, have emerged as promising candidates. This review summarizes recent advances in lanthanide-based luminescent systems for anti-counterfeiting applications, emphasizing molecular design strategies and structural engineering to enhance luminescence efficiency, stability, and dynamic optical responses to light, temperature, mechanical forces, and chemical reagents. Representative material classes, including lanthanide metal-organic frameworks, polymers, hydrogels, doped inorganic nanomaterials, covalent and hydrogen-bonded organic frameworks, and scintillators, are highlighted. Furthermore, advanced encryption strategies such as time-gated luminescence, persistent phosphorescence, and multimode optical responses are discussed as pathways toward multi-level information protection. Finally, key challenges limiting practical implementation are outlined, and future research directions are proposed to improve the adaptability, efficiency, and scalability of these materials in next-generation information security technologies.

信息安全和防伪技术对于保护金融系统、品牌完整性和国家安全至关重要。传统的防伪方法往往是静态的和单一功能的，越来越不足以应对不断发展的假冒战略。镧系发光材料由于其独特的4f-4f电子跃迁、长寿命发射、高颜色纯度和对外部刺激的特殊响应性，已成为有希望的候选材料。本文综述了近年来镧系发光防伪系统的研究进展，重点介绍了分子设计策略和结构工程，以提高发光效率、稳定性以及对光、温度、机械力和化学试剂的动态光学响应。重点介绍了具有代表性的材料类别，包括镧系金属有机框架、聚合物、水凝胶、掺杂无机纳米材料、共价和氢键有机框架以及闪烁体。此外，还讨论了时间门控发光、持续磷光和多模光响应等高级加密策略作为多级信息保护的途径。最后，概述了限制实际实施的关键挑战，并提出了未来的研究方向，以提高这些材料在下一代信息安全技术中的适应性、效率和可扩展性。

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引用次数: 0

Luminescent hydrogen bonded frameworks (HOFs) and covalent organic frameworks (COFs) for biomedical applications 发光氢键框架（HOFs）和共价有机框架（COFs）生物医学应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-13 DOI: 10.1016/j.ccr.2025.217453

Xiao-Ping Zhan , Shao-Qi Guan , Ya-Ping Wang , Jun Shen , Mei Pan

Hydrogen-bonded organic frameworks (HOFs) and covalent organic frameworks (COFs) are two prominent classes of crystalline porous materials assembled from organic building blocks through hydrogen bonds and covalent bonds, respectively. Their well-defined structures, tunable porosity, and designable functionalities have attracted extensive attention in various fields. In particular, luminescent HOFs and COFs exhibit remarkable advantages in biomedical applications, including excellent photostability, low toxicity, modular design for functionalization, and strong luminescent signals suitable for cancer therapy, bioimaging, antibacterial, and biosensing. This review summarizes the fundamental characteristics and recent research progress of luminescent HOFs and COFs and their underlying emission mechanisms. Furthermore, it provides an in-depth discussion on the design strategies for constructing photoactive HOFs/COFs and highlights their applications in cancer therapy, bioimaging, antibacterial, and biosensing. Finally, a perspective is offered on the existing challenges and future directions of luminescent HOFs/COFs in biomedical applications. This review aims to provide valuable insights for researchers dedicated to advancing luminescent HOFs/COFs-based materials for biomedical applications.

氢键有机框架（hof）和共价有机框架（COFs）是两种由有机构建块通过氢键和共价键组装而成的晶体多孔材料。其明确的结构、可调的孔隙度和可设计的功能在各个领域引起了广泛的关注。特别是，发光的hof和COFs在生物医学应用中具有显着的优势，包括优异的光稳定性，低毒性，模块化的功能化设计，以及适合癌症治疗，生物成像，抗菌和生物传感的强发光信号。本文综述了发光hof和COFs的基本特性、最新研究进展及其发光机理。此外，本文还深入讨论了构建光活性hof /COFs的设计策略，并重点介绍了它们在癌症治疗、生物成像、抗菌和生物传感方面的应用。最后，对发光hof /COFs在生物医学应用中存在的挑战和未来发展方向进行了展望。本文综述旨在为致力于推进基于hof / cofs的发光生物医学应用材料的研究人员提供有价值的见解。

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引用次数: 0

Cellulose/zeolitic imidazolate framework (ZIF) hybrid: Recent progress in synthesis and applications 纤维素/咪唑酸分子筛骨架（ZIF）杂化物的合成及应用进展

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-13 DOI: 10.1016/j.ccr.2025.217479

Milad Asadnia, Hatam Najafi Fath Dehghan, Mahsa Khorasani, Hadieh Rahbar Kafshboran, Mehdi Sadat-Shojai, Soheila Ghasemi, Amir Abdolmaleki

Hybrid materials, which combine organic and inorganic components, represent a forefront class of materials that exhibit sustainable properties and high performance due to the synergy between their constituents. Among them, composites based on cellulose, a biodegradable biopolymer, and zeolitic imidazolate framework (ZIF), known for their high porosity and customizable structure, have emerged as a novel class of green hybrid systems. The combination of high crystallinity, adsorption capacity, and antibacterial activity of ZIF with the mechanical flexibility, biocompatibility, and hydrophilicity of cellulose results in materials with enhanced capabilities that are not unattainable with either material alone. While numerous articles have been published on cellulose-based materials and ZIFs individually, the current literature lacks detailed and concentrated investigations specifically on cellulose/ZIF composites. This review directly addresses this gap by providing a targeted analysis of these hybrid materials, focusing on their synthesis methods, structural properties, and prominent applications. This review not only consolidates dispersed knowledge but also provides a clear roadmap for future innovation. In addition, an attempt is made to portray the current status of these hybrid materials, the most recent technologies of commercialization, and some recent scientific research in the field. Despite the outstanding properties of cellulose/ZIF composites, several challenges, including issues of scalability, reproducibility, and a limited understanding of molecular-level interactions, hinder their commercialization as the next generation of hybrid materials. Therefore, the review explores promising pathways to address these challenges, such as the integration of artificial intelligence (AI) for the predictive design of ZIF components.

混合材料结合了有机和无机成分，代表了一类前沿材料，由于其成分之间的协同作用，它们表现出可持续的性能和高性能。其中，基于纤维素（一种可生物降解的生物聚合物）和沸石咪唑酸酯框架（ZIF）的复合材料以其高孔隙率和可定制结构而闻名，已成为一类新型的绿色混合体系。ZIF的高结晶度、吸附能力和抗菌活性与纤维素的机械灵活性、生物相容性和亲水性相结合，使材料具有增强的性能，这是单独使用任何一种材料都无法实现的。虽然已经分别发表了许多关于纤维素基材料和ZIF的文章，但目前的文献缺乏针对纤维素/ZIF复合材料的详细和集中的研究。这篇综述通过对这些杂化材料的合成方法、结构特性和突出应用进行有针对性的分析，直接解决了这一空白。这一回顾不仅巩固了分散的知识，而且为未来的创新提供了清晰的路线图。此外，还试图描述这些混合材料的现状，最新的商业化技术，以及该领域最近的一些科学研究。尽管纤维素/ZIF复合材料具有出色的性能，但一些挑战，包括可扩展性、可重复性以及对分子水平相互作用的有限理解，阻碍了它们作为下一代混合材料的商业化。因此，本文探讨了解决这些挑战的有希望的途径，例如将人工智能（AI）集成到ZIF组件的预测设计中。

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引用次数: 0

Heterojunction engineering in electrocatalytic nitrate-to-ammonia conversion 电催化硝酸制氨转化中的异质结工程

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-13 DOI: 10.1016/j.ccr.2025.217483

Ruikai Qi, Dongming Wang, Xiaofeng Lu

Electrocatalytic nitrate reduction reaction (NO₃RR) represents a significant pathway for green ammonia (NH₃) synthesis due to its environmental compatibility and mild reaction conditions. Heterostructure nanomaterials provide breakthrough solutions for enhancing NO₃RR performance. This review firstly briefly elucidates the fundamental mechanism of NO₃RR, then focuses on how heterojunction design optimizes NO₃RR performance through active site engineering, electronic structure modulation, interfacial water management, and interface stability enhancement, supported by relevant application examples. It further summarizes strategies for constructing heterojunctions as bifunctional electrocatalysts to couple NO₃RR with anodic oxidation reactions, enabling co-production of dual value-added products within integrated electrolytic systems. Finally, this review discusses current challenges and future prospects in this field, aiming to guide the rational design of efficient heterostructured electrocatalysts for large-scale NO₃RR implementation. This work seeks to advance NO₃RR technology from laboratory research toward scalable green NH₃ production.

电催化硝酸还原反应（NO3RR）因其环境相容性和反应条件温和而成为绿色氨（NH3）合成的重要途径。异质结构纳米材料为提高NO3RR性能提供了突破性的解决方案。本文首先简要阐述了NO3RR的基本机理，然后重点介绍了异质结设计如何通过活性位点工程、电子结构调制、界面水管理和界面稳定性增强来优化NO3RR性能，并结合相关应用实例进行了阐述。进一步总结了构建异质结作为双功能电催化剂的策略，将NO3RR与阳极氧化反应偶联，从而在集成电解系统中实现双增值产品的协同生产。最后，本文综述了该领域目前面临的挑战和未来前景，旨在指导合理设计高效的异质结构电催化剂，以大规模实现NO3RR。这项工作旨在将NO3RR技术从实验室研究推进到可扩展的绿色NH3生产。

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引用次数: 0

Supramolecular metallaphenylsilsesquioxanes: non-covalent effects, magnetic and catalytic properties 超分子金属苯基硅氧烷：非共价效应、磁性和催化性能

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-13 DOI: 10.1016/j.ccr.2025.217455

Alexey N. Bilyachenko , Armando J.L. Pombeiro , M. Fátima C. Guedes da Silva , Elena S. Shubina , Yannick Guari , Joulia Larionova

Phenyl-surrounded silsesquioxane architectures based on transition metal ions including Cu(II), Ni(II) and Mn(II), (III), are reviewed in the context of their supramolecular aggregation. Several noncovalent mechanisms governing the formation of coordination polymers of different dimensionalities (1D, 2D, and 3D) based on cage-like metallasilsesquioxanes used as building blocks are discussed.These mechanisms include the employement of intercage connections via: (i) organic linkers or solvating ligands bridges, (ii) crown ether contacts, (iii) metallocene fragments, and (iv) π–π stacking or C–H…π interactions. Potential applications of supramolecular metallaphenylsilsesquioxanes in catalysis and magnetism are also discussed. For instance, Cu(II)- and Mn(II), (III)-based compounds appear as efficient catalysts in oxidative reactions and carbon dioxide couplings. On the other hand, Cu(II)- and Ni(II)-silsesquioxane-based coordination polymers exhibit intriguing magnetic properties, including observation of a slow relaxation of the magnetization due to spin glass behavior.

本文综述了基于Cu（II）、Ni（II）和Mn（II）、（III）等过渡金属离子的苯基环银半氧烷结构的超分子聚集。本文讨论了以笼状金属硅氧烷为构建块，形成不同维数（1D、2D和3D）配位聚合物的几种非共价机制。这些机制包括通过以下途径实现笼间连接：(i)有机连接剂或溶剂化配体桥，（ii）冠醚接触，（iii）茂金属碎片，(iv) π -π堆叠或C-H…π相互作用。讨论了超分子金属苯基硅氧烷在催化和磁性方面的潜在应用。例如，Cu(II)-和Mn(II), （III）基化合物在氧化反应和二氧化碳偶联中表现为有效的催化剂。另一方面，Cu(II)-和Ni(II)-硅氧烷基配位聚合物表现出有趣的磁性，包括观察到由于自旋玻璃行为导致磁化缓慢弛豫。

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引用次数: 0

A review: Insight into iron-based oxides of oxygen evolution reaction and their application 综述：析氧反应中铁基氧化物的研究进展及其应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-12 DOI: 10.1016/j.ccr.2025.217469

Guanjie Xue , Hongliang Fu , Hanyu Shi , Yue Lian , Yong Dai , Jing Zhao , Huaihao Zhang

Due to good redox activity and inherent catalytic performance, iron-based oxides have emerged as promising oxygen evolution reaction (OER) catalysts. Developing highly active and robustly stable iron-based oxides shows great potential for electrocatalytic performance enhancement in OER. Here, this work offers a comprehensive review of iron-based oxides as OER catalysts and its research progress. At first, we introduce the mechanisms of OER, including the conventional adsorption evolution mechanism (AEM), lattice oxygen evolution mechanism (LOM), oxidation pathway mechanism (OPM), and coupled oxygen evolution mechanism (COM). Subsequently, this review focuses on the structural characteristics of iron-based oxides, covering iron-based monometallic oxides, iron-based bimetallic oxides, iron-based polymetallic oxides and other types of iron-based oxides. Furthermore, we discuss the design approaches and their improvement of iron-based oxides, such as morphology optimization, defect engineering, support engineering, heterostructure construction and so on. Finally, the shortcomings of iron-based oxides in current study of OER catalysts are summarized, also with their future research prospects.

由于具有良好的氧化还原活性和固有的催化性能，铁基氧化物已成为很有前途的析氧反应催化剂。开发高活性和稳定的铁基氧化物对提高OER电催化性能具有很大的潜力。本文对铁基氧化物作为OER催化剂的研究进展进行了综述。首先介绍了OER的机理，包括常规吸附析氧机制（AEM）、晶格析氧机制（LOM）、氧化途径机制（OPM）和耦合析氧机制（COM）。随后，本文重点介绍了铁基氧化物的结构特征，包括铁基单金属氧化物、铁基双金属氧化物、铁基多金属氧化物和其他类型的铁基氧化物。并从形貌优化、缺陷工程、支撑工程、异质结构构建等方面探讨了铁基氧化物的设计方法及其改进。最后总结了目前OER催化剂研究中铁基氧化物存在的不足，并对其未来的研究前景进行了展望。

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引用次数: 0

Nanomedicine-driven strategies for CD8+ T cell enhancement in Cancer immunotherapy 肿瘤免疫治疗中CD8+ T细胞增强的纳米药物驱动策略

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-12 DOI: 10.1016/j.ccr.2025.217468

Zhenhao Gao , Chen Chen , Xinglin Chen , Pingyi Yao , Weiyu Li , Yueyun Fan , Sa Wang , Meng Sun , Ke Sun , Jinfeng Zhang

Immunotherapy has demonstrated remarkable clinical potential in tumor therapies by activating or augmenting the specific antitumor immune response. CD8⁺ T cells, as the key effector cells of adaptive immunity, play a pivotal role in inducing tumor cell apoptosis. Nevertheless, the immunosuppressive tumor microenvironment substantially restricts the proliferation, infiltration, and cytotoxic activity of CD8⁺ T cells. Furthermore, the depletion and functional impairment of CD8⁺ T cells constitute a major barrier to effective immunotherapy. Recent advances in nanomedicine have provided innovative strategies to overcome immunosuppression and CD8⁺ T cell exhaustion, rejuvenating CD8⁺ T cell-mediated antitumor immunity. In this timely review, a brief outline of the historical development of immunotherapy is first provided, together with a comprehensive overview of T cell classification. This review systematically examines five nanomedicine-driven strategies to potentiate CD8⁺ T cell immunity, including metalloimmunology, regulation of receptors, utilization of CAR-T cell, utilization of exosomes, and normalization of the tumor microenvironment (TME). Finally, the primary existing challenges faced by nanomedicine-driven cancer immunotherapy in clinical translation as well as future perspectives are also outlined. This review will provide guidance for developing next-generation nanomaterial-driven CD8⁺ T cell enhancement in cancer immunotherapy.

免疫疗法通过激活或增强特异性抗肿瘤免疫反应，在肿瘤治疗中显示出显著的临床潜力。CD8+ T细胞作为适应性免疫的关键效应细胞，在诱导肿瘤细胞凋亡中起着关键作用。然而，免疫抑制的肿瘤微环境实质上限制了CD8+ T细胞的增殖、浸润和细胞毒活性。此外，CD8+ T细胞的耗竭和功能损伤是有效免疫治疗的主要障碍。纳米医学的最新进展为克服免疫抑制和CD8+ T细胞衰竭提供了创新的策略，使CD8+ T细胞介导的抗肿瘤免疫恢复活力。在这篇及时的综述中，首先简要概述了免疫治疗的历史发展，并对T细胞分类进行了全面概述。本文系统地探讨了五种纳米药物驱动的增强CD8+ T细胞免疫的策略，包括金属免疫学、受体调节、CAR-T细胞的利用、外泌体的利用和肿瘤微环境（TME）的正常化。最后，概述了纳米医学驱动的癌症免疫治疗在临床转化中面临的主要挑战以及未来的前景。这一综述将为开发下一代纳米材料驱动的CD8+ T细胞增强在癌症免疫治疗中的应用提供指导。

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引用次数: 0

Macrocycle-based supramolecular functional materials driven by charge transfer interactions 电荷转移相互作用驱动的基于大环的超分子功能材料

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-12 DOI: 10.1016/j.ccr.2025.217488

Chun-Li Song, Ying-Wei Yang

Macrocycle-based supramolecular materials driven by charge-transfer (CT) interactions have emerged as a versatile platform for regulable solid-state functions. This minireview presents a structure-mechanism-function method to rationalize recent progress in constructing such materials, classified by the types of auxiliary interactions involved: (i) intermolecular CT synergistically stabilized by host-guest, π-π, or hydrogen bonding interactions; and (ii) intramolecular CT introduced into the macrocyclic backbone via inherent donor-acceptor (D-A) structure or post-synthetic modification. CT acts as a tunable interaction that shows various applications, including vapochromism, full-color thermally activated delayed fluorescence (TADF), chiral luminescence, microlasing, and selective adsorption, whose mechanisms are dissected from the perspective of crystal engineering. We conclude by identifying current problems and outlining future directions toward scalable synthesis and multi-stimuli responsiveness.

由电荷转移（CT）相互作用驱动的基于大环的超分子材料已经成为可调节固态功能的通用平台。本文简要介绍了一种结构-机制-功能方法，根据所涉及的辅助相互作用类型进行分类，以合理化构建此类材料的最新进展：(i)分子间CT通过主客体，π-π或氢键相互作用协同稳定；（ii）通过固有的供体-受体（D-A）结构或合成后修饰引入大环骨架的分子内CT。CT作为一种可调节的相互作用，显示出各种应用，包括气相变色、全彩热激活延迟荧光（TADF）、手性发光、微激光和选择性吸附，其机制从晶体工程的角度进行了剖析。最后，我们确定了当前的问题，并概述了可扩展合成和多刺激响应的未来方向。

引用次数: 0

Metal-NHC complexes as catalysts for hydrogenation, transfer hydrogenation, and electrochemical reduction of CO2 金属- nhc配合物作为加氢、转移加氢和电化学还原CO2的催化剂

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-12 DOI: 10.1016/j.ccr.2025.217444

Saswati Ray, Saurabh Kumar, Pabitra Mandal, Joyanta Choudhury

The continuous upward trend of the concentration of the most abundant greenhouse gas CO₂, in the atmosphere is triggering alarm across the globe. Among many measures, being taken to tackle the challenge of balancing the atmospheric CO₂ concentration, capture and catalytic conversion of CO₂ into various energy-rich products such as hydrocarbons, methanol, formic acid, CO etc. gained increased attention. N-heterocyclic carbene (NHC)-based transition metal complexes have been recognized as efficient catalysts for various reductive CO₂ conversion processes, due to (i) their easy synthesis and electronic tunability through ligand modification, and (ii) enhanced stability and robustness. This review highlights the recent progress on different reductive conversions of CO₂, such as hydrogenation, transfer hydrogenation, and electrochemical reduction, into high-value products by NHC-based transition metal catalysts. Generally, for the molecular homogeneous catalysts, electronic and geometric characteristics of the ligands are crucial to achieve high solubility, activity, rate of the reaction, and most importantly, product selectivity. Herein, we have discussed the reductive CO₂ conversion processes achieved with various metal-NHC catalysts possessing electronically and sterically varied NHC backbones such as normal and abnormal NHCs, as well as variable steric effects of the N-substituents on the NHCs. Based on the discussion of the developed systems, we also underscored the future direction of research in this critical area.

大气中最丰富的温室气体二氧化碳浓度的持续上升趋势正在全球范围内引发警报。在众多措施中，应对平衡大气二氧化碳浓度的挑战，二氧化碳的捕获和催化转化为各种高能量产品，如碳氢化合物、甲醇、甲酸、一氧化碳等，受到越来越多的关注。基于n -杂环碳（NHC）的过渡金属配合物被认为是各种还原性CO2转化过程的有效催化剂，因为(i)它们易于合成和通过配体修饰具有电子可调性，（ii）具有增强的稳定性和鲁棒性。本文综述了以nhc为基础的过渡金属催化剂在二氧化碳加氢、转移加氢和电化学还原等不同还原转化为高价值产品方面的最新进展。一般来说，对于分子均相催化剂来说，配体的电子和几何特性对于实现高溶解度、活性、反应速率以及最重要的产物选择性至关重要。本文中，我们讨论了不同的金属-NHC催化剂所实现的还原CO2转化过程，这些催化剂具有不同的电子和立体结构的NHC骨架，如正常NHC和异常NHC，以及n取代基对NHC的可变立体效应。在对发达系统进行讨论的基础上，我们还强调了这一关键领域未来的研究方向。

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引用次数: 0

Inorganic cesium manganese halides: Insights into optical properties, coordination chemistry, synthesis methods and optoelectronic applications 无机卤化铯锰：光学性质、配位化学、合成方法及光电应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-12-12 DOI: 10.1016/j.ccr.2025.217481

Sheikh Jobe , Lamia Ali Siddig , Adel Najar , Abbas Khaleel , Na'il Saleh , Fathy M. Hassan

In recent years, remarkable progress has been made in research on cesium manganese halides. These materials have sparked intense research interest in applications that require rapid response rates, such as X-ray scintillation and optical communication, due to their high PLQY and tunable radiative lifetimes depending on the shortest Mn-Mn distance. This review aims to provide an in-depth and exclusive review of cesium-Mn metal halides with respect to their optical, electronic, and spectroscopic properties, as well as their coordination chemistry. We explain the ion-luminescence emission mechanism and its dependency on the local coordination around the Mn²⁺ ions. Fundamental principles such as Mn-Mn coupling interactions, Mn-Mn distance, and d–d transition selection rules are discussed in depth. Then, we discuss the three most common protocols for synthesizing Mn halide perovskites. In conclusion, we provide perspectives to establish a clear and comprehensive understanding to optimize the structure-luminescence relationship to pioneer strategies to overcome challenges in cesium-Mn halides and develop optoelectronic devices.

近年来，卤化铯锰的研究取得了显著进展。这些材料在需要快速响应速率的应用中引发了强烈的研究兴趣，例如x射线闪烁和光通信，因为它们具有高PLQY和可调谐的辐射寿命，这取决于最短的Mn-Mn距离。本文对铯-锰金属卤化物的光学、电子、光谱性质及其配位化学进行了深入和独家的综述。我们解释了离子发光发射机制及其对Mn2+离子周围局部配位的依赖。深入讨论了Mn-Mn耦合相互作用、Mn-Mn距离和d-d跃迁选择规则等基本原理。然后，我们讨论了三种最常见的合成卤化锰钙钛矿的方案。综上所述，我们提供了建立清晰和全面的认识，以优化结构-发光关系，以克服铯-锰卤化物的挑战和开发光电器件的先驱策略的观点。

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引用次数: 0