Multi-Factor Orthogonal Experiments and Enhancement Mechanisms of Unconfined Compressive Strength of Soda Residue Cement Lime Soil

Wenbo Cheng, Wei Yin, Xiaoya Wang, Quan Xu, Guodong Wang, Jun Cao, Shengxue Zhu
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Abstract

In order to study the effects of soda residue content, particle size, moisture content, and curing age on the unconfined compressive strength (UCS) of soda residue cement lime soil (SRCLS), a 4-factor, 4-level orthogonal experimental design was employed in this study. Different conditions of SRCLS UCS and their impacts were tested and analyzed. The internal microstructure and hydration products of SRCLS were studied using SEM and XRD to explore the strengthening mechanism of SR in SRCLS. The results indicate that as the soda residue content gradually increased, SRCLS UCS initially increased and then decreased, with a maximum increase of up to 67%. With increasing soda residue particle size and moisture content, the UCS of SRCLS gradually decreased. The optimized mix ratio was determined to be soda residue:cement:lime:soil = 3%:3%:6%:100%, with the soda residue dried naturally and an ideal particle size of 0.15 mm. The factors influencing the unconfined compressive strength (UCS) of SRCLS, in order of importance, are curing age, soda residue content, moisture content, and particle size of SR. Among these, curing age and soda residue content have a significant impact on the UCS. An adequate amount of SR can act as a fine aggregate filler, replace lime, promote cement hydration, and enhance chloride ion binding. This improves the grading of SRCLS materials and facilitates the formation of cementitious products from AFm, AFt, and Friedel’s salt, resulting in denser and stronger SRCLS materials. The research findings provide a reference for the mix design of SRCLS and the large-scale utilization of waste soda residue.
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碱渣水泥石灰土非密实抗压强度的多因素正交实验与增强机理
为了研究苏打渣含量、粒度、含水量和固化龄期对苏打渣水泥石灰土(SRCLS)无压抗压强度(UCS)的影响,本研究采用了 4 因子、4 级正交实验设计。试验分析了 SRCLS 不同条件下的无压抗压强度及其影响。利用扫描电镜和 XRD 研究了 SRCLS 的内部微观结构和水化产物,以探索 SRCLS 中 SR 的强化机理。结果表明,随着苏打渣含量的逐渐增加,SRCLS 的 UCS 先增加后减少,最大增幅可达 67%。随着苏打渣粒度和含水量的增加,SRCLS 的 UCS 逐渐降低。经确定,苏打渣:水泥:石灰:土壤=3%:3%:6%:100%,苏打渣自然干燥,理想粒径为 0.15 毫米。影响 SRCLS 无压抗压强度(UCS)的因素依次为固化龄期、苏打渣含量、含水量和 SR 的粒径。其中,固化龄期和苏打残渣含量对无侧限抗压强度有重大影响。适量的苏打渣可以作为细骨料填料,替代石灰,促进水泥水化,增强氯离子结合力。这可以改善 SRCLS 材料的级配,促进 AFm、AFt 和 Friedel 盐形成胶凝产物,从而使 SRCLS 材料更致密、更坚固。研究成果为 SRCLS 的混合设计和大规模利用废碱渣提供了参考。
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