Advanced, high-performance thermo-insulating plaster

A. Athanasiadi, M. Andrikopoulou, M. Smyrnioti, Y. Georgiou, M. Zamparas, V. Dracopoulos, T. Ioannides
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Abstract

The main purpose of many current studies regarding energy efficiency is the improvement of the thermal resistance of buildings. To fulfill this goal, the development of advanced insulating materials, to be incorporated in the building envelopes, is imperative. Aerogels are ultralight porous materials typically produced via the sol-gel process followed by supercritical drying of the wet gel. They exhibit very high porosities and a mesoporous-macroporous structure which endows aerogels with extremely low thermal conductivity. This makes them ideal candidates for ambient thermal insulation applications. However, the cost for aerogel insulation is considerably higher than the one of standard insulation products. In the present work, highly porous aerogel-like materials based on silica and commercial novolac resin were developed and added to common mortars. The prepared materials were dried under ambient pressure to minimize the manufacturing cost. The bulk density of silica quasi-aerogels was 0.03 g/cm3–0.09 g/cm3 and that of the novolac resin samples 0.09 g/cm3–0.21 g/cm3. The aerogels were incorporated in mortars and cured for 28 days before measurement of thermal conductivity. The values of the thermal conductivity coefficient of the measured samples were 0.047 W/m K–0.058 W/m K for the silica reinforced mortars and 0.036 W/m K–0.044 W/m K for the novolac reinforced ones.

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先进的高性能隔热灰泥
目前,许多有关能源效率的研究的主要目的是提高建筑物的热阻。为了实现这一目标,必须开发先进的隔热材料,并将其应用于建筑围护结构中。气凝胶是一种超轻多孔材料,通常通过溶胶-凝胶工艺生产,然后对湿凝胶进行超临界干燥。气凝胶具有极高的孔隙率和介孔-大孔结构,因而导热率极低。这使它们成为环境隔热应用的理想候选材料。然而,气凝胶隔热材料的成本大大高于标准隔热产品。本研究开发了基于二氧化硅和商用酚醛树脂的高多孔气凝胶材料,并将其添加到普通砂浆中。所制备的材料在常压下干燥,以最大限度地降低制造成本。二氧化硅准气凝胶的体积密度为 0.03 g/cm3-0.09 g/cm3,酚醛树脂样品的体积密度为 0.09 g/cm3-0.21 g/cm3。在测量导热系数之前,将气凝胶加入砂浆中并固化 28 天。测得的样品导热系数值分别为:二氧化硅增强砂浆为 0.047 W/m K-0.058 W/m K,酚醛树脂增强砂浆为 0.036 W/m K-0.044 W/m K。
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