Study of liquid photopolymer 3D printing resins exposed to accelerated aging for cultural heritage purposes

María Higueras, Ana Carrasco-Huertas, A. I. Calero-Castillo, Manuel Moreno Alcaide, Francisco José Collado Montero
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Abstract

Purpose This paper aims to study the suitability of a selection of 3D printing liquid photopolymer resins for their application in the cultural heritage context. Design/methodology/approach The main concerns regarding the conservation and restoration of cultural assets are the chemical composition and long-term behavior of the new materials that will be in contact with the original object. Because of this, four different LED curing resins were exposed to an accelerated aging procedure and tested to identify the materials which demonstrated a better result. Some specific properties of the material (color, glossiness, pH and volatile organic compound emissions) were measured before and after the exposure. Findings Some of the properties measured reported good results demonstrating a decent stability against the selected aging conditions. The main changes were produced in the colorimetric aspect, probably indicating other chemical reactions in the material. Likewise, a case study could be also executed to demonstrate the usefulness of these materials in the cultural field. Research limitations/implications It is necessary to study in more detail the long-lasting behavior of the materials employed with these technologies. Further analysis should be carried out highlighting the chemical composition and degradation process of the materials proposed. Originality/value This paper contributes to the introduction of curing 3D printing resins in the restoration methodologies of cultural assets. For this, the study of a selection of properties represents the first stage to suggest or reject their use.
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为文化遗产目的对暴露于加速老化环境中的液态光聚合物 3D 打印树脂进行研究
设计/方法/途径 保护和修复文化资产的主要关注点是将与原物接触的新材料的化学成分和长期行为。因此,对四种不同的 LED 固化树脂进行了加速老化程序和测试,以确定哪种材料的效果更好。在曝晒前后,对材料的一些特定属性(颜色、光泽度、pH 值和挥发性有机化合物排放)进行了测量。主要变化出现在色度方面,这可能表明材料中发生了其他化学反应。同样,还可以通过案例研究来证明这些材料在文化领域的实用性。本文有助于在文化资产修复方法中引入固化 3D 打印树脂。为此,对部分特性的研究是建议或拒绝使用这些材料的第一阶段。
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