Bulk photovoltaic effect in Cu-doped LiNbO3 single crystals with controlled oxidation state

Abstract

We investigate the bulk photovoltaic (PV) effect of Cu-doped LiNbO3 single crystals with various oxidation states of Cu. The Cu-doped samples exhibit the PV response under below-bandgap excitation, and the onset of photocurrent shifts depending on partial oxygen pressures (pO2) during the annealing treatment. Open-circuit voltages (V oc) under simulated sunlight (AM 1.5G) illumination are changed by pO2, and crystals annealed at pO2 = 1.0 × 10−10 atm exhibit the highest V oc of 1,700 V. Moreover, density functional theory (DFT) calculations for Cu-doped LiNbO3 cells with Cu2+ on the Li site and the Nb site indicate that half-filled gap states derived from 3d orbitals of Cu are formed within the bandgap. Based on Glass coefficients obtained by the analyses of polarization angle-dependent photocurrent densities and the DFT calculations, we consider that Cu2+ on the Li site is the major active site for the generation and separation of electron-hole pairs under visible light at hν = 2.4 eV.