Peach Gum Polysaccharide as an Additive for Thermoplastic Starch to Produce Water-Soluble Films

Macromol Pub Date : 2024-07-08 DOI:10.3390/macromol4030028
Juan Vicente Miguel Guillem, Andrea Juan-Polo, C. Pavon, J. López‐Martínez
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Abstract

Thermoplastic starch (TPS) has gained considerable attention during the last few years in developing starch-based biodegradable food packaging materials or edible coatings due to its high availability and low cost. TPS is manufactured from starch plasticized with food-grade plasticizers, making it suitable for food contact applications. In addition, TPS is bio-based and biodegradable, which, from an environmental perspective, closes the circle of the circular economy. However, the industrial application of TPS is somewhat limited due to its poor mechanical performance and low water resistance. However, the low water resistance could increase the water sensitivity of TPS, which could be advantageous for coating application or food encapsulation. The present work aims to tailor the water sensitivity of TPS by adding peach gum polysaccharide to obtain water-soluble films. With this aim, peach gum polysaccharide (PGP) was extracted from peach gum (PG) using the thermal hydrolysis method. Films of TPS-PG and TPS-PGP were prepared and characterized by their water sensitivity and mechanical, microstructural, and thermal properties. The results show that PGP allows the obtaining of films with water sensitivities higher than 70% but also improves TPS elongation at break, making the material more suitable for application as film.
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桃胶多糖作为热塑性淀粉的添加剂,用于生产水溶性薄膜
在过去几年中,热塑性淀粉(TPS)因其高可用性和低成本,在开发以淀粉为基础的可生物降解食品包装材料或可食用涂层方面受到了广泛关注。TPS 是用食品级增塑剂增塑的淀粉制造而成,因此适用于食品接触应用。此外,TPS 以生物为基础,可生物降解,从环保的角度来看,可以实现循环经济。不过,由于 TPS 的机械性能差、耐水性低,其工业应用受到一定限制。不过,低耐水性可以提高 TPS 对水的敏感性,这在涂层应用或食品封装方面可能是有利的。本研究旨在通过添加桃胶多糖来调整 TPS 的水敏性,从而获得水溶性薄膜。为此,采用热水解法从桃胶(PG)中提取了桃胶多糖(PGP)。制备了 TPS-PG 和 TPS-PGP 薄膜,并对其水敏感性以及机械、微结构和热性能进行了表征。结果表明,PGP 可使薄膜的水敏性高于 70%,同时还能提高 TPS 的断裂伸长率,使该材料更适合用作薄膜。
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