Fuel starvation in automotive PEMFC stacks: hydrogen stoichiometry and electric cell-to-cell interaction

Abstract

Fuel gross starvation in a polymer electrolyte membrane fuel cell is an error state, during which the supplied amount of fuel is insufficient to sustain the requested electrical current. A novel experimental technique was developed to intentionally provoke well-controlled fuel starvation situations of one single cell in a multi-cell fuel cell stack. This modification was implemented in a 20-cell stack of automotive-sized cell geometry and carbon composite bipolar plates. The intentional fuel starvation situation was analyzed using a printed circuit board to measure the current density distribution in addition to a multipoint cell voltage monitoring to measure local cell voltages. The provoked detrimental subsidiary reactions of the anode were found to take place spatially separated from the normal hydrogen oxidation reaction. It was therefore possible to determine and intentionally vary the hydrogen stoichiometry of the fuel starved cell. This error state caused intense distortions of the starved cells current density distribution and local cell voltages. The maximum difference obtained between outlet and inlet voltage of the modified cell was 1.4 V. Compared to the average current density, a more than 4-times higher maximum local current density was measured in the affected cell. Adjacent cells were also affected via electric cell-to-cell interaction. Characteristic patterns therefore became visible in the cell voltage distribution, measured by the inlet and outlet cell voltage monitoring. The use of carbon composite bipolar plates is favoring the occurrence of these patterns due to their relatively high electric sheet resistance. Using the new hardware setup, we could investigate the relation between the hydrogen stoichiometry of the affected cell during fuel gross starvation and the observed irregular redistribution of current density and local cell voltages.