High-mobility and high-reliability Zn-incorporated amorphous In2O3-based thin-film transistors

Yuzhang Wu, Y. Magari, P. Ghediya, Yu-qiao Zhang, Y. Matsuo, Hiromichi Ohta
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Abstract

Polycrystalline indium oxide-based thin film transistors (In2O3 TFTs) have attracted considerable attention because of high field effect mobility (μFE ~100 cm2 V−1 s−1). However, In2O3 TFTs exhibit poor reliability owing to the adsorption and/or desorption of gas molecules at the grain boundaries. The incorporation of Zn suppresses the crystallization of In2O3. Herein, we systematically studied the effect of Zn incorporation into In2O3 TFTs. The crystallization of In2O3 was suppressed when the Zn concentration ranging from 25% to 68%. Amorphous IZO TFTs with 25% Zn exhibited the highest μFE of 41 cm2 V−1 s−1 and excellent reliability. In contrast, polycrystalline IZO TFTs showed a low μFE <12 cm2 V−1 s−1 due to the formation of grain boundaries, and poor reliability after positive gate bias, mostly due to electron trapping at the polycrystalline/insulator interface. These results render an approach to realize In2O3 TFTs that show reasonably high μFE and excellent reliability.
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高移动性和高可靠性 Zn 掺杂非晶 In2O3 基薄膜晶体管
基于氧化铟的多晶薄膜晶体管(In2O3 TFT)因其高场效应迁移率(μFE ~100 cm2 V-1 s-1)而备受关注。然而,由于气体分子在晶界的吸附和/或解吸,In2O3 TFT 的可靠性较差。Zn 的加入抑制了 In2O3 的结晶。在此,我们系统地研究了在 In2O3 TFT 中掺入 Zn 的影响。当锌浓度在 25% 至 68% 之间时,In2O3 的结晶受到抑制。含锌 25% 的无定形 IZO TFT 的 μFE 值最高,达到 41 cm2 V-1 s-1,可靠性极佳。相比之下,多晶 IZO TFT 由于晶界的形成而显示出较低的μFE <12 cm2 V-1 s-1,并且在正栅极偏压后可靠性较差,这主要是由于多晶/绝缘体界面上的电子捕获造成的。这些结果提供了一种实现 In2O3 TFT 的方法,这种 TFT 具有相当高的μFE 值和出色的可靠性。
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