Complex Diagnostics of Silicon-on-Insulator Layers after Ion Implantation and Annealing

P. A. Yunin, M. N. Drozdov, A. V. Novikov, V. B. Shmagin, E. V. Demidov, A. N. Mikhailov, D. I. Tetelbaum, A. I. Belov
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Abstract

A technology was developed for activating ion-implanted dopants in silicon-on-insulator layers at a low annealing temperature (600°C) using the pre-amorphization technique of a silicon device layer. In the case of phosphorus implantation, silicon was amorphized directly by dopant ions. In the case of boron implantation for pre-amorphization, the layers were preliminary irradiated with argon or fluorine ions. Complex diagnostics of the implanted layers was carried out using secondary ion mass spectrometry, X-ray diffractometry, and small-angle X-ray reflectometry. The combination of methods made it possible to characterize the impurity distribution, the degree of silicon crystallinity, the layer thicknesses, and the interface widths in structures. The results of diagnostics of the structure and composition correlate well with calculations in the SRIM software package and the electrophysical characteristics of the layers after annealing. It was shown that the use of argon for pre-amorphization of silicon interfered with the recrystallization process and did not make it possible to achieve acceptable electrical characteristics of the doped layer. Amorphization with phosphorus and pre-amorphization with fluorine during boron implantation allowed obtaining the required values of the resistance of the doped layers after annealing at a temperature of 600°C. The use of a complex approach rendered it possible to optimize the modes of amorphization, ion doping, and annealing of silicon-on-insulator structures at low temperatures necessary for the creation of light-emitting device structures based on silicon-germanium nanoislands.

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离子注入和退火后绝缘体上硅层的复杂诊断方法
摘要 利用硅器件层的预变质技术,开发了一种在低退火温度(600°C)下激活硅-绝缘体层中离子注入掺杂剂的技术。在磷植入的情况下,硅被掺杂离子直接非晶化。在硼植入预变质的情况下,硅层首先受到氩离子或氟离子的辐照。使用二次离子质谱法、X 射线衍射仪和小角 X 射线反射仪对植入层进行了复杂的诊断。这些方法的结合可以确定结构中杂质分布、硅结晶度、层厚度和界面宽度的特征。结构和成分的诊断结果与 SRIM 软件包的计算结果以及退火后层的电物理特性密切相关。研究表明,使用氩气对硅进行预变质会干扰再结晶过程,无法使掺杂层达到可接受的电特性。在植入硼的过程中,用磷进行非晶化和用氟进行预非晶化,可以使掺杂层在 600°C 的退火温度下获得所需的电阻值。通过采用复杂的方法,可以优化硅绝缘体结构的非晶化、离子掺杂和低温退火模式,这些都是制造基于硅锗纳米带的发光器件结构所必需的。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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