Simulation of the Electrical Parameters of Microarc Oxide Coatings Using the Matrix-Operator Method

E. A. Pecherskaya, S. V. Konovalov, A. D. Semenov, P. E. Golubkov, S. A. Gurin, M. D. Novichkov
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Abstract

The work addresses the issues of controllability of the microarc-oxidation process. This problem is mostly due to the difficulty of analytically characterizing the heterogeneous physical–chemical processes, which are nonlinear and nonstationary, that take place during microarc oxidation. To tackle this issue, a digital twin of the process is being developed, within which an analytical model is proposed to describe the behavior of the equivalent electrical circuit of the galvanic cell during coating deposition. The proposed analytical model of the process is nonlinear and nonstationary, which is attributed to the abrupt decrease in the active resistance of the coating during dielectric breakdowns. Based on experimentally obtained current and voltage oscillograms and the proposed analytical model, parametric identification of the electrical parameters of oxide coatings is performed using the matrix-operator method on the orthonormal Walsh basis. The matrix-operator method is selected because of its applicability to solving problems with both linear and nonlinear equations, as well as stationary and nonstationary parameters and variables, along with the relative simplicity of the mathematical and algorithmic implementation of computations. The calculations result in weight functions of the electrical model of the microarc-oxidation process, reflecting the relationship between the voltage and current in the galvanic cell (coating conductivity). The mean values of the weight functions (average conductivity) decrease during coating deposition, which confirms the adequacy of the proposed model and enables its use for implementing real-time procedures for monitoring coating properties. The scientific novelty of the work lies in the possibility of the real-time control of microarc oxidation through parametric identification of the electrical parameters of coatings using the matrix-operator method.

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使用矩阵-操作器法模拟微弧氧化涂层的电气参数
摘要 这项工作涉及微弧氧化过程的可控性问题。造成这一问题的主要原因是难以分析描述微弧氧化过程中发生的非线性和非稳态的异质物理化学过程。为了解决这个问题,我们正在开发一个该过程的数字孪生模型,并在该模型中提出了一个分析模型,用于描述涂层沉积过程中电化学电池等效电路的行为。所提出的过程分析模型是非线性和非稳态的,这归因于电介质击穿时涂层有源电阻的突然下降。根据实验获得的电流和电压振荡图以及提出的分析模型,在正交沃尔什基础上使用矩阵算子法对氧化物涂层的电参数进行了参数化识别。之所以选择矩阵算子法,是因为该方法既适用于解决线性和非线性方程问题,也适用于解决静态和非静态参数和变量问题,而且计算的数学和算法实现相对简单。计算得出了微弧氧化过程电气模型的权函数,反映了电化池中电压和电流(涂层导电率)之间的关系。在涂层沉积过程中,权重函数的平均值(平均电导率)会降低,这证明了所建议模型的适当性,并可用于实施实时监控涂层性能的程序。这项工作的科学新颖性在于,通过使用矩阵操作器方法对涂层电参数进行参数化识别,可以实时控制微弧氧化。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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